1,2-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)ethane | 346647-87-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,2-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)ethane
• 英文别名: 5,5'-(Ethane-1,2-diylidene)bis(1,2,3,4-tetrachlorocyclopenta-1,3-diene)；1,2,3,4-tetrachloro-5-[2-(2,3,4,5-tetrachlorocyclopenta-2,4-dien-1-ylidene)ethylidene]cyclopenta-1,3-diene
• CAS: 346647-87-8
• 化学式: C₁₂H₂Cl₈
• 分子量: 429.772
• InChiKey: KAQLTTRRVRAGRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1,2,2-四甲氧基乙烷 、 1,2,3,4-四氯-1,3-环戊二烯 在 哌啶 、 溶剂黄146 作用下， 生成 1,2-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)ethane
  参考文献：
  名称：

  Fulvalene derivatives: strong proaromatic electron acceptors

  摘要：

  Synthesis and electrochemical properties of novel proaromatic electron accepters based on the fulvalene parent system are described. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00327-6

文献信息

• Fulvalene derivatives: strong proaromatic electron acceptors
  作者：Emad Aqad、Philippe Leriche、Gilles Mabon、Alain Gorgues、Vladimir Khodorkovsky

  DOI：10.1016/s0040-4039(01)00327-6

  日期：2001.4

  Synthesis and electrochemical properties of novel proaromatic electron accepters based on the fulvalene parent system are described. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Base-catalyzed condensation of cyclopentadiene derivatives. Synthesis of fulvalene analogues: strong proaromatic electron acceptors
  作者：Emad Aqad、Philippe Leriche、Gilles Mabon、Alain Gorgues、Magali Allain、Amédée Riou、Arkady Ellern、Vladimir Khodorkovsky

  DOI：10.1016/s0040-4020(03)00877-9

  日期：2003.7

  A series of proaromatic electron acceptors derived from fulvenes were synthesized from tetrachlorocyclopentadiene and previously unknown 1,4-dicyano- and 1,4-dialkoxycarbonyl-2,3-dimethoxy cyclopentadienes. Two reversible one-electron reductions steps observed for fulvalenes coalesce into one two-electron reduction step upon increasing the length of the conjugating bridge. (C) 2003 Elsevier Ltd. All rights reserved.