2,7-二溴-9,9-双(4-正己基苯基)芴 | 1059179-65-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,7-二溴-9,9-双(4-正己基苯基)芴
• 中文别名: 2,7-二溴-9,9-双(4-己基苯基)-9H-芴
• 英文名称: 2,7-dibromo-9,9-bis(4-hexylphenyl)-9H-fluorene
• 英文别名: 2,7-dibromo-9,9-bis(4-n-hexylphenyl)fluorene；2,7-dibromo-9,9-bis(4-hexylphenyl)fluorene
• CAS: 1059179-65-5
• 化学式: C₃₇H₄₀Br₂
• 分子量: 644.533
• InChiKey: VEVPFFNTCVXORC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  39
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,7-二溴-9,9-双(4-正己基苯基)芴 在 正丁基锂 、 杜醌 、 copper(l) cyanide 作用下， 以 四氢呋喃 为溶剂， 反应 25.5h， 以4.95 g的产率得到
  参考文献：
  名称：

  신규한 화합물 및 이를 이용한 유기발광 소자

  摘要：

  本发明提供了一种新的化合物以及利用该化合物制备的有机发光器件。

  公开号：

  KR20200043756A
• 作为产物：
  描述：

  1-(4-溴苯基)己烷 在 正丁基锂 、 三氟化硼乙醚 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 5.5h， 生成 2,7-二溴-9,9-双(4-正己基苯基)芴
  参考文献：
  名称：

  신규한 화합물 및 이를 이용한 유기발광 소자

  摘要：

  本发明提供了一种新的化合物以及利用该化合物制备的有机发光器件。

  公开号：

  KR20200043755A

文献信息

• COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAID COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2520576A1

  公开（公告）日：2012-11-07

  The present invention provides a novel compound having an excellent property to inject a hole into a device such as an organic EL device. More specifically, the present invention provides a compound comprising a residue obtained by removing at least one hydrogen atom from a structure represented by the following formula (1): wherein each R1 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R1s may be the same or different; each R2 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R2s may be the same or different; each R4 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R4s may be the same or different; each R15 represents an alkyl group or the like, each of such groups optionally having a substituent; where there are a plurality of R15, they may be the same or different; each e represents an integer of from 0 to 6; and the e's may be the same or different.

  本发明提供了一种新型化合物，具有优良的性能，可以向有机EL器件等设备注入孔。更具体地，本发明提供了一种化合物，其包括通过从以下式（1）所表示的结构中去除至少一个氢原子而获得的残基：其中每个R1代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R1可以相同也可以不同；每个R2代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R2可以相同也可以不同；每个R4代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R4可以相同也可以不同；每个R15代表烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；如果有多个R15，则它们可以相同也可以不同；每个e表示从0到6的整数；e可以相同也可以不同。
• HIGH-MOLECULAR COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Sumitom Chemical Company, Limited

  公开号：US20150155495A1

  公开（公告）日：2015-06-04

  A polymer compound has a repeating unit represented by general formula (1): wherein R 1a represents an alkyl group, an aryl group, a monovalent aromatic heterocyclic group or an aralkyl group, each possibly substituted and the same or different; and X 1a represents a group selected from formulae (1a) to (1c).] wherein R 1c represents an aryl group or a monovalent aromatic heterocyclic group, possibly substituted; and R 1d to R 1f represent each independently an alkyl group, an aryl group, a monovalent aromatic heterocyclic group, an alkoxy group, an aryloxy group, an aralkyl group, an arylalkoxy group, a substituted amino group, a substituted carbonyl group, a substituted carboxyl group, a fluorine atom or a cyano group; and the pairs R 1d and R 1e , R 1f and R 1g , R 1d and R 1f , and R 1e and R 1g may be mutually linked to form a ring together with a carbon atom to which they are linked.

