2-((2,5,9,12-tetraoxatridecan-7-yloxy)methyl)oxirane

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 2-((2,5,9,12-tetraoxatridecan-7-yloxy)methyl)oxirane
• 英文别名: 2-[1,3-Bis(2-methoxyethoxy)propan-2-yloxymethyl]oxirane
• 化学式: C₁₂H₂₄O₆
• 分子量: 264.319
• InChiKey: AMOFRTURSQPXGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-((2,5,9,12-tetraoxatridecan-7-yloxy)methyl)oxirane 在 4-二甲氨基吡啶 、 三乙胺 、 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 7-((2-methoxyethoxy)methyl)-2,5,8,12,15-pentaoxahexadecan-10-yl methacrylate
  参考文献：
  名称：

  Synthesis of Neutral, Water-Soluble Oligo–Ethylene Glycol-Containing Dendronized Homo- and Copolymers of Generations 1, 1.5, 2, and 3

  摘要：

  Oligo-ethylene glycol-containing dendronized monomers MG1, MG1.5, MG2, and MG3 were synthesized in a particularly easy fashion on the gram scale involving only few steps. Their corresponding homopolymers (PG1, PG1.5, PG2, and PG3) and copolymers (PG1co2, PG1co3, and PG2co3) were synthesized via free radical polymerization. All the polymers are soluble in water and also in organic solvents such as DCM, CHCl3, 1,4-dioxolane, DMF, and DMSO. Their glass transition temperatures (T-g) are in the range -68 degrees C < T-g < -48 degrees C and thus rather low. All polymers show thermoresponsive behavior which was investigated by turbidity measurements. Interestingly, a 1:1 mixture of homopolymers PG1 and PG2 behaves identical with PG1 alone, while the collapse curve of copolymer PG1co2 is almost superimposable with that of PG2 alone. Thus, in the former case PG1 dominates the thermoresponsive behavior while in the latter this is done by the G2-dendrons in the copolymer. Finally, the polymer chains were visualized by AFM, confirming the rod-like behavior of these rigidified polymers.

  DOI：

  10.1021/ma5017192
• 作为产物：
  描述：

  2-甲氧基乙基缩水甘油醚 在 sodium hydride 、 sodium hydroxide 作用下， 以 四氢呋喃 、 水 、 mineral oil 为溶剂， 反应 22.0h， 生成 2-((2,5,9,12-tetraoxatridecan-7-yloxy)methyl)oxirane
  参考文献：
  名称：

  Synthesis of Neutral, Water-Soluble Oligo–Ethylene Glycol-Containing Dendronized Homo- and Copolymers of Generations 1, 1.5, 2, and 3

  摘要：

  Oligo-ethylene glycol-containing dendronized monomers MG1, MG1.5, MG2, and MG3 were synthesized in a particularly easy fashion on the gram scale involving only few steps. Their corresponding homopolymers (PG1, PG1.5, PG2, and PG3) and copolymers (PG1co2, PG1co3, and PG2co3) were synthesized via free radical polymerization. All the polymers are soluble in water and also in organic solvents such as DCM, CHCl3, 1,4-dioxolane, DMF, and DMSO. Their glass transition temperatures (T-g) are in the range -68 degrees C < T-g < -48 degrees C and thus rather low. All polymers show thermoresponsive behavior which was investigated by turbidity measurements. Interestingly, a 1:1 mixture of homopolymers PG1 and PG2 behaves identical with PG1 alone, while the collapse curve of copolymer PG1co2 is almost superimposable with that of PG2 alone. Thus, in the former case PG1 dominates the thermoresponsive behavior while in the latter this is done by the G2-dendrons in the copolymer. Finally, the polymer chains were visualized by AFM, confirming the rod-like behavior of these rigidified polymers.

  DOI：

  10.1021/ma5017192

文献信息

• COPOLYETHER AND SOLID POLYMER ELECTROLYTE
  申请人：DAISO CO., LTD.

  公开号：EP0885913A1

  公开（公告）日：1998-12-23

  A solid polymer electrolyte obtained by blending (1) a polyether copolymer having a main chain, which is derived form ethylene oxide, and a side chain having two oligooxyethylene groups, (2) an electrolyte salt compound, and, if necessary, (3) a plasticizer which is any one of an aprotic organic solvent or a derivative or metal salt of a polyalkylene glycol having a number-average molecular weight of 200 to 5,000 or a metal salt of the derivative, is superior in ionic conductivity and also superior in processability, moldability and mechanical strength to a conventional solid electrolyte. A secondary battery is constructed by using the solid polymer electrolyte in combination with a lithium metal negative electrode and a lithium cobaltate positive electrode.

  一种固体聚合物电解质，由以下物质混合而成：(1) 聚醚共聚物，其主链由环氧乙烷衍生而来，侧链上有两个低聚氧乙烯基团；(2) 电解质盐化合物；必要时，还可加入以下物质(3) 增塑剂，增塑剂为壬烷有机溶剂或聚亚烷基二醇的衍生物或金属盐中的任一种，其平均分子量在 200 至 5000 之间，或为该衍生物的金属盐。固体聚合物电解质与金属锂负极和钴酸锂正极结合使用，可制成二次电池。
• US6180287B1
  申请人：——

  公开号：US6180287B1

  公开（公告）日：2001-01-30
• Synthesis of Neutral, Water-Soluble Oligo–Ethylene Glycol-Containing Dendronized Homo- and Copolymers of Generations 1, 1.5, 2, and 3
  作者：Xiaoyu Sun、Jean-Pierre Lindner、Bernd Bruchmann、A. Dieter Schlüter

  DOI：10.1021/ma5017192

  日期：2014.11.11

  Oligo-ethylene glycol-containing dendronized monomers MG1, MG1.5, MG2, and MG3 were synthesized in a particularly easy fashion on the gram scale involving only few steps. Their corresponding homopolymers (PG1, PG1.5, PG2, and PG3) and copolymers (PG1co2, PG1co3, and PG2co3) were synthesized via free radical polymerization. All the polymers are soluble in water and also in organic solvents such as DCM, CHCl3, 1,4-dioxolane, DMF, and DMSO. Their glass transition temperatures (T-g) are in the range -68 degrees C < T-g < -48 degrees C and thus rather low. All polymers show thermoresponsive behavior which was investigated by turbidity measurements. Interestingly, a 1:1 mixture of homopolymers PG1 and PG2 behaves identical with PG1 alone, while the collapse curve of copolymer PG1co2 is almost superimposable with that of PG2 alone. Thus, in the former case PG1 dominates the thermoresponsive behavior while in the latter this is done by the G2-dendrons in the copolymer. Finally, the polymer chains were visualized by AFM, confirming the rod-like behavior of these rigidified polymers.