2,2'-[氧基二(乙烷-2,1-二基氧基)]二乙基二乙酸酯 | 22790-12-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,2'-[氧基二(乙烷-2,1-二基氧基)]二乙基二乙酸酯
• 英文名称: bis-[2-(2-acetoxy-ethoxy)-ethyl]-ether
• 英文别名: Bis-[2-(2-acetoxy-aethoxy)-aethyl]-aether；2,2'-[oxybis(ethane-2,1-diyloxy)]bisethyl diacetate；tetraethylene glycol diacetate；(CH3CO2CH2CH2OCH2CH2)2O；2,2'-(Oxybis(ethane-2,1-diyloxy))bisethyl diacetate；2-[2-[2-(2-acetyloxyethoxy)ethoxy]ethoxy]ethyl acetate
• CAS: 22790-12-1
• 化学式: C₁₂H₂₂O₇
• mdl: MFCD00680003
• 分子量: 278.302
• InChiKey: DXYGJDUJLDXFOD-UHFFFAOYSA-N

物化性质

• 沸点：
  344 °C
• 密度：
  1.101±0.06 g/cm3(Predicted)
• 保留指数：
  1828;1829;1830;1831;1831;1832;1832;1833;1834;1834;1836;1836

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2,2'-[氧基二(乙烷-2,1-二基氧基)]二乙基二乙酸酯 在 fluorine 作用下， 生成 ((oxybis(1,1,2,2-tetrafluoroethane-2,1-diyl))bis(oxy))bis(1,1,2,2-tetrafluoroethane-2,1-diyl) bis(2,2,2-trifluoroacetate)
  参考文献：
  名称：

  WO2007/75804

  摘要：

  公开号：
• 作为产物：
  描述：

  环氧乙烷 、 溶剂黄146 生成 2,2'-[氧基二(乙烷-2,1-二基氧基)]二乙基二乙酸酯
  参考文献：
  名称：

  Wurtz, Annales de Chimie (Cachan, France), 1863, vol. <3> 69, p. 321

  摘要：

  DOI：

文献信息

• Amide/Iminium Zwitterionic Catalysts for (Trans)esterification: Application in Biodiesel Synthesis
  作者：Ying-Pong Lam、Xinyan Wang、Fei Tan、Wing-Hin Ng、Ying-Lung Steve Tse、Ying-Yeung Yeung

  DOI：10.1021/acscatal.9b01959

  日期：2019.9.6

  organocatalysts based on an amide anion/iminium cation charge pair has been developed. The zwitterions are easily prepared by reacting aziridines with aminopyridines. They are catalytically applicable to transesterifications and dehydrative esterifications. Mechanistic studies reveal that the amide anion and iminium cation work synergistically in activating the reaction partners, with the iminium cationic

  已经开发了一类基于酰胺阴离子/亚胺阳离子电荷对的两性离子有机催化剂。两性离子易于通过使氮丙啶与氨基吡啶反应来制备。它们催化地适用于酯交换和脱水酯化。机理研究表明，酰胺阴离子和亚胺阳离子在活化反应伙伴方面具有协同作用，亚胺阳离子部分通过非经典氢键与羰基底物相互作用。该反应可在温和条件下用于大规模合成生物柴油。
• ZWITTERIONIC CATALYSTS FOR (TRANS)ESTERIFICATION: APPLICATION IN FLUOROINDOLE-DERIVATIVES AND BIODIESEL SYNTHESIS
  申请人：The Chinese University of Hong Kong

  公开号：US20210023539A1

  公开（公告）日：2021-01-28

  An amide/iminium zwitterion catalyst has a catalyst pocket size that promotes transesterification and dehydrative esterification. The amide/iminium zwitterions are easily prepared by reacting aziridines with aminopyridines. The reaction can be applied a wide variety of esterification processes including the large-scale synthesis of biodiesel. The amide/iminium zwitterions allow the avoidance of strongly basic or acidic condition and avoidance of metal contamination in the products. Reactions are carried out at ambient or only modestly elevated temperatures. The amide/iminium zwitterion catalyst is easily recycled and reactions proceed in high to quantitative yields.

