1-(10-mercaptodecyl)pyrrole | 213907-76-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 1-(10-mercaptodecyl)pyrrole
• 英文别名: 10-(1H-Pyrrol-1-yl)decane-1-thiol；10-pyrrol-1-yldecane-1-thiol
• CAS: 213907-76-7
• 化学式: C₁₄H₂₅NS
• 分子量: 239.425
• InChiKey: NDOQVDMKEMRQEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  5.9
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-(10-bromodecyl)pyrrole 在 盐酸 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 4.0h， 生成 1-(10-mercaptodecyl)pyrrole
  参考文献：
  名称：

  Preparation and characterization of gold nanoparticles with a ruthenium-terpyridyl complex, and electropolymerization of their pyrrole-modified metal nanocomposites

  摘要：

  在 2,2′:6′,2″-三吡啶辛硫醇存在下，用硼氢化钠还原四氯金酸酯，得到了三吡啶功能化金纳米粒子（Tpy-Au，核心尺寸 2.0 nm）。Tpy-Au 与三氯化钌-三吡啶（Ru(typy)Cl3）发生金属络合，产生了带有钌-三吡啶络合物的新金纳米粒子（Ru-Tpy-Au，核心尺寸为 5.在紫外可见光谱中，Ru-Tpy-Au 在 ∼ 510 nm 处显示出等离子共振。循环伏安法研究了 Ru-Tpy-Au 的氧化还原行为。Ru-Tpy-Au 与 ω-(N-吡咯基)癸硫醇的配体交换反应得到的吡咯官能化 Ru-Tpy-Au 纳米粒子（Pyr-Ru-Tpy-Au）通过电聚合作用对金属电极进行了表面修饰。

  DOI：

  10.1039/b412406e

文献信息

• Organic electronic device and its manufacturing method
  申请人：Yamamoto Shinichi

  公开号：US20050145839A1

  公开（公告）日：2005-07-07

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、形成在基板上的至少两个电极、形成在基板上并电性连接电极的导电有机薄膜以及用于涂覆电极至少一部分的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。
• Organic electronic device and method for manufacturing the same
  申请人：Yamamoto Shinichi

  公开号：US20070085076A1

  公开（公告）日：2007-04-19

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、至少两个形成在基板上的电极、形成在基板上并电性连接电极的导电有机薄膜，以及用于涂覆至少一部分电极的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。
• US7259389B2
  申请人：——

  公开号：US7259389B2

  公开（公告）日：2007-08-21
• US7560731B2
  申请人：——

  公开号：US7560731B2

  公开（公告）日：2009-07-14
• Preparation and characterization of gold nanoparticles with a ruthenium-terpyridyl complex, and electropolymerization of their pyrrole-modified metal nanocomposites
  作者：Masayuki Ito、Takashi Tsukatani、Hisashi Fujihara

  DOI：10.1039/b412406e

  日期：——

  The reduction of tetrachloroaurate with sodium borohydride in the presence of 2,2′:6′,2″-terpyridyloctanethiol gave terpyridine-functionalized gold nanoparticles (Tpy–Au, core size 2.0 nm). Metal complexation of Tpy–Au with ruthenium-terpyridyl trichloride, Ru(tpy)Cl3, led to new gold nanoparticles bearing the ruthenium-terpyridine complex (Ru–Tpy–Au, core size 5.5 nm) which showed a characteristic MLCT (metal-to-ligand charge transfer) band in the visible region at 483 nm due to the terpyridine-ruthenium complex and a plasmon resonance at ∼510 nm in the UV-vis spectrum. The redox behavior of Ru–Tpy–Au was studied by cyclic voltammetry. Surface modification of metal electrodes was performed by the electropolymerization of pyrrole-functionalized Ru–Tpy–Au nanoparticles (Pyr–Ru–Tpy–Au) which were obtained from the ligand-exchange reaction of Ru–Tpy–Au with ω-(N-pyrrolyl)decanethiol.

  在 2,2′:6′,2″-三吡啶辛硫醇存在下，用硼氢化钠还原四氯金酸酯，得到了三吡啶功能化金纳米粒子（Tpy-Au，核心尺寸 2.0 nm）。Tpy-Au 与三氯化钌-三吡啶（Ru(typy)Cl3）发生金属络合，产生了带有钌-三吡啶络合物的新金纳米粒子（Ru-Tpy-Au，核心尺寸为 5.在紫外可见光谱中，Ru-Tpy-Au 在 ∼ 510 nm 处显示出等离子共振。循环伏安法研究了 Ru-Tpy-Au 的氧化还原行为。Ru-Tpy-Au 与 ω-(N-吡咯基)癸硫醇的配体交换反应得到的吡咯官能化 Ru-Tpy-Au 纳米粒子（Pyr-Ru-Tpy-Au）通过电聚合作用对金属电极进行了表面修饰。