[copper(II)(13,13-bis(hydroxymethyl)-6-methyl-6-nitro-1,4,8,11-tetra-aza-cyclotetradecane)(perchlorate)2] | 896101-18-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [copper(II)(13,13-bis(hydroxymethyl)-6-methyl-6-nitro-1,4,8,11-tetra-aza-cyclotetradecane)(perchlorate)2]
• CAS: 896101-18-1
• 化学式: C₁₃H₂₉Cl₂CuN₅O₁₂
• 分子量: 581.852
• InChiKey: WBWZHLNHWLDBMP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 硝基乙烷 、 [Copper(II)(2,2-bis(2-aminoethylaminomethyl)-propan-1,3-diol)Cl2]*2H2O 、 sodium perchlorate 在 triethylamine 、 acetic acid 作用下， 以 甲醇 、 水 为溶剂， 生成 [copper(II)(13,13-bis(hydroxymethyl)-6-methyl-6-nitro-1,4,8,11-tetra-aza-cyclotetradecane)(perchlorate)2]
  参考文献：
  名称：

  Polyamines from polyols – Pathways to azamacrocycles with hydroxymethyl pendent groups

  摘要：

  Several pathways to macromonocylic polyamine ligands with pendent hydroxymethyl substituents have been explored. The new ligands have all been characterised by single-crystal, X-ray structure determinations on their complexes with Co(III) (one case) and Cu(II). As in some related systems, four-membered ring species, here oxetanes rather than azetidines, appear to be involved as reaction intermediates and can be quite readily isolated, providing reactants of potential for the construction of even more complicated multidentate ligands. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.11.024