(dibenzylidene propylene diamine o,o'-dihydroxo) oxo vanadium (IV) | 22785-41-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (dibenzylidene propylene diamine o,o'-dihydroxo) oxo vanadium (IV)
• 英文别名: propan-1,2-diylbis(N,N'-salicylideneiminato)oxovanadium(IV)；N,N'-bis(salicylidene)propylenediaminatooxovanadium(IV)；VO(N,N'-1,2-propylenebis-salicylideneaminato)；VO(N,N'-bis(salicylidene)-1,2-diaminopropane)
• CAS: 22785-41-7；36537-60-7；29876-29-7；1021603-25-7
• 化学式: C₁₇H₁₆N₂O₃V
• 分子量: 347.267
• InChiKey: ODGRTWPIUGNSPE-IZJQDONGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (dibenzylidene propylene diamine o,o'-dihydroxo) oxo vanadium (IV) 、 氢溴酸 以 乙腈 为溶剂， 以74%的产率得到dibromo[propan-1,2-diylbis(N,N'-salicylideneiminato)]vanadium(IV)
  参考文献：
  名称：

  新的四齿席夫碱，它们的氧钒（IV）配合物以及双齿席夫碱与钒（III）的某些配合物

  摘要：

  摘要描述了在两个亚氨基氮原子之间包含一个，两个或三个碳原子的四齿席夫碱双阴离子新的钒（IV）配合物。这些化合物是单核的或高分子的，如v（V = O）的值所示，具体取决于席夫碱的二价阴离子。没有证据表明电子会沿着聚合物链发生离域化。还分离了一些双齿席夫碱单阴离子钒（III）配合物。报道了[VO（2-OC6H4CHNH）2]的晶体结构和[V（Prhap）3]·甲苯[HPrhap = 2-HOC6H4C（Me）NCH2CH2Me]的结构的初步数据。

  DOI：

  10.1016/s0277-5387(96)00436-6
• 作为产物：
  描述：

  (dibenzylidene propylene diamine o,o'-dihydroxo) vanadium (III) hydrogensulfate 以 水 为溶剂， 生成 (dibenzylidene propylene diamine o,o'-dihydroxo) oxo vanadium (IV)
  参考文献：
  名称：

  Bielig, H. J.; Bayer, E., Liebigs Annalen der Chemie, 1953, vol. 580, p. 135 - 158

  摘要：

  DOI：

文献信息

• A vanadyl donor bond to tin in a heterobimetallic complex: the crystal structure of SnPh₃Cl·VO(salpren)(H₂salpren =N,N′-1,2-propylenebis-salicylideneamine)
  作者：Brenda Cashin、Desmond Cunningham、John F. Gallagher、Pat McArdle、Tim Higgins

  DOI：10.1039/c39890001445

  日期：——

  The title complex has an adduct structure in which the vanadyl salicylaldimine forms a donor bond through the vanadyl oxygen to tin, thereby generating an almost linear V–O–Sn moiety.

  标题复合物具有加合物结构，其中氧钒水杨醛亚胺通过氧钒氧与锡形成供体键，从而生成几乎线性的V–O–Sn部分。
• Reporting a New Class of Divanadium(V) Compounds Connected by an Unsupported Hydroxo Bridge
  作者：Pabitra Baran Chatterjee、Debdas Mandal、Anandalok Audhya、Ki-Young Choi、Akira Endo、Muktimoy Chaudhury

  DOI：10.1021/ic702286h

  日期：2008.5.1

  X-ray diffraction analyses. The molecules of 1- 3 have centrosymmetric structures with each vanadium center having a distorted octahedral geometry. The bridging OH (-) group is located trans to the terminal VO t bond. The latter exerts strong trans labilizing influence to set the participating vanadium centers apart by about 4.1 A. These separations are by far the largest (e.g., V...V#, 4.131 A in 1) among

  双核氧钒（V）化合物[LV（V）O（mu-OH）OV（V）L]（PF6）[H2L = N，N'-叔乙烯双（水杨亚胺）（H 2Salen）及其衍生物]（ 1-3）是通过在添加的NH 4PF 6存在下将V（IV）OL前体在THF中进行空气氧化而获得的。氧化的钒（V）可能会从溶剂中的残留水分中提取OH（-）配体。如单晶X射线衍射分析所证实的那样，这些化合物的金属中心之间保留有无支撑的羟基桥连基。1-3的分子具有中心对称结构，每个钒中心具有扭曲的八面体几何形状。桥连的OH（-）基团位于末端VO t键的反式位置。后者施加强大的反通斜影响，使参与的钒中心相距约4.1A。迄今为止，这些分离是所有含无载体羟基桥的双核化合物中最大的分离（例如，V ... V＃，4.131 A）。如（1）1 H NMR光谱法所确定的，该络合物还在溶液中保持其身份。电化学上，如循环伏安法在乙腈中研究的1-3的行为非常有趣，每个
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B2, 162, page 713 - 714
  作者：

  DOI：——

  日期：——
• 1:1 Adducts of triphenyltin chloride with oxovanadium(IV) tetradentate Schiff-base complexes
  作者：Nosheen F. Choudhary、Peter B. Hitchcock、G.Jeffery Leigh、Seik Weng Ng

  DOI：10.1016/s0020-1693(99)00230-3

  日期：1999.10

  Triphenyltin chloride-N,N'-ethylenebis(salicylideneiminato)oxovanadium(IV) (1/1), which crystallises from acetonitrile with half a molecule of the solvent, is a heterodinuclear entity that displays an almost linear tin-oxygen-vanadium unit [Sn-O-V = 172.7(2)degrees; Sn-O = 2.382(2), V-O = 1.614(3) Angstrom]. The tin atom shows approximately trigonal bipyramidal coordination in the adduct with the axial sites occupied by the O and Cl atoms. On the other hand, the vanadium atom is in square-pyramidal coordination, and the vanadium-containing moiety is 68% displaced along the Berry pseudorotation pathway from trigonal bipyramidal towards square pyramidal, compared with the 83% mean displacement for [VO(salen)] itself. The corresponding displacements for the vanadium moiety in Ph3SnCl . VO(hap-1,2-pn). 2CH(3)CN are 94% [Sn-O = 2.405(6), V-O = 1.627(6) Angstrom; Sn-O-V = 175.5(3)degrees] and 89% in Ph3SnCl . VO[salen(3-OMe)(2)]. CH3CN [Sn-O = 2.428(2), V-O = 1.625(2) Angstrom; Sn-O-V = 167.5(1)degrees] [H(2)hap-1,2-pn = N,N'-methylmethylenebis(2-phenolatoacetophenoneimine); H(2)salen(3-OMe)(2) = N,N'-ethylenebis(3-methoxysalicylideneimine)]. The [VO(salen)] adduct of N-triphenylstannyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide has also been synthesised, and characterised by spectroscopic measurements. (C) 1999 Elsevier Science S.A. All rights reserved.
• Binuclear metal complexes XVII. Vanadium(V)-copper(I) hetero-metal binuclear complexes prepared from oxovanadium(IV) complexes with quadridentate schiff bases and copper(II) halides
  作者：H. Okawa、S. Kida

  DOI：10.1016/s0020-1693(00)94770-4

  日期：1977.1