3-乙烯基环己烯氧化物 | 123366-20-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 中文名称: 3-乙烯基环己烯氧化物
• 英文名称: 3-vinylcyclohexene oxide
• 英文别名: 2-Ethenyl-7-oxabicyclo[4.1.0]heptane
• CAS: 123366-20-1
• 化学式: C₈H₁₂O
• 分子量: 124.183
• InChiKey: FDWQGNULGGFFDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-乙烯基环己烯氧化物 在 B 作用下， 生成 3-乙烯基环己烯
  参考文献：
  名称：

  硼原子与环氧化物的反应：产物氧化硼（BO）（A2.PI.）状态下的振动分布

  摘要：

  DOI：

  10.1021/j150664a019
• 作为产物：
  描述：

  3-乙烯基环己烯 在 氢氧化钾 、 potassium sulfate 、 potassium hydrogensulfate 、 oxone 作用下， 以 水 为溶剂， 反应 5.0h， 以21%的产率得到3-oxiranyl 1,2-cyclohexene oxide
  参考文献：
  名称：

  Epoxidation of alkenes with potassium hydrogen persulfate

  摘要：

  DOI：

  10.1021/jo00209a040

文献信息

• [EN] (METH)ACRYLOXY-CONTAINING TRISILOXANE, SILOXANE-CONTAINING POLYMERS AND BIOMEDICAL DEVICES THEREFROM<br/>[FR] TRISILOXANE CONTENANT UN (MÉTH)ACRYLOXY, POLYMÈRES CONTENANT UN SILOXANE ET DISPOSITIFS BIOMÉDICAUX LES CONTENANT
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2014123956A1

  公开（公告）日：2014-08-14

  There is provided a trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group, useful in making water absorbing silicone-hydrogel films for biomedical devices, such as contact lens, and a process for producing these monomers. This invention also provides for copolymers made from the trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group described herein.

  提供了一种三硅氧烷，其具有3-(甲基)丙烯氧基取代的(羟基环己基)乙基基团，可用于制备用于生物医疗器械（如隐形眼镜）的吸水硅烷凝胶膜，并提供了制备这些单体的方法。本发明还提供了由所述具有3-(甲基)丙烯氧基取代的(羟基环己基)乙基基团的三硅氧烷制成的共聚物。
• CURATIVES FOR EPOXY ADHESIVE COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100113643A1

  公开（公告）日：2010-05-06

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  该发明提供了包括新型酰氧基和N-酰基固化剂的环氧树脂和氧环烷组合物。使用该发明的固化剂可使胶粘剂组合物固化后的粘附性大大增加，并且与用其他类型的固化剂固化的树脂相比，其亲水性减少。此外，该发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• SYNTHESIS OF METAL COMPLEXES AND USES THEREOF
  申请人：Novomer, Inc.

  公开号：US20170225157A1

  公开（公告）日：2017-08-10

  The present disclosure provides novel methods of making aluminum complexes with utility for promoting epoxide carbonylation reactions. Methods include reacting neutral metal carbonyl compounds with alkylaluminum complexes.

  本公开提供了制备铝配合物的新方法，可用于促进环氧丙烯酸酯羰基化反应。方法包括将中性金属羰基化合物与烷基铝配合物反应。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。
• Sensitizer dyes for photoacid generating systems
  申请人：Waldman A. David

  公开号：US20060019197A1

  公开（公告）日：2006-01-26

  Photosensitizing dyes are often used in conjunction with a photoacid generator in holographic recording media. Conventional photosensitizing dyes typically are limited by having an appreciable absorption of light when used in a sufficient concentration, such that the intensity of light decreases significantly with penetration into a recording medium. The present invention discloses a number of new 5-alkynyl substituted napthacene photosensitizing dyes that have low extinction coefficients coupled with good sensitizing properties, such that the problems associated with the photosensitizing dyes absorbing light are significantly reduced.

  光敏染料通常与光酸发生剂一起在全息记录介质中使用。传统的光敏染料通常受到限制，因为在足够浓度下使用时，它们吸收光的程度相当高，导致光线穿透记录介质时光强度显著降低。本发明揭示了一些新的5-炔基取代萘并光敏染料，其消光系数低且具有良好的敏化性能，从而显著降低了与光敏染料吸收光有关的问题。