(E,E,Ss,Ss)-N,N'-(anthracene-9,10-diylbis(methan-1-yl-1-ylidene))bis(2-methylpropane-2-sulfinamide) | 1104003-75-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (E,E,Ss,Ss)-N,N'-(anthracene-9,10-diylbis(methan-1-yl-1-ylidene))bis(2-methylpropane-2-sulfinamide)
• CAS: 1104003-75-9
• 化学式: C₂₄H₂₈N₂O₂S₂
• 分子量: 440.631
• InChiKey: YZXKAFNYKVTWOZ-XCKBNOQKSA-N

物化性质

• 沸点：
  660.5±65.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  30.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  58.86
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (E,E,Ss,Ss)-N,N'-(anthracene-9,10-diylbis(methan-1-yl-1-ylidene))bis(2-methylpropane-2-sulfinamide) 在 potassium tert-butylate 、 (三氟甲基)三甲基硅烷 作用下， 生成 9,10-二氰基蒽
  参考文献：
  名称：

  Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

  摘要：

  A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1'R)-1,1'-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.082
• 作为产物：
  描述：

  9,10-二甲酰基蒽 、 S-叔丁基亚磺酰胺 以 四氢呋喃 为溶剂， 以86%的产率得到(E,E,Ss,Ss)-N,N'-(anthracene-9,10-diylbis(methan-1-yl-1-ylidene))bis(2-methylpropane-2-sulfinamide)
  参考文献：
  名称：

  Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

  摘要：

  A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1'R)-1,1'-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.082