1-methoxy-4-(2-phenoxy-ethoxy)-benzene | 98183-24-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-methoxy-4-(2-phenoxy-ethoxy)-benzene
• 英文别名: (β-Phenoxy-aethyl)-(4-methoxy-phenyl)-aether；Aethylenglykol-phenylaether-(4-methoxy-phenylaether)；1-Methoxy-4-(2-phenoxy-aethoxy)-benzol；1-Methoxy-4-(2-phenoxyethoxy)benzene
• CAS: 98183-24-5
• 化学式: C₁₅H₁₆O₃
• mdl: MFCD20760999
• 分子量: 244.29
• InChiKey: IYQIAVRZWFMVGZ-UHFFFAOYSA-N

物化性质

• 熔点：
  102-104 °C
• 沸点：
  385.2±22.0 °C(Predicted)
• 密度：
  1.098±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-苯氧乙基溴 在 氢氧化钾 作用下， 生成 1-methoxy-4-(2-phenoxy-ethoxy)-benzene
  参考文献：
  名称：

  Kohn; Benczer, Justus Liebigs Annalen der Chemie, 1923, vol. 433, p. 312

  摘要：

  DOI：

文献信息

• Electron-accepting compounds and color recording materials containing them
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0567314A1

  公开（公告）日：1993-10-27

  An electron-accepting compound is represented by the formula : wherein X represents a hydrogen or halogen atom, a hydroxyl, carboxyl, alkoxycarbonyl, alkyl, alkoxy, allyl, aryl, aralkyl or cycloalkyl group ; Ar represents an arylene group containing 2 to 5 benzene rings, or having said rings condensed thereto or a bisarylene group in which arylene groups are connected to each other via a divalent group ; and R represents a hydrogen atom or an alkyl, aralkyl or aryloxyalkyl. Preferably R is H ; and Ar is -C6H4-0-C6H4-. A novel recording material, heat- or pressure-sensitive, contains one of these compounds and at least one electron-providing colorless dye precursor, e.g. a fluoran, dispersed in a binder on a support. Color images are obtained without background fog or discoloration.

  一种电子接受化合物的化学式为 ： 其中，X 代表氢原子或卤素原子、羟基、羧基、烷氧基羰基、烷基、烷氧基、烯丙基、芳基、芳烷基或环烷基；Ar 代表含有 2 至 5 个苯环的芳烯基，或具有上述缩合环的芳烯基，或芳烯基通过二价基团相互连接的双芳基；R 代表氢原子或烷基、芳烷基或芳氧基烷基。R 最好是 H；Ar 是 -C6H4-0-C6H4-。 一种新型热敏或压敏记录材料含有上述化合物之一和至少一种提供电子的无色染料前体，例如氟烷，分散在支撑物上的粘合剂中。获得彩色图像时不会产生背景雾或变色。
• A phtalide compound and a near infrared absorber and a recording material each comprising the same compound
  申请人：YAMAMOTO CHEMICALS, INC.

  公开号：EP0664292A1

  公开（公告）日：1995-07-26

  A phthalide compound of general formula (I) and a near infrared absorber and a recording material each utilizing the phthalide compound are disclosed. wherein ring A represents a substituent group of the following formula    where R₁ represents hydrogen, alkyl, alkoxy or halogen; n represents an integer of 1-3; ring B represents a defined aromatic ring; R₂ represents alkyl or aryl; R₃ represents alkyl; R₄ and R₅ independently represent alkyl or unsubstituted or substituted phenyl; R₆ represents hydrogen, alkyl or alkoxy. The near infrared absorber and the recorded image on the recording material absorb strongly the near infrared region with no appreciable absorption in the visible region of the spectrum. The near infrared absorber is colorless or pale in color and yet highly capable of absorbing near infrared radiation. The recorded image on the recording material can hardly be read with the eye but can be read with the OCR. Moreover, the effect on the developed shade of any concomitant color former in a recording material is minimal.

