14,15-Dimethoxy-5,8,21,24-tetraoxahexacyclo[16.8.0.02,11.04,9.012,17.020,25]hexacosa-1(26),2,4(9),10,12,14,16,18,20(25)-nonaene | 134025-15-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 14,15-Dimethoxy-5,8,21,24-tetraoxahexacyclo[16.8.0.02,11.04,9.012,17.020,25]hexacosa-1(26),2,4(9),10,12,14,16,18,20(25)-nonaene
• CAS: 134025-15-3
• 化学式: C₂₄H₂₀O₆
• 分子量: 404.419
• InChiKey: KTSZWHGQOWTOHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,4-苯并二恶烷 、 邻苯二甲醚 以 乙腈 为溶剂， 生成 2,3,6,7,10,11-六甲氧基三亚苯 、 2,3,6,7-tetramethoxy-11,12-dihydrotriphenyleno[2,3-b][1,4]dioxine 、 14,15-Dimethoxy-5,8,21,24-tetraoxahexacyclo[16.8.0.02,11.04,9.012,17.020,25]hexacosa-1(26),2,4(9),10,12,14,16,18,20(25)-nonaene 、 2,3,8,9,14,15-hexahydrotriphenyleno<2,3-b:6,7-b':10,11-b''>tris<1,4>-dioxin
  参考文献：
  名称：

  The anodic trimerization of aromatic orthodiethers: new developments

  摘要：

  While the anodic trimerization of veratrole (leading to hexamethoxytriphenylene) is now a very well known reaction, developments concerning either mixed electrolysis (mixture of two orthodiethers) and/or oxidation of dissymmetrical substrates have not been conducted so far. The presented method, often specific, allows the synthesis of a new palette of liquid crystal precursors.

  DOI：

  10.1016/s0040-4020(01)87068-x

文献信息

• The anodic trimerization of aromatic orthodiethers: new developments
  作者：Jean-Marc Chapuzet、Jacques Simonet

  DOI：10.1016/s0040-4020(01)87068-x

  日期：1991.1

  While the anodic trimerization of veratrole (leading to hexamethoxytriphenylene) is now a very well known reaction, developments concerning either mixed electrolysis (mixture of two orthodiethers) and/or oxidation of dissymmetrical substrates have not been conducted so far. The presented method, often specific, allows the synthesis of a new palette of liquid crystal precursors.