N-butyl-N-vinylacetamide | 13044-09-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-butyl-N-vinylacetamide
• 英文别名: N-butyl-N-ethenylacetamide
• CAS: 13044-09-2
• 化学式: C₈H₁₅NO
• 分子量: 141.213
• InChiKey: ZBOGIZPRKHYUDS-UHFFFAOYSA-N

物化性质

• 沸点：
  85-90 °C(Press: 10 Torr)
• 密度：
  0.882±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-butyl-N-vinylacetamide 在 五氯化磷 、 二氧化硫 作用下， 以 苯 为溶剂， 以30%的产率得到(3-butyl-2-chloro-3-azapenta-1,4-dienylene)bis
  参考文献：
  名称：

  Rozinov, V. G.; Izhboldina, L. P.; Donskikh, V. I., Journal of General Chemistry of the USSR, 1984, vol. 54, # 1, p. 197 - 198

  摘要：

  DOI：
• 作为产物：
  描述：

  poly(N-n-butylvinylamine) 、 乙酸酐 在 三乙胺 作用下， 以 苯 为溶剂， 以66%的产率得到N-butyl-N-vinylacetamide
  参考文献：
  名称：

  Aksenov, A. I.; Kondrat'ev, N. B.; Demidova, N. V., Journal of general chemistry of the USSR, 1987, vol. 57, p. 1457 - 1460

  摘要：

  DOI：

文献信息

• Intermolecular Carboamination of Unactivated Alkenes
  作者：Yu Zhang、Haidong Liu、Luning Tang、Hai-Jun Tang、Lu Wang、Chuan Zhu、Chao Feng

  DOI：10.1021/jacs.8b07023

  日期：2018.8.29

  Herein, we report the first example of group transfer radical addition of O-vinylhydroxylamine derivatives onto unactivated alkenes. By utilizing O-vinylhydroxylamine derivatives as both the N- and C-donors, this reaction enables intermolecular carboamination of unactivated alkenes in an atom economical fashion. As the process is initiated through N-radical addition followed by C-transfer, linear carboamination

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• Amino Alcohol Derivatives And Their Use As Renin Inhibitor
  申请人：Herold Peter

  公开号：US20090118281A1

  公开（公告）日：2009-05-07

  The application relates to novel amino alcohols of the general formula (I) where R, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 each have the definitions illustrated in detail in the description, to a process for their preparation and to the use of these compounds as medicines, in particular as renin inhibitors.

  该申请涉及一种新型氨基醇，其一般式为（I），其中R、R1、R2、R3、R4、R5和R6各自具有详细说明中所示的定义，以及其制备的方法和将这些化合物作为药物的用途，特别是作为肾素抑制剂。
• La-Catalyzed Decarbonylation of Formamides and Its Applications
  作者：Shaocheng Li、Thayalan Rajeshkumar、Jincheng Liu、Laurent Maron、Xigeng Zhou

  DOI：10.1021/acs.orglett.2c03981

  日期：2023.1.13

  Herein we report the first catalytic decarbonylation and decarbonylative hydroamination of formamides without using additives enabled by a redox-neutral rare earth catalyst. The protocol displays complete N-aryl/alkenyl formamide-selectivity, thus providing a wide variety of creative uses of the N-formylation and N-deformylation method and opening up new prospects for minimizing waste and controlling

  在这里，我们报告了甲酰胺的首次催化脱羰和脱羰加氢胺化，而不使用由氧化还原中性稀土催化剂启用的添加剂。该协议显示了完整的N-芳基/烯基甲酰胺选择性，从而提供了N-甲酰化和N-脱甲酰化方法的广泛创造性用途，并为最大限度地减少浪费和控制胺转化事件中所需的选择性开辟了新的前景。
• Polymeric binders for ceramic processing
  申请人：NALCO CHEMICAL COMPANY

  公开号：EP0648718A2

  公开（公告）日：1995-04-19

  A composition suitable for use as a binder of ceramic materials and a method for preparing a ceramic material which provides relatively greater green ceramic strength is disclosed. The improved binder contains a substantially hydrolyzed copolymer made from monomers having ester or amide functional groups, poly(vinyl amine), poly(vinyl formamide) or a copolymer of vinyl alcohol and vinyl amine. The binder is combined with an aqueous solution containing a ceramic powder to make a slurry, and the slurry is subsequently spray dried, pressed and heated to make a ceramic.

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• Liquid-absorbing material composition, molded product therefrom, process for preparing the same and use thereof
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0844006A1

  公开（公告）日：1998-05-27

  A liquid-absorbing material composition containing a crosslinking agent (component A), N-vinylcarboxamide copolymer (component B) having a functional group capable of crosslinking with the component A, water (component C), a water-soluble organic solvent (component D) and a plasticizer (component E), a molded liquid-absorbing material prepared from the composition, a method of manufacturing the molded liquid-absorbing material, and uses thereof are provided. The liquid-absorbing material composition has a high flowability, and gives a uniform continuous layer so that it can be directly molded readily into film- or sheet-shaped molded liquid-absorbing material without requiring secondary processing as in the case of conventional water-absorbing polymer. Use of the liquid-absorbing material composition allows manufacture in short time of molded products which are excellent in liquid-absorbing performance that can be utilized as a freshness retaining agent, a moisture-conditioning agent, an agricultural and horticultural water-retaining sheet, a soil improving agent, an anti-dewing agent, sanitary goods, a waste liquid solidifying material, a water preventing sheet, a water running preventing shielding material, a pharmaceutical, a medical tool, a humectant or desiccant.

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