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n-butyl 4-hydroxybutyl sulfide | 5331-34-0

中文名称
——
中文别名
——
英文名称
n-butyl 4-hydroxybutyl sulfide
英文别名
4-Hydroxybutylpropylsulfid;4-butylsulfanyl-butan-1-ol;4-Butylmercapto-butan-1-ol;4-Hydroxy-dibutylsulfid;Butyl-(4-hydroxy-butyl)-sulfid;4-(Butylsulfanyl)butan-1-ol;4-butylsulfanylbutan-1-ol
n-butyl 4-hydroxybutyl sulfide化学式
CAS
5331-34-0
化学式
C8H18OS
mdl
——
分子量
162.296
InChiKey
JDJGCJOQZVATQU-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    2.2
  • 重原子数:
    10
  • 可旋转键数:
    7
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    1.0
  • 拓扑面积:
    45.5
  • 氢给体数:
    1
  • 氢受体数:
    2

反应信息

  • 作为反应物:
    描述:
    n-butyl 4-hydroxybutyl sulfide三甲基氯硅烷 、 sodium hydride 、 sodium iodide 作用下, 以 乙腈 为溶剂, 反应 14.0h, 生成 1-n-butylthiolanium iodide
    参考文献:
    名称:
    通过Me 3 SiI促进硫化物分子内置换氢氧化物或甲醇,形成环sulf盐。环收缩硫烷→硫烷
    摘要:
    适当定位的(1、2、1、1、4和1、5-)分子内硫化物会干扰碘代三甲基硅烷促进的碘的羟基取代,以及相关的醇脱保护步骤(甲基醚的区域选择性裂解)。结果可能是由于intermediate中间体的裂解而产生的环状an盐或碘化物。特别优选仲和叔醇或醚以及脂族而不是芳族硫化物官能团的环化。该反应的跨环形形式导致7元至5元环状硫化物的容易的环收缩。
    DOI:
    10.1016/0040-4020(96)00229-3
  • 作为产物:
    参考文献:
    名称:
    Hurd; Wilkinson, Journal of the American Chemical Society, 1949, vol. 71, p. 3431
    摘要:
    DOI:
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文献信息

  • Et<sub>3</sub>B Induced Radical Addition of Thiols to Acetylenes
    作者:Yoshifumi Ichinose、Kuni Wakamatsu、Kyoko Nozaki、Jean-Luc Birbaum、Koichiro Oshima、Kiitiro Utimoto
    DOI:10.1246/cl.1987.1647
    日期:1987.8.5
    Thiols added easily to acetylenic compounds in the presence of Et3B to give alkenyl sulfides in good yields. The reaction of acetylenes with 3-methyl-2-buten-1-thio1 gave dihydro-thiophene derivatives in one pot.
    在 Et3B 存在下,硫醇很容易添加到乙炔化合物中,从而以良好的收率得到烯基硫化物。乙炔与 3-methyl-2-buten-1-thio1 的反应在一锅中得到二氢噻吩衍生物。
  • Method for producing anellated tetrahydro-{1h}-triazoles
    申请人:——
    公开号:US20040097728A1
    公开(公告)日:2004-05-20
    The present invention relates to a process for preparing fused tetrahydro-[ 1 H]-triazoles of the formula I 1 where the variables R a , Z, Z 1 , X, W, n and Q are as defined in claim 1, by cyclization of compounds of the formula II 2 where R is C(X)OR 2 or C(X)SR 2 , where X is oxygen or sulfur, and R 2 is as defined in claim 1, in the presence of a base. The invention also relates to compounds of the formula I where W is sulfur if Z is a methylene group optionally substituted by R a , and furthermore to compounds of the formula I where Q is a benzoxazole or benzothiazole radical, and to the use of these compounds as herbicides.