  一种聚合物化合物具有由通式（1）表示的重复单元，其中R1表示一个烷基、芳基、一价芳香杂环基或芳基烷基，每个可能被取代且相同或不同；X1表示从式（1a）到（1c）中选择的基团，其中R1c表示芳基或一价芳香杂环基，可能被取代；R1d到R1f分别独立地表示烷基、芳基、一价芳香杂环基、烷氧基、芳氧基、芳基烷基、芳基烷氧基、取代氨基、取代羰基、取代羧基、氟原子或氰基；并且R1d和R1e、R1f和R1g、R1d和R1f以及R1e和R1g这些配对可能相互连接，与它们连接的碳原子一起形成环。
• POLYMER COMPOUND AND METHOD FOR PRODUCING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20120217445A1

  公开（公告）日：2012-08-30

  A polymer compound comprising a first constitutional unit represented by formula (1), a second constitutional unit represented by formula (2), and at least one constitutional unit selected from the group consisting of a third constitutional unit represented by formula (3) and a fourth constitutional unit represented by formula (4).

  一种聚合物化合物，包括第一构成单元，其由式（1）表示，第二构成单元，其由式（2）表示，以及至少选择自由式（3）表示的第三构成单元和自由式（4）表示的第四构成单元中的一种构成单元。
• METAL COMPLEX, COMPOSITION COMPRISING SAME AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Ikeda Tomiki

  公开号：US20120298932A1

  公开（公告）日：2012-11-29

  The invention provides a metal complex having a structure represented by the following formula (1): wherein M represents a metal atom such as copper; C 1 and C 2 are each an sp3 carbon atom; A 1 -A 4 each independently represent hydrogen, etc; this is with the proviso that A 1 and A 3 may bond together to form a C4 or greater alkylene group and form a ring together with C 1 and C 2 ; the alkylene group may be optionally substituted; R 0 -R 7 each independently represent hydrogen, etc; Z represents a monovalent monodentate ligand, and p is the number of monodentate ligands, represented by (“valency of central metal atom M” −2).

  该发明提供了一种具有以下式(1)所表示结构的金属配合物：其中M表示金属原子，例如铜；C1和C2分别是sp3碳原子；A1-A4分别独立地表示氢等；但是，A1和A3可以结合形成C4或更大的烷基基团，并与C1和C2一起形成环；烷基基团可以选择性地被取代；R0-R7独立地表示氢等；Z表示单价单齿配体，p是单齿配体的数量，由(“中心金属原子M的价-2”)表示。
• HIGH MOLECULAR COMPOUND, METHOD FOR PRODUCING SAME, AND LIGHT-EMITTING ELEMENT
  申请人：Goto Osamu

  公开号：US20130248778A1

  公开（公告）日：2013-09-26

  A polymer compound is provided for achieving satisfactory brightness even at a low driving voltage when applied to a light-emitting device. A preferred embodiment includes multiple first groups and a block (A) having a structure in which the first groups are linked by a second group represented by formula (0-0), and includes at least one of a group represented by formula (0-1) or a group represented by formula (0-2) as the first group; wherein Ar 0 represents an optionally substituted arylene group or divalent aromatic heterocyclic group having a structure different from the first group; n represents an average chain length of Ar 0 and equals 1.0 to 8.0; and X 11 to X 16 and X 21 to X 25 each represent a carbon atom or a nitrogen atom, where two or three of X 11 to X 16 are a nitrogen atom and three of X 21 to X 25 are a nitrogen atom.

  提供了一种聚合物化合物，可在低驱动电压下应用于发光装置，以实现令人满意的亮度。首选实施例包括多个第一组和一个具有结构的块(A)，其中第一组由由公式(0-0)表示的第二组连接，并且至少包括由公式(0-1)或公式(0-2)表示的一组作为第一组;其中Ar0表示结构不同于第一组的可选取代芳基或二价芳香杂环基；n表示Ar0的平均链长，等于1.0至8.0；X11到X16和X21到X25分别表示碳原子或氮原子，其中X11到X16中的两个或三个为氮原子，X21到X25中的三个为氮原子。