1,1,3,3-Tetramethylindantellone | 150194-22-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 1,1,3,3-Tetramethylindantellone
• 英文别名: 1,1,3,3-Tetramethylindene-2-tellone
• CAS: 150194-22-2
• 化学式: C₁₃H₁₆Te
• 分子量: 299.87
• InChiKey: JGCUAJSHOBCMIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,3,3-Tetramethylindantellone 生成 1,1,3,4-四甲基-2-茚酮
  参考文献：
  名称：

  1,1,3,3-Tetramethylindantellone, the first telluroketone stable in solution

  摘要：

  DOI：

  10.1021/ja00068a088
• 作为产物：
  描述：

  1,1,3,3-tetramethylindane-2-one hydrazone 在 氯化碲 、 三乙胺 作用下， 以 氯仿 、 苯 为溶剂， 生成 1,1,3,3-Tetramethylindantellone
  参考文献：
  名称：

  Minoura, Mao; Kawashima, Takayuki; Tokitoh, Norihiro, Phosphorus, Sulfur and Silicon and the Related Elements, 1998, vol. 136, p. 549 - 552

  摘要：

  DOI：

文献信息

• Structure and Thermolysis of a 1,4,2-Oxatellurazole, a Novel Tellurium Containing Heterocycle
  作者：Mao Minoura、Takayuki Kawashima、Renji Okazaki

  DOI：10.1246/cl.1994.1691

  日期：1994.9

  A novel tellurium containing heterocycle, 1,4,2-oxatellurazole, was characterized by X-ray crystallographic analysis which showed a remarkably small C-Te-C bond angle (79.4°), and its thermolysis afforded the corresponding ketone and isonitrile derived from an intermediary isotellurocyanate in a manner of 1,3-dipolar cycloreversion.

  一种新型含碲杂环--1,4,2-氧杂碲唑通过 X 射线晶体学分析进行了表征，分析表明其 C-Te-C 键角（79.4°）非常小，通过 1,3 二极环化反应，其热解产物可从中间体异戊脲酸酯中得到相应的酮和异腈。
• The First Isolation of a Telluroketone and Its Reversible Dimerization
  作者：Mao Minoura、Takayuki Kawashima、Renji Okazaki*

  DOI：10.1016/s0040-4039(97)00377-8

  日期：1997.4

  The solid-state thermolysis of a sterically hindered Delta(3)-1,3,4-telluradiazoline 2 afforded products resulting from intermediary tellone 1 and diazo compound 8 formed by retrocyclization, whereas the flash vacuum thermolysis of 2 led to isolation of tellone 1 as green needles. The spontaneous dimerization of 1 thus obtained occurred in the solid state to give the corresponding 1,3-ditelluretane 10, which underwent the thermal cycloreversion in solution to regenerate pure tellone 1. (C) 1997 Elsevier Science Ltd.
• Weak coordination of a telluroketone in an η¹-mode complex: synthesis and characterization of pentacarbonyl(1,1,3,3-tetramethylindantellone)tungsten
  作者：Mao Minoura、Takayuki Kawashima、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1039/cc9960000123

  日期：——

  Treatment of a stable telluroketone with W(CO)(5)-thf affords the title compound, the X-ray crystal structure of which shows eta(1),sigma-complexation and the trans influence of the weakly coordinated telluroketone; the regeneration of a 'free' telluroketone by ligand exchange of the complex under mild conditions is also reported.