2-cyano-N-ethyl-N-methylacetamide | 119164-07-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-cyano-N-ethyl-N-methylacetamide
• CAS: 119164-07-7
• 化学式: C₆H₁₀N₂O
• 分子量: 126.158
• InChiKey: OOKDKRGEASFNIU-UHFFFAOYSA-N

物化性质

• 沸点：
  238.1±23.0 °C(Predicted)
• 密度：
  1.006±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  44.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-苄基-2-丁醇 、 2-cyano-N-ethyl-N-methylacetamide 在 硫酸 作用下， 以 苯 为溶剂， 反应 2.0h， 以61%的产率得到(2Z)-2-(3-ethyl-3-methyl-2,4-dihydroisoquinolin-1-ylidene)-1-morpholin-4-ylethanone;hydrochloride
  参考文献：
  名称：

  Synthesis of enaminoamides of the 1,2,3,4-tetrahydroisoquinoline series

  摘要：

  DOI：

  10.1007/bf00487305

文献信息

• Herbicidally active enols
  申请人：Rohm and Haas Company

  公开号：US04781750A1

  公开（公告）日：1988-11-01

  Enols, their geometric isomers, tautomers and halogen addition products having the formula ##STR1## as defined herein and compositions containing these compounds exhibit herbicidal activity.

  Enols，它们的几何异构体，互变异构体和卤素加成产物的化学式为##STR1##，并且含有这些化合物的组合物表现出除草活性。
• US4781750A
  申请人：——

  公开号：US4781750A

  公开（公告）日：1988-11-01
• [EN] CURABLE POLYORGANYLOXY-SILOXANE COMPOSITIONS<br/>[FR] COMPOSITIONS DE POLYORGANYLOXY-SILOXANE DURCISSABLES
  申请人：WACKER CHEMIE AG

  公开号：WO2021118548A1

  公开（公告）日：2021-06-17

  The present invention is a curable silicone composition comprising a linear polyorganyloxy-siloxane component (A) of the following general formula (I) R1aR23-aSiO(R2 2SiO)b(R3HSiO)c(R3R4OSiO)dSiR1aR23-a wherein, R1, R2, R3, a, b, c are as defined above and R4 is a hydrocarbon derivative, which has from 1 to 15 carbon atoms having linear, branched, or cyclic arrangements, and may be substituted by OH groups, halogen atoms, silyl groups, siloxy groups, -CN, -COOR6, -OCOOR7, -CONR8R9, -OCONR10R11, -NR12CONR13R14, -SO2-R15, -OSO2-R16, -OP(OR17) (OR18), 1,3-dioxolan-2-one, wherein the carbon may be interrupted by nonadjacent groups which are selected from -(CO)-, -O-, -S- or -NR19-, R6 to R19 are each a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and may be substituted by halogen atoms, and d comprises up to 60 mol % of the silicon atoms of the organosilicon compound (A) of the general formula (I); of an organosilicon compound (B) containing Si-H-bonded hydrogen atoms; and a curing promoting component (C) is selected from a transition metal catalyst (C1) a peroxide (C2); The present invention further relates to the linear polyorganyloxy-siloxane component (A) and a process for preparing component (A).
• [EN] RADIATION CURABLE POLYORGANYLOXY-SILOXANE COMPOSITIONS<br/>[FR] COMPOSITIONS DE POLYORGANYLOXY-SILOXANE DURCISSABLES PAR RAYONNEMENT
  申请人：WACKER CHEMIE AG

  公开号：WO2021126178A1

  公开（公告）日：2021-06-24

  The present invention is a curable silicone composition comprising a linear polyorganyloxy-siloxane component (A) of the following general formula (I) R1 aR2 3-aSiO(R2 2SiO)b(R3HSiO)c(R3R4OSiO)dSiR1 aR2 3-a (I) wherein, R1, R2, R3, a, b, c are as defined above and R4 is a hydrocarbon derivative, which has from 1 to 30 carbon atoms having linear, branched, or cyclic arrangements, and may be substituted by OH groups, halogen atoms, silyl groups, siloxy groups, -CN, -COOR6, -OCOOR7, -CONR8R9, -OCONR10R11, -NR12CONR13R14, -SO2-R15, -OSO2-R16, -OP(OR17) (OR18), 1,3-dioxolan-2-one, wherein the carbon may be interrupted by nonadjacent groups which are selected from -(CO)-, -O-, -S- or -NR19-,R6 to R19 are each a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and may be substituted by halogen atoms, and d comprises up to 60 mol % of the silicon atoms of the organosilicon compound (A) of the general formula (I); a mercapto group containing component (B) containing at least two carbon bonded SH groups per molecule; and a photoiniator component (C). The present invention further relates to a process for curing the curable silicone composition by energetic radiation.
• [EN] PROCESS FOR CURING POLYORGANYLOXYSILOXANE COMPOSITIONS BY RADIATION<br/>[FR] PROCÉDÉ DE DURCISSEMENT DE COMPOSITIONS DE POLYORGANYLOXYSILOXANE PAR RAYONNEMENT
  申请人：WACKER CHEMIE AG

  公开号：WO2021151510A1

  公开（公告）日：2021-08-05

  The present invention is a process for curing a silicone composition comprising a linear polyorganyloxy-siloxane component (A) of general formula (I): R1 aR2 3-aSiO(R2 2SiO)b(R3HSiO)c(R3R4OSiO)dSiR1 aR2 3—a wherein, R1, R2, R3, a, b, c are as defined in claim 1 and R4 is a hydrocarbon derivative, which has from 1 to 15 carbon atoms, and may be substituted by OH groups, halogen atoms, silyl groups, siloxy groups, -CN, -COOR6, -OCOOR7, -CONR8R9, -OCONR10R11, -NR12CONR13R14, -SO2-R15, -OSO2-R16, -OP(OR17) (OR18), 1,3-dioxolan-2-one, wherein the carbon may be interrupted by nonadjacent groups which are selected from - (CO) -, -O-, -S- or -NR19-, R6 to R19 are each a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and may be substituted by halogen atoms, d is a positive integer number which is chosen so that (R3R4OSiO)d comprises up to 60 mol % of the silicon atoms of the organosilicon compound (A) of general formula (I); wherein the silicone composition does not contain a SiH group containing component, by exposure to radiation.