[3,5-Bis[[3,5-bis[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenoxy]methyl]phenyl] hexadecane-1-sulfonate | 234096-73-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: [3,5-Bis[[3,5-bis[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenoxy]methyl]phenyl] hexadecane-1-sulfonate
• CAS: 234096-73-2
• 化学式: C₉₂H₁₁₀N₄O₁₃S
• 分子量: 1511.97
• InChiKey: NXPBBWYQHIGQAT-UHFFFAOYSA-N

物化性质

• 密度：
  1.200±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  21.1
• 重原子数：
  110
• 可旋转键数：
  39
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  188
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  [3,5-Bis[[3,5-bis[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenoxy]methyl]phenyl] hexadecane-1-sulfonate 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以91%的产率得到7-[[3-[[3-[[3,5-Bis[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenoxy]methyl]-5-hydroxyphenyl]methoxy]-5-[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenyl]methyl-ethylamino]-4,6-dimethylchromen-2-one
  参考文献：
  名称：

  新型聚合构造树枝状聚合物的光收集和能量转移。

  摘要：

  通过将相互作用的激光染料附着到树枝状大分子的链端和焦点，可以有效地将树枝状大分子的大外围天线（参见左图）收集的能量直接漏到中央荧光芯上（图左）在中间）的过程中不涉及树枝状大分子内部骨架。然后，能量从纤芯以窄带荧光辐射的形式发出（右图）。

  DOI：

  10.1002/(sici)1521-3773(19990517)38:10<1422::aid-anie1422>3.0.co;2-v
• 作为产物：
  描述：

  香豆素 2 、 [3,5-Bis[[3,5-bis(bromomethyl)phenoxy]methyl]phenyl] hexadecane-1-sulfonate 在 calcium hydride 作用下， 以 乙腈 为溶剂， 反应 85.0h， 以76%的产率得到[3,5-Bis[[3,5-bis[[(4,6-dimethyl-2-oxochromen-7-yl)-ethylamino]methyl]phenoxy]methyl]phenyl] hexadecane-1-sulfonate
  参考文献：
  名称：

  Modular Approach to the Accelerated Convergent Growth of Laser Dye-Labeled Poly(aryl ether) Dendrimers Using a Novel Hypermonomer

  摘要：

  The synthesis of novel dendrimers functionalized with laser dyes both at the periphery and at the core, along with all relevant model compounds necessary for accurate photophysical studies, is described. The utilized synthetic strategy involves a modular approach in which a variety of peripheral and core moieties can be placed an a dendritic structure bearing electrophilic peripheral groups and a nucleophilic core. Specifically, the target macromolecules required functionalization with the laser dyes coumarin 2 (periphery) and coumarin 343 (core) due to the possibility of energy transfer from the former to the latter dye. In addition, the preparation of a novel, highly soluble and reactive hypermonomer utilized in the rapid and efficient synthesis of high-generation dye-labeled dendrimers and model compounds is outlined.

  DOI：

  10.1021/jo990776m

文献信息

• Light Harvesting and Energy Transfer in Novel Convergently Constructed Dendrimers
  作者：Sylvain L. Gilat、Alex Adronov、Jean M. J. Fréchet

  DOI：10.1002/(sici)1521-3773(19990517)38:10<1422::aid-anie1422>3.0.co;2-v

  日期：1999.5.17

  focal point of a dendritic macromolecule it is possible to funnel energy harvested by the large peripheral antenna of the dendrimer (see picture on the left) efficiently and directly to the central fluorescent core (picture in the middle) by a process that does not involve the dendrimer inner backbone. The energy is then emitted as a narrow band of fluorescent radiation from the core (picture on the right)

  通过将相互作用的激光染料附着到树枝状大分子的链端和焦点，可以有效地将树枝状大分子的大外围天线（参见左图）收集的能量直接漏到中央荧光芯上（图左）在中间）的过程中不涉及树枝状大分子内部骨架。然后，能量从纤芯以窄带荧光辐射的形式发出（右图）。
• Modular Approach to the Accelerated Convergent Growth of Laser Dye-Labeled Poly(aryl ether) Dendrimers Using a Novel Hypermonomer
  作者：Sylvain L. Gilat、Alex Adronov、Jean M. J. Fréchet

  DOI：10.1021/jo990776m

  日期：1999.10.1

  The synthesis of novel dendrimers functionalized with laser dyes both at the periphery and at the core, along with all relevant model compounds necessary for accurate photophysical studies, is described. The utilized synthetic strategy involves a modular approach in which a variety of peripheral and core moieties can be placed an a dendritic structure bearing electrophilic peripheral groups and a nucleophilic core. Specifically, the target macromolecules required functionalization with the laser dyes coumarin 2 (periphery) and coumarin 343 (core) due to the possibility of energy transfer from the former to the latter dye. In addition, the preparation of a novel, highly soluble and reactive hypermonomer utilized in the rapid and efficient synthesis of high-generation dye-labeled dendrimers and model compounds is outlined.