  一种酰胺/亚胺兹维特离子催化剂具有促进酯交换和脱水酯化的催化剂口袋尺寸。酰胺/亚胺兹维特离子通过将环氮烷与氨基吡啶反应而容易制备。该反应可应用于各种酯化过程，包括生物柴油的大规模合成。酰胺/亚胺兹维特离子可避免强碱性或酸性条件，并避免产品中的金属污染。反应在常温或仅略微升温下进行。酰胺/亚胺兹维特离子催化剂易于回收，反应产率高且接近定量。
• Photoimageable compositions having improved chemical resistance and stripping ability
  申请人：Shipley Company LLC

  公开号：EP1008912A1

  公开（公告）日：2000-06-14

  A negative-acting photoimageable composition useful as a primary imaging resist in the manufacture of printed circuit boards comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which the binder polymer has an anhydride functional backbone half-esterified with a meth(acrylate) functional hydroxy-terminated oligomer, wherein the meth(acrylate) functionality is separated from the half-ester linkage by at least two alkoxylate groups and at least one ring opened lactone group for improved stripping ability in strong alkaline aqueous stripping solutions, while maintaining good chemical resistance to other processing chemicals, such as alkaline developing solutions, acid etching solutions, and acid plating baths.

  一种可负作用光成像组合物，可用作印刷电路板制造过程中的主成像抗蚀剂，该组合物由酸官能团粘合剂聚合物、可光聚合组分和光引发剂化学体系组成，其中粘合剂聚合物具有与甲基（丙烯酸酯）官能团羟基封端低聚物半酯化的酸酐官能团骨架、其中甲基丙烯酸酯官能团通过至少两个烷氧基官能团和至少一个开环内酯官能团与半酯连接分开，以提高在强碱性水性剥离溶液中的剥离能力，同时保持对其他加工化学品（如碱性显影液、酸性蚀刻溶液和酸性电镀液）的良好耐化学性。
• Photoimageable compositions having improved stripping ability and resolution
  申请人：Shipley Company LLC

  公开号：EP1008910A1

  公开（公告）日：2000-06-14

  A negative-acting photoimageable composition useful as a primary imaging resist in the manufacture of printed circuit boards comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which all or a portion of the photopolymerizable component comprises a (meth)acrylate functional urethane oligomer, wherein the (meth)acrylate functionality is separated from the urethane linkage by at least two alkylene oxide groups and at least one ring-opened lactone group for improved flexibility, tenting strength, fine line adhesion, developer scumming, coupled with unexpectedly improved resistance to processing chemicals, such as alkaline developing solutions, acid etching solutions, and acid plating baths, and stripping ability in strong alkaline aqueous stripping solutions. The acid-functional binder polymer has a low molecular weight and does not contain styrene, contributing to stripping ability and improved resolution.

  一种可负作用光成像组合物，可用作印刷电路板制造中的主成像抗蚀剂，该组合物包括酸官能团粘合剂聚合物、可光聚合组分和光引发剂化学体系，其中可光聚合组分的全部或部分包括(甲基)丙烯酸酯官能团聚氨酯低聚物、其中，(甲基)丙烯酸酯官能团通过至少两个环氧亚烷基和至少一个开环内酯基团与氨基甲酸乙酯链节分离，以改善柔韧性、抗张力、细线附着力、显影剂浮渣性，并意外地改善对碱性显影溶液、酸蚀刻溶液和酸电镀浴等加工化学品的耐受性，以及在强碱性水性剥离溶液中的剥离能力。酸功能粘合剂聚合物分子量低，不含苯乙烯，有助于提高剥离能力和分辨率。
• Photoimageable compositions having improved flexibility and stripping ability
  申请人：Shipley Company LLC

  公开号：EP1008911A1

  公开（公告）日：2000-06-14

  A negative-acting photoimageable composition useful as a primary imaging resist in the manufacture of printed circuit boards comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which all or a portion of the photopolymerizable component comprises a (meth)acrylate functional urethane oligomer, wherein the (meth)acrylate functionality is separated from the urethane linkage by at least two alkylene oxide groups and at least one ring-opened lactone group for improved flexibility, tenting strength, fine line adhesion, developer scumming, coupled with unexpectedly improved resistance to processing chemicals, such as alkaline developing solutions, acid etching solutions, and acid plating baths, and stripping ability in strong alkaline aqueous stripping solutions.

  一种可负作用光成像组合物，可用作印刷电路板制造中的主成像抗蚀剂，该组合物包括酸官能团粘合剂聚合物、可光聚合组分和光引发剂化学体系，其中可光聚合组分的全部或部分包括(甲基)丙烯酸酯官能团聚氨酯低聚物、其中，(甲基)丙烯酸酯官能团通过至少两个环氧亚烷基和至少一个开环内酯基团与聚氨酯链节分离，从而提高了柔韧性、抗张力、细线附着力、显影剂浮渣性，并意外地提高了对加工化学品（如碱性显影溶液、酸蚀刻溶液和酸电镀浴）的耐受性，以及在强碱性水性剥离溶液中的剥离能力。