[Cu(2,3,8,9-dibenzo-4,7-dimethyl-5,6-dihydro-1,10-phenanthroline)(OH)] | 946416-88-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Cu(2,3,8,9-dibenzo-4,7-dimethyl-5,6-dihydro-1,10-phenanthroline)(OH)]
• CAS: 946416-88-2
• 化学式: C₂₂H₁₉CuN₂O
• 分子量: 390.952
• InChiKey: QGUFAHDWFSLWIO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(I) oxide 、 乙醇 、 6,7-二氢-5,8-二甲基二苯并(b,j)(1,10)菲咯啉 以 乙醇 为溶剂， 生成 [Cu(2,3,8,9-dibenzo-4,7-dimethyl-5,6-dihydro-1,10-phenanthroline)(OH)]
  参考文献：
  名称：

  Mixed-ligand complex formation in the copper(I)-2,9-dimethyl-1,10-phenanthroline-3,3′-bonded biquinoline system according to 1H NMR data

  摘要：

  The reaction of the copper(I) 2,9-dimethyl-1,10-phenanthroline (neocuproine, DMP) complex with 2,3,8,9-dibenzo-4,7-dimethyl-5,6-dihydro-1,10-phenanthroline (cuprotest, DMQ) in a CD3OD solution has been studied by H-1 NMR spectroscopy. The substitution of DMQ for the DMP liqand in the inner coordination sphere of the Cu+ complex has been observed. A model of the process including the formation of a mixed-ligand complex, presumably of bridged structure, is proposed to describe the observed experimental dependences of integrated intensities of the NMR signals in the spectrum on the concentrations of the components of the solution.

  DOI：

  10.1134/s0036023607060150