(E)-2,3-dihydroinden-1-ylidenehydrazine | 5736-44-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (E)-2,3-dihydroinden-1-ylidenehydrazine
• CAS: 5736-44-7
• 化学式: C₉H₁₀N₂
• 分子量: 146.192
• InChiKey: ZFFYDQAURJCWPQ-PKNBQFBNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  38.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-2,3-dihydroinden-1-ylidenehydrazine 在 正丁基锂 、 azidophosphonium bromide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以53%的产率得到1H-茚,1-重氮基-2,3-二氢-
  参考文献：
  名称：

  正丁基锂和叠氮（二乙氨基）phosph将of转化为重氮化合物

  摘要：

  由与正丁基锂/己烷在-78°C下于THF反应制得的酰肼锂在约0°C下于THF中由叠氮基（二乙基氨基）efficiently有效，快速，安全地转化为相应的重氮化合物与三（二乙氨基）磷亚胺，氮和溴化锂。

  DOI：

  10.1016/s0040-4039(02)01443-0

文献信息

• [EN] TETRAZOLINONE COMPOUNDS AND ITS USE AS PEST CONTROL AGENTS<br/>[FR] COMPOSÉS TÉTRAZOLINONE ET LEUR UTILISATION EN TANT QU'AGENTS DE LUTTE CONTRE LES NUISIBLES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2018097318A1

  公开（公告）日：2018-05-31

  The present invention provides a tetrazolinone represented by formula (I) and a pest control agent comprising the same, and their use thereof. Formula (I) [wherein, W1 represents an oxygen atom or a sulfur atom; W2 represents a hydrogen atom, or a C1-C6 chain hydrocarbon group; R15 and R16 represent a halogen atom and the like; u is 0, 1, 2 or 3; the combination of E, G, X1, Y1 and Z1 represents any one of the combinations of the following a and the like: a: a combination wherein E represents #-C(X1)(Y1)-O-N=C(Z1)-, #-C(X1)(Y1)-S-N=C(Z1)-, #-C(X1)(Y1)-O-N=C(Z1)-O-CH2-, #-C(X1)(Y1)-O-N=C(Z1)-S-CH2-, #-C(X1)(Y1)-S-N=C(Z1)-O-CH2-, #-C(X1)(Y1)-S-N=C(Z1)-S-CH2-, #-C(Z1)=N-N=C(Z2)-, #-C(X1)=C(Y1)-C(Z1)=N-O-CH2- or #-C(X1)=C(Y1)-C(Z1)=N-S-CH2-; G represents a C1-C6 chain hydrocarbon group, a (C1-C6 alkoxy)C1-C6 alkyl group, a (C1-C6 alkylthio)C1-C6 alkyl group the C1-C6 chain hydrocarbon group, the (C1-C6 alkoxy)C1-C6 alkyl group, and the (C1-C6 alkylthio)C1-C6 alkyl group may have one or more substituents selected from Group S} or R1-T1-, X1 and Y1, which are identical to or different from each other, independently represents substituents selected from Group T, and Z1 represents a substituent selected from Group V.]

  本发明提供了一种由式(I)表示的四唑酮化合物，以及包含该化合物的杀虫剂，以及它们的使用。式(I)中，W1代表氧原子或硫原子；W2代表氢原子或C1-C6链烃基；R15和R16代表卤素原子等；u为0、1、2或3；E、G、X1、Y1和Z1的组合代表以下a等组合中的任意一种：a：E代表#-C(X1)(Y1)-O-N=C(Z1)-、#-C(X1)(Y1)-S-N=C(Z1)-、#-C(X1)(Y1)-O-N=C(Z1)-O-CH2-、#-C(X1)(Y1)-O-N=C(Z1)-S- -、#-C(X1)(Y1)-S-N=C(Z1)-O- -、#-C(X1)(Y1)-S-N=C(Z1)-S- -、#-C(Z1)=N-N=C(Z2)-、#-C(X1)=C(Y1)-C(Z1)=N-O- -或#-C(X1)=C(Y1)-C(Z1)=N-S- -；G代表C1-C6链烃基、(C1-C6烷氧基)C1-C6烷基、(C1-C6烷硫基)C1-C6烷基C1-C6链烃基、(C1-C6烷氧基)C1-C6烷基和(C1-C6烷硫基)C1-C6烷基中的每一种可能具有来自S族的一个或多个取代基}或R1-T1-，X1和Y1互相相同或不同，独立地代表来自T族的取代基，Z1代表来自V族的取代基。
• Tetrazolinone compounds and its use as pest control agents
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US11225470B2

