(8-methacryloyloxy-2-oxaoctyl)-15-crown-5 | 503003-36-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: (8-methacryloyloxy-2-oxaoctyl)-15-crown-5
• 英文别名: 6-(1,4,7,10,13-Pentaoxacyclopentadec-2-ylmethoxy)hexyl 2-methylprop-2-enoate；6-(1,4,7,10,13-pentaoxacyclopentadec-2-ylmethoxy)hexyl 2-methylprop-2-enoate
• CAS: 503003-36-9
• 化学式: C₂₁H₃₈O₈
• 分子量: 418.528
• InChiKey: GEYXKXXWTGNXGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  81.7
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-羟甲基-15-冠-5 在 盐酸 、 thallium (I) ethoxide 、 三乙胺 作用下， 以 甲醇 、 乙醚 、 乙腈 为溶剂， 反应 30.08h， 生成 (8-methacryloyloxy-2-oxaoctyl)-15-crown-5
  参考文献：
  名称：

  Efficient Fixation of Carbon Dioxide into Poly(glycidyl methacrylate) Containing Pendant Crown Ether

  摘要：

  The copolymers (CP1-CP4) of glycidyl methacrylate (GMA) and methacrylate derivatives bearing 15-crown-5-ether (1-4) with M-n of 9100-12 300 were prepared under radical conditions, and they were employed for the fixation Of CO2 using NaI as a catalyst in nitromethane. The conversion of oxirane groups to carbonate by fixation Of CO2 increased remarkably compared to the homopolymer of GMA. In the case of CP1, the reaction proceeded readily even in a dilute reaction system. Poly-GMA could convert into the corresponding polymer containing a carbonate moiety by the introduction of crown ether into the polymer backbone.

  DOI：

  10.1021/ma021316p

文献信息

• Efficient Fixation of Carbon Dioxide into Poly(glycidyl methacrylate) Containing Pendant Crown Ether
  作者：Shin-ichi Yamamoto、Osamu Moriya、Takeshi Endo

  DOI：10.1021/ma021316p

  日期：2003.3.1

  The copolymers (CP1-CP4) of glycidyl methacrylate (GMA) and methacrylate derivatives bearing 15-crown-5-ether (1-4) with M-n of 9100-12 300 were prepared under radical conditions, and they were employed for the fixation Of CO2 using NaI as a catalyst in nitromethane. The conversion of oxirane groups to carbonate by fixation Of CO2 increased remarkably compared to the homopolymer of GMA. In the case of CP1, the reaction proceeded readily even in a dilute reaction system. Poly-GMA could convert into the corresponding polymer containing a carbonate moiety by the introduction of crown ether into the polymer backbone.