    本发明涉及一种制备公式I的熔融四氢咪唑的方法,其中变量Ra、Z、Z1、X、W、n和Q如权利要求1中定义,通过在碱存在下,将公式II的化合物环化得到,其中R为C(X)OR2或C(X)SR2,其中X为氧或硫,R2如权利要求1中定义。该发明还涉及公式I的化合物,其中如果Z是可选地由Ra取代的亚甲基基团,则W为硫,此外还涉及公式I的化合物,其中Q为苯并噁唑或苯并噻唑基团,并将这些化合物用作除草剂。
  • Pyrimidine nucleoside derivatives having anti-tumor activity, their preparation and use
    申请人:Sankyo Company Limited
    公开号:EP0536936A1
    公开(公告)日:1993-04-14
    Compounds of formula (I): [in which: R¹, R² and R³ are the same or different and each represents a hydrogen atom, an optionally substituted alkanoyl group or an alkenylcarbonyl group, provided that at least one of R¹, R² and R³ represents an unsubstituted alkanoyl group having from 5 to 24 carbon atoms, said substituted alkanoyl group or said alkenylcarbonyl group; and one of R⁴ and R⁵ represents a hydrogen atom and the other represents a cyano group]; have valuable anti-tumour activity.
    式子(I)的化合物:[其中:R¹、R²和R³相同或不同,每个代表氢原子、可选取代的脂肪酰基团或烯基羰基团,前提是至少有一个R¹、R²和R³代表有5到24个碳原子的未取代脂肪酰基团,或者是所述取代的脂肪酰基团或所述烯基羰基团;R⁴和R⁵中的一个代表氢原子,另一个代表氰基],具有有价值的抗肿瘤活性。
  • [DE] 1-AMINO-3-BENZYLURACILE<br/>[EN] 1-AMINO-3-BENZYLURACILS<br/>[FR] 1-AMINO-3-BENZYLURACILES
    申请人:BASF AKTIENGESELLSCHAFT
    公开号:WO1997001543A1
    公开(公告)日:1997-01-16
    (DE) 1-Amino-3-benzyluracile (I) und deren Salze (R1 = Halogen; R2, R3 = H, CN, SCN, Halogen, C1-C4-Halogenalkyl, C1-C4-Halogenalkoxy, C1-C4-Halogenalkylthio; R4 = R3 + C1-C4-Alkyl, C1-C4-Alkoxy, C1-C6-Alkyl-NH-CO-; R5 = H, CN, NO2, OH, Halogen, gegebenenfalls substituiertes NH2, gegebenenfalls subst. C1-C6-Halogenalkoxy, C1-C6-Halogenalkylthio, C1-C6-Alkoxy, C1-C6-Alkylthio, C3-C8-Cycloalkoxy, C3-C8-Cycloalkylthio, C3-C6-Alkenyloxy, C3-C6-Alkenylthio, C3-C6-Alkinyloxy, C3-C6-Alkinylthio, C1-C6-Alkyl-COO-, C1-C6-Alkyl-COS-, C3-C6-Alkenyl-COO-, C3-C6-Alkenyl-COS-, C3-C6-Alkinyl-COO-, C3-C6-Alkinyl-COS-, C1-C6-Alkyl-SO2-O- oder C1-C6-Alkyl-SO2-; R6 = 1) H, OH, SH, Halogen, C1-C6-Halogenalkoxy, C1-C6-Halogenalkylthio, C1-C6-Alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-Alkyliminooxy-CO-, 2) gegebenenfalls subst. C1-C6-Alkoxy, C1-C6-Alkylthio, C3-C8-Cycloalkoxy, C3-C8-Cycloalkylthio, C2-C6-Alkenyloxy, C2-C6-Alkenylthio, C2-C6-Alkinyloxy, C2-C6-Alkinylthio, C1-C6-Alkyl-COO-, C2-C6-Alkyl-COS-, C1-C6-Alkoxy-COO-, C2-C6-Alkenyl-COO-, C2-C6-Alkenyl-COS-, C2-C6-Alkinyl-COO-, C2-C6-Alkinyl-COS-, C1-C6-Alkyl-SO2-O-, C1-C6-Alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, gegebenenfalls subst. -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12) (Z2R13)-SR19, -C(Z1R12) (Z2R13)-N(R23)R24, gegebenenfalls substituiertes Amino oder -CONH2, Azaheterocyclyl, -CO-Azaheterocyclyl, (N + O oder N + O + S) Heterocyclyl enthaltende Kette); als Herbizide, zur Dessikation/Defoliation von Pflanzen.