2-[4-(3,6-Diphenyl-9H-carbazol-9-yl)phenyl]-3-phenylquinoxaline | 1333108-01-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2-[4-(3,6-Diphenyl-9H-carbazol-9-yl)phenyl]-3-phenylquinoxaline
• 英文别名: 3,6-diphenyl-9-[4-(3-phenylquinoxalin-2-yl)phenyl]carbazole
• CAS: 1333108-01-2
• 化学式: C₄₄H₂₉N₃
• 分子量: 599.734
• InChiKey: FLSDMRQSMQTSBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,6-二苯基咔唑 、 2-(4-bromophenyl)-3-phenylquinoxaline 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 水 、 xylene 为溶剂， 反应 6.0h， 以96%的产率得到2-[4-(3,6-Diphenyl-9H-carbazol-9-yl)phenyl]-3-phenylquinoxaline
  参考文献：
  名称：

  Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device

  摘要：

  提供一种新型有机金属配合物的目的是利用一种有机化合物作为配体，该有机化合物可以轻松合成各种衍生物，并且能够发射磷光。另一个目的是提供具有高耐热性的有机金属配合物。其他目的包括提供具有高发射效率的发光元件，以及提供具有降低功耗的发光装置、电子装置和照明装置。提供了一种包括以下一般式（G1）所代表的结构的有机金属配合物，以及使用包括以下一般式（G1）所代表的结构的有机金属配合物形成的发光元件、发光装置、电子装置和照明装置。

  公开号：

  US20110245495A1

文献信息

• [EN] METAL COMPLEXES WITH DIBENZO[F,H]QUINOXALINES<br/>[FR] COMPLEXES MÉTALLIQUES COMPRENANT DES DIBENZO[F,H]QUINOXALINES
  申请人：BASF SE

  公开号：WO2013104649A1

  公开（公告）日：2013-07-18

  This invention relates to electroluminescent metal complexes of the formula electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs). The metal complexes of formula (I) show high emission efficiency, excellent vaporizability, thermal stability, processing stability, high charge carrier mobilities, low turn-on voltage and high temperature stability of the emission color.

  该发明涉及公式为电致发光金属配合物的电子器件，包括金属配合物及其在电子器件中的应用，特别是有机发光二极管（OLEDs）。公式（I）的金属配合物显示出高发射效率、优异的蒸发性、热稳定性、加工稳定性、高载流子迁移率、低开启电压和发射颜色的高温稳定性。
• Quinoxaline derivative, and light-emitting element, light-emitting device, and electronic device including quinoxaline derivative
  申请人：Nomura Hiroko

  公开号：US20090072718A1

  公开（公告）日：2009-03-19

  An object of the present invention is to provide a quinoxaline derivative represented by a general formula (1). Ar 1 represents one of a substituted or unsubstituted biphenyl group, and a substituted or unsubstituted terphenyl group; Ar 2 represents one of a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, and a substituted or unsubstituted terphenyl group; α 1 represents an arylene group having 6 to 25 carbon atoms; and R 11 to R 15 are the same or different from one another, and each of them represents any one of a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 25 carbon atoms.

  本发明的一个目的是提供一种由通式（1）表示的喹喔啉衍生物。Ar1代表取代或未取代的联苯基团，以及取代或未取代的三苯基团；Ar2代表取代或未取代的苯基团，取代或未取代的联苯基团，以及取代或未取代的三苯基团；α1代表具有6到25个碳原子的芳基基团；R11到R15彼此相同或不同，并且它们中的每一个代表氢原子、具有1到4个碳原子的烷基基团，以及具有6到25个碳原子的取代或未取代芳基团。
• HETEROCYCLIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Kadoma Hiroshi

  公开号：US20110210316A1

  公开（公告）日：2011-09-01

  An object is to provide a novel heterocyclic compound which can be used for a light-emitting element, as a host material of a light-emitting layer in which a light-emitting substance is dispersed. Other objects are to provide a light-emitting element having low driving voltage, a light-emitting element having high current efficiency, and a light-emitting element having a long lifetime. Provided are a light-emitting element including a compound in which a dibenzo[f,h]quinoxaline ring and a hole-transport skeleton are bonded through an arylene group, and a light-emitting device, an electronic device, and a lighting device each using this light-emitting element. The heterocyclic compound represented by General Formula (G1) below is provided.

  本发明的目的是提供一种新颖的杂环化合物，可用作发光元件，作为发光物质分散的发光层的主体材料。另一个目的是提供具有低驱动电压、高电流效率和长寿命的发光元件。提供了一种包括通过芳基基团连接的二苯并[f，h]喹喔啉环和空穴传输骨架的化合物的发光元件，以及使用该发光元件的发光装置、电子装置和照明装置。提供了下述通式（G1）所表示的杂环化合物。
• Organometallic complex, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Inoue Hideko

  公开号：US09056883B2

  公开（公告）日：2015-06-16

  An object is to provide a novel organometallic complex capable of emitting phosphorescence by using, as a ligand, an organic compound with which a variety of derivatives can be easily synthesized. Another object is to provide an organometallic complex having high heat resistance. Other objects are to provide a light-emitting element having high emission efficiency and to provide a light-emitting device, an electronic device, and a lighting device having reduced power consumption. Provided are an organometallic complex including a structure represented by the following General Formula (G1), and a light-emitting element, a light-emitting device, an electronic device, and a lighting device formed using the organometallic complex including the structure represented by the following General Formula (G1).

  本发明的目的是提供一种新型有机金属配合物，其可以通过使用一种有机化合物作为配体来发射磷光，并且可以轻松合成多种衍生物。另一个目的是提供一种具有高耐热性的有机金属配合物。其他目的是提供一种具有高发射效率的发光元件，并提供使用包括以下通用公式（G1）所表示的结构的有机金属配合物形成的发光元件、发光装置、电子装置和照明装置。
• Light-Emitting Element and Lighting Device
  申请人：Semiconductor Energy Laboratory Co, Ltd.

  公开号：EP2366753A1

  公开（公告）日：2011-09-21

  To provide a light-emitting element whose power efficiency is improved and which emits light of natural color like light bulb color. In the light-emitting element, at least three light-emitting units are stacked. The emission spectrum of the light-emitting element has two peaks. One of the two peaks is obtained by combining spectra of light emitted from two light-emitting units. The peak is in the yellow to orange wavelength range and has a wavelength greater than or equal to 560 nm and less than 580 nm. Thus, a wavelength range of high luminosity can be used and the power efficiency can be improved. The color of light emitted from the light-emitting element is close to a blackbody locus in a chromaticity diagram, and light of natural color like light bulb color can be achieved.

  提供一种发光元件，它能提高电源效率，并能发出类似灯泡颜色的自然光。在该发光元件中，至少有三个发光单元叠加在一起。发光元件的发射光谱有两个峰值。其中一个峰值是由两个发光元件发出的光谱组合而成。峰值在黄色至橙色波长范围内，波长大于或等于 560 纳米，小于 580 纳米。因此，可以使用高亮度的波长范围，并提高功率效率。从发光元件发出的光的颜色接近色度图中的黑体位置，可实现类似灯泡颜色的自然色光。