9,10-二(4-溴甲基苯基)-菲 | 1010812-15-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 中文名称: 9,10-二(4-溴甲基苯基)-菲
• 英文名称: 9,10-di(4-bromomethylphenyl)-phenanthrene
• 英文别名: 9,10-Bis[4-(bromomethyl)phenyl]phenanthrene；9,10-bis[4-(bromomethyl)phenyl]phenanthrene
• CAS: 1010812-15-3
• 化学式: C₂₈H₂₀Br₂
• 分子量: 516.275
• InChiKey: RDNXCLWTJSKGJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9,10-二(4-溴甲基苯基)-菲 、 亚磷酸三乙酯 反应 7.0h， 以91.2%的产率得到9,10-di[4-(O,O-diethylphosphonomethyl)phenyl]-phenanthrene
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z
• 作为产物：
  描述：

  9,10-di-p-tolylphenanthrene 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 以53.5%的产率得到9,10-二(4-溴甲基苯基)-菲
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES EMPLOYANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011136482A1

  公开（公告）日：2011-11-03

  Provided are novel organic electroluminescent compounds and an organic electroluminescent device using the same. Since the organic electroluminescent compound exhibits good luminous efficiency in blue color and excellent life property of the material, it may be used to manufacture OLED devices having very superior operation life.
• Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s
  作者：Bo He、Hongkun Tian、Yanhou Geng、Fosong Wang、Klaus Müllen

  DOI：10.1021/ol702873z

  日期：2008.3.1

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.