  公开（公告）日：2022-01-18

  The present invention provides a tetrazolinone represented by formula (I) and a pest control agent comprising the same, and their use thereof. Formula (I) [wherein, W1 represents an oxygen atom or a sulfur atom; W2 represents a hydrogen atom, or a C1-C6 chain hydrocarbon group; R15 and R16 represent a halogen atom and the like; u is 0, 1, 2 or 3; the combination of E, G, X1, Y1 and Z1 represents any one of the combinations of the following a and the like: a: a combination wherein E represents #—C(X1)(Y1)—O—N═C(Z1)—, #—C(X1)(Y1)—S—N═C(Z1)—, #—C(X1)(Y1)—O—N═C(Z1)—O—CH2—, #—C(X1)(Y1)—O—N═C(Z1)—S—CH2—, #—C(X1)(Y1)—S—N═C(Z1)—O—CH2—, #—C(X1)(Y1)—S—N═C(Z1)—S—CH2—, #—C(Z1)═N—N═C(Z2)—, #—C(X1)═C(Y1)—C(Z1)═N—O—CH2— or #—C(X1)═C(Y1)—C(Z1)═N—S—CH2—; G represents a C1-C6 chain hydrocarbon group, a (C1-C6 alkoxy)C1-C6 alkyl group, a (C1-C6 alkylthio)C1-C6 alkyl group the C1-C6 chain hydrocarbon group, the (C1-C6 alkoxy)C1-C6 alkyl group, and the (C1-C6 alkylthio)C1-C6 alkyl group may have one or more substituents selected from Group S} or R1-T1-, X1 and Y1, which are identical to or different from each other, independently represents substituents selected from Group T, and Z1 represents a substituent selected from Group V.]

  本发明提供了由式(I)代表的四唑啉酮和由其组成的害虫防治剂及其用途。式（I）[其中，W1代表氧原子或硫原子；W2代表氢原子，或C1-C6链烃基团；R15和R16代表卤原子等；u为0、1、2或3；E、G、X1、Y1和Z1的组合代表以下a等组合中的任意一种：a．其中 E 代表 #-C(X1)(Y1)-O-N═C(Z1)-、#-C(X1)(Y1)-S-N═C(Z1)-、#-C(X1)(Y1)-O-N═C(Z1)-O-CH2-、#-C(X1)(Y1)-O-N═C(Z1)-S- -的组合、#-C(X1)(Y1)-S-N═C(Z1)-O- -，#-C(X1)(Y1)-S-N═C(Z1)-S- -，#-C(Z1)═N-N═C(Z2)-，#-C(X1)═C(Y1)-C(Z1)═N-O- -或#-C(X1)═C(Y1)-C(Z1)═N-S- -；G代表C1-C6链烃基，(C1-C6烷氧基)C1-C6烷基，(C1-C6烷硫基)C1-C6烷基C1-C6链烃基，(C1-C6烷氧基)C1-C6烷基和(C1-C6烷硫基)C1-C6烷基可以有一个或多个选自S组的取代基}或R1-T1-，X1和Y1彼此相同或不同，独立地代表选自T组的取代基，Z1代表选自V组的取代基。]
• TETRAZOLINONE COMPOUNDS AND ITS USE AS PEST CONTROL AGENTS
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3544973B1

  公开（公告）日：2021-07-28
• MULTILAYER PHASE DIFFERENCE PLATE, POLARIZING PLATE, AND IMAGE DISPLAY DEVICE
  申请人：ZEON CORPORATION

  公开号：US20220177419A1

  公开（公告）日：2022-06-09

  A phase difference plate includes a phase difference plate P1 and a phase difference plate P2. An in-plane slow axis of the phase difference plate P1 is orthogonal to an in-plane slow axis of the phase difference plate P2. The phase difference plate P2 includes a layer of a liquid crystal material oriented in an in-plane direction. An in-plane retardation ReP2(λ) at a wavelength λ nm of the phase difference plate P2 satisfies the following formulae (e1) and (e2): Re2(400)−Re2(550)}/Re2(550)−Re2(700)}<2.90 (e1), and Re2(400)/Re2(700)>1.13 (e2). An in-plane retardation ReP1(λ) of the phase difference plate P1 at a wavelength λ nm and the in-plane retardation ReP2(λ) of the phase difference plate P2 at the wavelength λ nm satisfy the following formulae (e4) and (e5): ReP1(550)>ReP2(550) (e4), and ReP1(400)/ReP1(700)
• US4028380A
  申请人：——

  公开号：US4028380A

  公开（公告）日：1977-06-07