11-hydroxyundecyl methacrylate | 118915-07-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 11-hydroxyundecyl methacrylate
• 英文别名: 11-hydroxyundecyl 2-methylprop-2-enoate；1,11-undecanediol di(meth)acrylate
• CAS: 118915-07-4
• 化学式: C₁₅H₂₈O₃
• 分子量: 256.386
• InChiKey: BNEHVIPZGXTFLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(3,4,5,6-四氢吡喃-2-氧基)苯甲酸 、 11-hydroxyundecyl methacrylate 在 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and investigation of photophysical and photochemical properties of new side-group liquid crystalline polymers containing coumarin moieties

  摘要：

  制备并研究了四种含香豆素（2-氧代-2H-1-苯并吡喃）的液晶聚甲基丙烯酸酯，这些聚合物具有相同的单体结构，但其介质的连接方向和/或构造方向不同。四种聚合物均表现出向列相A型液晶相。构造和/或连接方向的变化显著影响了它们的液晶特性。特别是，介质构造方向的改变导致了不同的光物理和光化学性质。

  DOI：

  10.1039/b408554j

文献信息

• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• Relining material for dentures
  申请人：Kuraray Co., Ltd.

  公开号：EP1033125A1

  公开（公告）日：2000-09-06

  Provided is a denture rebase comprising a fluoro(meth)acrylate having a specific side chain structure and a specific amount of a polyfunctional (meth)acrylate. The denture rebase is free from the serious problems with conventional denture rebases that are readily discolored and stained and absorb smelling substances and water. It has good contamination and staining resistance, and its cured product is tough.

  本文提供了一种义齿修复剂，它由具有特定侧链结构的氟丙烯酸酯和特定量的多官能（甲基）丙烯酸酯组成。该义齿修复基托不存在传统义齿修复基托容易褪色、染色、吸附异味物质和水分等严重问题。它具有良好的抗污染和抗染色性，固化后的产品韧性强。
• ZUSAMMENSETZUNG FÜR OPHTHALMOLOGISCHE PRODUKTE
  申请人：Merck Patent GmbH

  公开号：EP3502147A1

  公开（公告）日：2019-06-26

  Die vorliegende Erfindung betrifft eine Zusammensetzung für ophthalmologische Produkte, ensprechende Copolymere und deren Herstellung sowie deren Verwendung zur Herstellung von opthalmischen Linsen oder ophthalmologischen Implantaten sowie diese Produkte.

  本发明涉及一种用于眼科产品的组合物、相应的共聚物及其制备方法，以及它们在制造眼科镜片或眼科植入物和这些产品中的用途。
• ACTIVE ENERGY RAY-CURABLE COATING COMPOSITION
  申请人：Nippon Paint Automotive Coatings Co., Ltd.

  公开号：EP3677649A1

  公开（公告）日：2020-07-08

  An object of the present invention is to provide an active energy ray-curable coating composition including a specific resin component and at least one pigment (D) selected from the group consisting of a coloring pigment and a glitter pigment. The present invention provides an active energy ray-curable coating composition including a poly[(meth)acryloyloxyalkyl] isocyanurate (A); a polyfunctional (meth)acrylate (B) having 4 or more (meth)acrylate groups; an acrylic resin (C); and at least one pigment (D) selected from the group consisting of a coloring pigment and a glitter pigment, wherein the acrylic resin (C) has a weight-average molecular weight in the range of 5,000 to 30,000 and a solubility parameter in the range of 9.0 to 11.5.

  本发明的目的是提供一种活性能量射线固化涂料组合物，包括特定的树脂组分和至少一种选自着色颜料和闪光颜料的颜料（D）。本发明提供了一种活性能量射线固化涂料组合物，包括聚[（甲基）丙烯酰氧基烷基]异氰脲酸酯（A）；具有 4 个或更多个（甲基）丙烯酸酯基团的多官能（甲基）丙烯酸酯（B）；丙烯酸树脂（C）；和至少一种选自着色颜料和闪光颜料组成的组的颜料 (D)，其中丙烯酸树脂 (C) 的重量平均分子量在 5,000 至 30,000 之间，溶解度参数在 9.0 至 11.5。