(EN) The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R1 = halogen; R2, R3 = H, CN, SCN, halogen, C1¿-C¿4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R4 = R3 + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R5 = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R6 = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, optionally substituted -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20,-C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants.(FR) L'invention concerne des 1-amino-3-benzyluraciles de la formule (I) et leurs sels. Dans ladite formule (I), R1 représente de l'halogène; R2, R3 représentent H, CN, SCN, halogène, halogénure d'alkyle C1-C4, halogénure d'alcoxy C1-C4, halogénure d'alkylthio C1-C4; R4 représente R3 + alkyle C1-C4, alcoxy C1-C4, alkyle C1-C6 -NH-CO-; R5 représente H, CN, NO2, OH, halogène, NH2 éventuellement substitué, halogénure d'alcoxy C1-C6 éventuellement substitué, halogénure d'alkylthio C1-C6, alcoxy C1-C6, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C3-C6, alcénylthio C3-C6, alkinyloxy C3-C6, alkinylthio C3-C6, alkyle C1-C6-COO-, alkyle C1-C6-COS-, alcényle C3-C6-COO-, alcényle C3-C6-COS-, alkinyle C3-C6-COO-, alkinyle C3-C6-COS-, alkyle C1-C6-SO2-O- ou alkyle C1-C6-SO2-; R6 représente 1) H, OH, SH, halogène, halogénure d'alcoxy C1-C6, halogénure d'alkylthio C1-C6, alkylthio C1-C6-(alkyle C1-C6) carbonyle, alkyliminooxy C1-C6-CO-, 2) alcoxy C1-C6 éventuellement substitué, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C2-C6, alcénylthio C2-C6, alkinyloxy C2-C6, alkinylthio C2-C6, alkyle C1-C6-COO-, alkyle C2-C6-COS, alcoxy C1-C6-COO-, alcényle C2-C6-COO-, alcényle C2-C6 -COS-, alkinyle C2-C6-COO-, alkinyle C2-C6 -COS-, alkyle C1-C6-SO2-O-, alkyle C1-C6-SO2-, 3) -CY-R11 Y = -O-, -S-, -NH- éventuellement substitué}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, amino éventuellement substitué ou -CONH2, azahétérocyclyle, -CO-azahétérocyclyle, ou une chaîne comprenant de un hétérocyclyle (N + O ou N + O + S). Ces composés chimiques peuvent être utilisés comme herbicides pour la dessication/défoliation des plantes.
    (DE)1-氨基-3-苯并嘧啶尿嘧啶(I)及其衍生物的盐类(R1 = 卤素;R2, R3 = H, CN, SCN, 卤素, C1-C4卤代烷基, C1-C4卤代烷氧基, C1-C4卤代烷硫基; R4 = R3 + C1-C4烷基, C1-C4烷氧基, C1-C6-NH-CO-烷基; R5 = H, CN, NO2, OH, 卤素, 可能是取代的NH2, 可能是取代的C1-C6卤代烷氧基, C1-C6卤代烷硫基, C1-C6烷氧基, C1-C6烷硫基, C3-C8环烷氧基, C3-C8环烷硫基, C3-C6烯基氧基, C3-C6烯基硫基, C3-C6炔基氧基, C3-C6炔基硫基, C1-C6烷基-COO-, C1-C6烷基-COS-, C3-C6烯基-COO-, C3-C6烯基-COS-, C3-C6炔基-COO-, C3-C6炔基-COS-, C1-C6烷基-SO2-O-或C1-C6烷基-SO2-; R6 = 1) H, OH, SH, 卤素, C1-C6卤代烷氧基, C1-C6卤代烷硫基, C1-C6烷硫基-(C1-C6烷基)羰基, C1-C6烷基亚胺氧基-CO-, 2) 可能是取代的C1-C6烷氧基, C1-C6烷硫基, C3-C8环烷氧基, C3-C8环烷硫基, C2-C6烯基氧基, C2-C6烯基硫基, C2-C6炔基氧基, C2-C6炔基硫基, C1-C6烷基-COO-, C2-C6烷基-COS-, C1-C6烷氧基-COO-, C2-C6烯基-COO-, C2-C6烯基-COS-, C2-C6炔基-COO-, C2-C6炔基-COS-, C1-C6烷基-SO2-O-, C1-C6烷基-SO2-, 3) -CY-R11 Y = -O-, -S-, 可能是取代的-NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C(*)(0)C-CO-NH-OR20, -C(*)(0)C-CO-N(R19)-OR20, -C(*)(0)C-CS-NH-OR20, -C(*)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C(*)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, 可能是取代的氨基或-CONH2, 含氮杂环基, -CO-含氮杂环基, 或包含(N + O或N + O + S)的杂环基链)。