7-((2-methoxyethoxy)methyl)-2,5,8,12,15-pentaoxahexadecan-10-yl methacrylate | 1431609-71-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 7-((2-methoxyethoxy)methyl)-2,5,8,12,15-pentaoxahexadecan-10-yl methacrylate
• 英文别名: [1-[1,3-Bis(2-methoxyethoxy)propan-2-yloxy]-3-(2-methoxyethoxy)propan-2-yl] 2-methylprop-2-enoate
• CAS: 1431609-71-0
• 化学式: C₁₉H₃₆O₉
• 分子量: 408.489
• InChiKey: UPXOUAORRZFLFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  28
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  90.9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2-甲氧基乙基缩水甘油醚 在 4-二甲氨基吡啶 、 三乙胺 、 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 7-((2-methoxyethoxy)methyl)-2,5,8,12,15-pentaoxahexadecan-10-yl methacrylate
  参考文献：
  名称：

  Synthesis of Neutral, Water-Soluble Oligo–Ethylene Glycol-Containing Dendronized Homo- and Copolymers of Generations 1, 1.5, 2, and 3

  摘要：

  Oligo-ethylene glycol-containing dendronized monomers MG1, MG1.5, MG2, and MG3 were synthesized in a particularly easy fashion on the gram scale involving only few steps. Their corresponding homopolymers (PG1, PG1.5, PG2, and PG3) and copolymers (PG1co2, PG1co3, and PG2co3) were synthesized via free radical polymerization. All the polymers are soluble in water and also in organic solvents such as DCM, CHCl3, 1,4-dioxolane, DMF, and DMSO. Their glass transition temperatures (T-g) are in the range -68 degrees C < T-g < -48 degrees C and thus rather low. All polymers show thermoresponsive behavior which was investigated by turbidity measurements. Interestingly, a 1:1 mixture of homopolymers PG1 and PG2 behaves identical with PG1 alone, while the collapse curve of copolymer PG1co2 is almost superimposable with that of PG2 alone. Thus, in the former case PG1 dominates the thermoresponsive behavior while in the latter this is done by the G2-dendrons in the copolymer. Finally, the polymer chains were visualized by AFM, confirming the rod-like behavior of these rigidified polymers.

  DOI：

  10.1021/ma5017192

文献信息

• Copolymerization of a dendronized monomer with styrene and different acrylates: Determination of reactivity ratios
  作者：Anke Krebs、Bernd Bruchmann、Anna Müller-Cristadoro、Rabie Al-Hellani、A. Dieter Schlüter

  DOI：10.1002/pola.26504

  日期：2013.3.15

  The reactivity ratios for the copolymerization of a first‐generation dendronized monomer with styrene and different acrylates are determined. The obtained ratios as well as the copolymer compositions that can be expected are discussed in detail. The influence of the dendron on the polymerization potential of the monomer is estimated by comparing its reactivity to those of linear systems as well as

  确定了第一代树状化单体与苯乙烯和不同丙烯酸酯共聚的反应率。详细讨论了所获得的比例以及可以预期的共聚物组成。树突对单体聚合潜能的影响是通过将其反应性与线性体系的反应性进行比较，以及使用更高生成量的树突化单体来估算的。©2012 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem，2013年