  本发明公开了通式（I）的邻苯二甲酸盐化合物以及利用该邻苯二甲酸盐化合物的近红外吸收剂和记录材料。 其中环 A 代表下式的取代基团 其中 R₁ 代表氢、烷基、烷氧基或卤素；n 代表 1-3 的整数；环 B 代表确定的芳环；R₂ 代表烷基或芳基；R₃ 代表烷基；R₄ 和 R₅ 独立地代表烷基或未取代或取代的苯基；R₆ 代表氢、烷基或烷氧基。 近红外吸收体和记录材料上记录的图像对近红外区域有强烈的吸收，而对光谱的可见光区域没有明显的吸收。近红外吸收体是无色或浅色的，但吸收近红外辐射的能力很强。记录材料上记录的图像几乎无法用肉眼读取，但可以用 OCR 读取。此外，记录材料中的任何伴色前者对显影色调的影响微乎其微。
• THERMAL RECORDING MATERIAL AND NOVEL CRYSTAL OF BISPHENOL S DERIVATIVE
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP0913267A1

  公开（公告）日：1999-05-06

  A heat-sensitive recording material in which a heat-sensitive color-developing layer comprising, as the main components, a usually colorless or light-colored color former and a developer capable of developing the color former upon heating on a support, characterized by comprising, as the developer, crystals of 3,3'-diallyl-4,4'-dihydroxy-diphenyl sulfone which have DSC (Te) of at least 149°C and which are of a crystal form characterized by an X-ray diffraction pattern having peaks at least at diffraction angles (2θ) [°] of 7.2 and 22.0, obtained by an X-ray powder diffractometry using Cu-Kα rays. This heat-sensitive recording material is high in sensitivity, little in Discoloration of the ground in heat and moisture and excellent in image durability.

  一种热敏记录材料，其热敏显色层的主要成分包括通常为无色或浅色的显色剂和在支持物上加热后能使显色剂显色的显影剂，其特征在于包括、作为显影剂，3,3'-二烯丙基-4,4'-二羟基二苯砜的晶体，其 DSC（Te）至少为 149°C，其晶体形态的 X 射线衍射图的特征是至少在衍射角（2θ）[°]为 7.2 和 22.0 的 X 射线粉末衍射图。这种热敏记录材料灵敏度高，在高温和潮湿条件下地面变色小，图像耐久性好。
• HEAT-SENSITIVE RECORDING MATERIAL AND DIPHENYLSULFONE
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP3378666A1

  公开（公告）日：2018-09-26

  The content of compound(s) having a molecular weight of 650-670, preferably a molecular weight of 660, as measured by mass spectrometry, is reduced to 0.5 mass% or less in a heat-sensitive recording material comprising 3,3'-diallyl-4,4'-dihydroxy diphenylsulfone, or in a diphenylsulfone or a color-developing agent. Provided is, thereby, a heat-sensitive recording material, a color-developing agent, or a diphenylsulfone which cause less background fogging under moisture and heat conditions and which has excellent preservation stability of a colored image.

  在含有 3,3'-二烯丙基-4,4'-二羟基二苯砜的热敏记录材料中，或在二苯砜或显色剂中，经质谱法测量，分子量为 650-670 的化合物（最好分子量为 660）的含量降至 0.5 质量％或以下。因此，本发明提供了一种热敏记录材料、显色剂或二苯砜，它在湿热条件下产生的背景雾化较少，并且对彩色图像具有出色的保存稳定性。
• HEAT-SENSITIVE RECORDING MATERIAL
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP3395583A1

  公开（公告）日：2018-10-31

  To provide a heat-sensitive recording material which produce images with excellent resistance to water, while producing background with resistance to heat. A heat-sensitive recording material which is characterized by containing at least one compound represented by general formula (1) as a color-developing compound. wherein, R1-R5 each independently represents a hydrogen atom, a halogen atom, a nitro group, an amino group, an alkyl group, an alkoxy group, an aryloxy group, an alkylcarbonyloxy group, an arylcarbonyloxy group, an alkylcarbonylamino group, an arylcarbonylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, a monoalkylamino group, a dialkylamino group or an arylamino group.

  提供一种热敏记录材料，它能产生耐水性极佳的图像，同时产生耐热背景。一种热敏记录材料，其特征是含有至少一种由通式（1）代表的化合物作为显色化合物。 其中，R1-R5 各自独立地代表氢原子、卤素原子、硝基、氨基、烷基、烷氧基、芳氧基、烷基羰氧基、芳基羰氧基、烷基羰基氨基、芳基羰基氨基、烷基磺酰基氨基、芳基磺酰基氨基、单烷基氨基、二烷基氨基或芳基氨基。