tributyl(thieno[3,2-b]furan-5-yl)stannane | 1173058-36-0

• 分子结构分类: 有机化合物
• 英文名称: tributyl(thieno[3,2-b]furan-5-yl)stannane
• 英文别名: 5-(tributylstannyl)thieno[3,2-b]furan
• CAS: 1173058-36-0
• 化学式: C₁₈H₃₀OSSn
• 分子量: 413.212
• InChiKey: YHBSMTPTLUIMRS-UHFFFAOYSA-N

物化性质

• 沸点：
  407.8±48.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.55
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  41.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-溴噻吩并[3,2-B]呋喃 、 tributyl(thieno[3,2-b]furan-5-yl)stannane 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 以52%的产率得到2,5'-bithieno[3,2-b]furan
  参考文献：
  名称：

  Regiochemical Effects of Furan Substitution on the Electronic Properties and Solid-State Structure of Partial Fused-Ring Oligothiophenes

  摘要：

  Oligomers containing the new fused-ring heterocyclic conjugated building block thieno[3,2-b]furan were synthesized, and the effects associated with furan ring substitution into fused-ring oligothiophenes on the electronic properties and solid-state structure were assessed. A series of four ring oligomers which vary in. the degree of furan ring substitution and the regiochemistry of placement were synthesized via Stille cross coupling and oxidative homocoupling strategies. The electronic properties of these oligomers were studied by UV-vis absorption and fluorescence spectroscopies. Substitution of furan rings at the terminal positions yields oligomers with a narrower HOMO-LUMO gap relative to the all-thiophene analogue 2,2'-bithieno[3,2-b]thiophene, and incorporation of furan rings at the interior positions results in oligomers with an increase in rigidity and a higher fluorescence quantum yield. Packing motifs of the oligomers were determined using single crystal X-ray diffraction. In contrast to the herringbone crystal packing observed for nonfused oligothiophenes, oligofurans, thiophene-furan hybrid oligomers, and the all-thiophene analogue 2,2'-bithieno[3,2-b]thiophene, all three regioisomers derived from the dimerization of thieno[3,2-b]furan arrange in a pi-stacked packing motif in the solid state.

  DOI：

  10.1021/jo301744s
• 作为产物：
  描述：

  thieno[3,2-b]furan 、 三丁基氯化锡 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 生成 tributyl(thieno[3,2-b]furan-5-yl)stannane
  参考文献：
  名称：

  Regiochemical Effects of Furan Substitution on the Electronic Properties and Solid-State Structure of Partial Fused-Ring Oligothiophenes

  摘要：

  Oligomers containing the new fused-ring heterocyclic conjugated building block thieno[3,2-b]furan were synthesized, and the effects associated with furan ring substitution into fused-ring oligothiophenes on the electronic properties and solid-state structure were assessed. A series of four ring oligomers which vary in. the degree of furan ring substitution and the regiochemistry of placement were synthesized via Stille cross coupling and oxidative homocoupling strategies. The electronic properties of these oligomers were studied by UV-vis absorption and fluorescence spectroscopies. Substitution of furan rings at the terminal positions yields oligomers with a narrower HOMO-LUMO gap relative to the all-thiophene analogue 2,2'-bithieno[3,2-b]thiophene, and incorporation of furan rings at the interior positions results in oligomers with an increase in rigidity and a higher fluorescence quantum yield. Packing motifs of the oligomers were determined using single crystal X-ray diffraction. In contrast to the herringbone crystal packing observed for nonfused oligothiophenes, oligofurans, thiophene-furan hybrid oligomers, and the all-thiophene analogue 2,2'-bithieno[3,2-b]thiophene, all three regioisomers derived from the dimerization of thieno[3,2-b]furan arrange in a pi-stacked packing motif in the solid state.

  DOI：

  10.1021/jo301744s

文献信息

• Facile and Scalable Synthesis of the Fused-Ring Heterocycles Thieno[3,2-<i>b</i>]thiophene and Thieno[3,2-<i>b</i>]furan
  作者：John T. Henssler、Adam J. Matzger

  DOI：10.1021/ol9010745

  日期：2009.7.16

  An optimized synthetic methodology which allows for efficient and scalable access to the important fused-ring heterocycle thieno[3,2-b]thiophene and the first reported isolation of thieno[3,2-b]furan Is presented. The properties of thieno[3,2-b]furan were assessed through a detailed analysis of the NMR data and an investigation of the chemical reactivity. Thieno[3,2-b]furan is chemically robust and offers good selectivity toward functionalization at the 2-position via bromination and the 5-position via deprotonation.