这些化合物可用作除草剂,用于植物的脱水/脱叶。 (EN)The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R1 = halogen; R2, R3 = H, CN, SCN, halogen, C1-C4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R4 = R3 + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R5 = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R6 = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, optionally substituted -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$(m)(0)C-CO-NH-OR20, -C$(m)(0)C-CO-N(R19)-OR20, -C$(m)(0)C-CS-NH-OR20, -C$(m)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$(m)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants. (FR)L'invention concerne des 1-amino-3-benzyluraciles de la formule (I) et leurs sels. Dans ladite formule (I), R1 représente de l'halogène; R2, R3 représentent H, CN, SCN, halogène, halogénure d'alkyle C1-C4, halogénure d'alcoxy C1-C4, halogénure d'alkylthio C1-C4; R4 représente R3 + alkyle C1-C4, alcoxy C1-C4, alkyle C1-C6 -NH-CO-; R5 Represents H, CN, NO2, OH, halogène, NH2 éventuellement substitué, halogénure d'alcoxy C1-C6 éventuellement substitué, halogénure d'alkylthio C1-C6, alcoxy C1-C6, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C3-C6, alcénylthio C3-C6, alkinyloxy C3-C6, alkinylthio C3-C6, alkyle C1-C6-COO-, alkyle C1-C6-COS-, alcényle C3-C6-COO-, alcényle C3-C6-COS-, alkinyle C3-C6-COO-, alkinyle C3-C6-COS-, alkyle C1-C6-SO2-O- ou alkyle C1-C6-SO2-; R6 représente 1) H, OH, SH, halogène, halogénure d'alcoxy C1-C6, halogénure d'alkylthio C1-C6, alkylthio C1-C6-(alkyle C1-C6) carbonyle, alkyliminooxy C1-C6-CO-, 2) alcoxy C1-C6 éventuellement substitué, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C2-C6, alcénylthio C2-C6, alkinyloxy C2-C6, alkinylthio C2-C6, alkyle C1-C6-COO-, alkyle C2-C6-COS, alcoxy C1-C6-COO-, alcényle C2-C6-COO-, alcényle C2-C6-COS-, alkinyle C2-C6-COO-, alkinyle C2-C6-COS-, alkyle C1-C6-SO2-O-, alkyle C1-C6-SO2-, 3) -CY-R11 Y = -O-, -S-, -NH- éventuellement substitué}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$(m)(0)C-CO-NH-OR20, -C$(m)(0)C-CO-N(R19)-OR20, -C$(m)(0)C-CS-NH-OR20, -C$(m)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$(m)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, amino éventuellement substitué ou -CONH2, azahétérocyclyle, -CO-azahétérocyclyle, ou une chaîne comprenant de un hétérocyclyle (N + O ou N + O + S). Ces composés chimiques peuvent être utilisés comme herbicides pour la dessication/défoliation des plantes.
  • Functional sulfur-containing compounds.
    作者:A. R. Derzhinskii、L. D. Konyushkin、E. N. Prilezhaeva
    DOI:10.1007/bf00949956
    日期:1982.5
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