4-amino-3,4'-dinitrodiphenyl sulfide | 127923-96-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 4-amino-3,4'-dinitrodiphenyl sulfide
• 英文别名: Benzenamine, 2-nitro-4-[(4-nitrophenyl)thio]-；2-nitro-4-(4-nitrophenyl)sulfanylaniline
• CAS: 127923-96-0
• 化学式: C₁₂H₉N₃O₄S
• 分子量: 291.287
• InChiKey: CCZYAADVWIVMMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-amino-3,4'-dinitrodiphenyl sulfide 在 三氯化铁 、 甲烷 、 一水合肼 作用下， 以 正丁醇 为溶剂， 生成 3,4,4'-triaminodiphenyl sulfide
  参考文献：
  名称：

  摘要：

  A procedure for preparation of 3,4,4'-triaminodiphenyl sulfide by reduction of 4-amino-3,4'-dinitrodiphenyl sulfide with hydrazine hydrate in butanol catalyzed by a mixture of iron(Ill) chloride and activated carbon was developed providing the product in no less than 80% yield with the main compound content no less than 93%.

  DOI：

  10.1023/a:1020993224642
• 作为产物：
  描述：

  2-硝基-4-硫氰基苯胺 、 对硝基氯苯 在 sodium hydroxide 、 PEG 400 作用下， 以 水 为溶剂， 生成 4-amino-3,4'-dinitrodiphenyl sulfide
  参考文献：
  名称：

  摘要：

  A method for preparing 4-amino-3,4'-dinitrodiphenyl sulfide is developed, based on the reaction of 2-nitro-4-thiocyanatoaniline with 4-nitrochlorobenzene in aqueous-alkaline medium in the presence of a phase-transfer catalyst (PEG 400 or Katamin AB).

  DOI：

  10.1023/a:1021638231873

文献信息

• Synthesis of 2-Amino-5(6)-(4-aminophenyl)benzimidazole Derivatives: II. Reaction of 2-Nitro-4-thiocyanatoaniline with 4-Nitrochlorobenzene
  作者：V. S. Pilyugin、Yu. E. Sapozhnikov、G. P. Shitov

  DOI：10.1023/b:rujo.0000003189.87809.53

  日期：2003.7

  The reaction of 2-nitro-4-thiocyanatoaniline with 4-nitrochlorobenzene in aqueous alkaline medium in the presence of phase-transfer catalyst at 95-100degreesC was studied with a view to obtain 4-amino-3,4'-dinitrodiphenyl sulfide. Optimal conditions for the synthesis and isolation of the product were found.
• XOXRYAKOV, YU. B.;AVRUTSKAYA, I. A.;PILYUGIN, V. S.;CHERNYSHEVA, T. V.;LE+
  作者：XOXRYAKOV, YU. B.、AVRUTSKAYA, I. A.、PILYUGIN, V. S.、CHERNYSHEVA, T. V.、LE+

  DOI：——

  日期：——
• XOXRYAKOV, YU. B.;AVRUTSKAYA, I. A.;KUCHEROV, S. S.;ITOV, G. V.;TOMILOV, +
  作者：XOXRYAKOV, YU. B.、AVRUTSKAYA, I. A.、KUCHEROV, S. S.、ITOV, G. V.、TOMILOV, +

  DOI：——

  日期：——
• ——
  作者：V. S. Pilyugin、L. V. Yakovleva

  DOI：10.1023/a:1020993224642

  日期：——

  A procedure for preparation of 3,4,4'-triaminodiphenyl sulfide by reduction of 4-amino-3,4'-dinitrodiphenyl sulfide with hydrazine hydrate in butanol catalyzed by a mixture of iron(Ill) chloride and activated carbon was developed providing the product in no less than 80% yield with the main compound content no less than 93%.
• ——
  作者：V. S. Pilyugin、G. E. Chikisheva、R. B. Valitov、Yu. E. Sapozhnikov

  DOI：10.1023/a:1021638231873

  日期：——

  A method for preparing 4-amino-3,4'-dinitrodiphenyl sulfide is developed, based on the reaction of 2-nitro-4-thiocyanatoaniline with 4-nitrochlorobenzene in aqueous-alkaline medium in the presence of a phase-transfer catalyst (PEG 400 or Katamin AB).