(1R,6S)-10,10-dibromotricyclo[4.3.1.01,6]deca-2,4-diene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: (1R,6S)-10,10-dibromotricyclo[4.3.1.01,6]deca-2,4-diene
• 化学式: C₁₀H₁₀Br₂
• 分子量: 289.997
• InChiKey: AWXSVSOXAHDYLU-DTORHVGOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 1,5-双(三甲硅烷基)五-1,4-二炔-3-酮 、 (1R,6S)-10,10-dibromotricyclo[4.3.1.01,6]deca-2,4-diene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以46%的产率得到
  参考文献：
  名称：

  Vinylidene to alkyne rearrangement to form polyynes: synthesis and photolysis of dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives

  摘要：

  Dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives were synthesized as precursors to generate dialkynylvinylidenes by extrusion of an aromatic fragment, indane. Photolysis of the trienes gave linear polyynes as the major products produced by rearrangement of the vinylidenes, together with the isomerization products having a methylenecycloheptatriene moiety. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01042-5
• 作为产物：
  描述：

  dibromo[4.3.1]propellene 在 pyridinium hydrobromide perbromide 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 吡啶 、 二氯甲烷 、 甲苯 为溶剂， 以35%的产率得到(1R,6S)-10,10-dibromotricyclo[4.3.1.01,6]deca-2,4-diene
  参考文献：
  名称：

  Vinylidene to alkyne rearrangement to form polyynes: synthesis and photolysis of dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives

  摘要：

  Dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives were synthesized as precursors to generate dialkynylvinylidenes by extrusion of an aromatic fragment, indane. Photolysis of the trienes gave linear polyynes as the major products produced by rearrangement of the vinylidenes, together with the isomerization products having a methylenecycloheptatriene moiety. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01042-5

文献信息

• Vinylidene to alkyne rearrangement to form polyynes: synthesis and photolysis of dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives
  作者：Yoshito Tobe、Naruhito Iwasa、Rui Umeda、Motohiro Sonoda

  DOI：10.1016/s0040-4039(01)01042-5

  日期：2001.8

  Dialkynylmethylenebicyclo[4.3.1]deca-1,3,5-triene derivatives were synthesized as precursors to generate dialkynylvinylidenes by extrusion of an aromatic fragment, indane. Photolysis of the trienes gave linear polyynes as the major products produced by rearrangement of the vinylidenes, together with the isomerization products having a methylenecycloheptatriene moiety. (C) 2001 Elsevier Science Ltd. All rights reserved.