2-dodecyloxyaniline | 27046-10-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-dodecyloxyaniline
• 英文别名: 2-Dodecyloxy-anilin；2-(Dodecyloxy)aniline；2-dodecoxyaniline
• CAS: 27046-10-2
• 化学式: C₁₈H₃₁NO
• 分子量: 277.45
• InChiKey: DHQYZMFTSQWQQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.57
• 重原子数：
  20.0
• 可旋转键数：
  12.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  35.25
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2-dodecyloxyaniline 在 苯 作用下， 生成 2-dodecyloxy-tri-N-methyl-anilinium; methyl sulfate
  参考文献：
  名称：

  Kuhn; Jerchel, Chemische Berichte, 1940, vol. 73, p. 1100,1104

  摘要：

  DOI：
• 作为产物：
  描述：

  sodium o-nitrophenate 在 盐酸 、 铁粉 、 xylene 作用下， 生成 2-dodecyloxyaniline
  参考文献：
  名称：

  Nodzu et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1951, vol. 71, p. 713

  摘要：

  DOI：

文献信息

• Selective alkylation of aminophenols
  作者：Jiaxi Xu、Renchao Wang

  DOI：10.3998/ark.5550190.0011.927

  日期：——

  Oor N-Alkylated derivatives of aminophenols are important synthetic intermediates in organic synthesis. A series of aminophenols were selectively alkylated on their hydroxyl group in good yields via benzaldehyde protection of the amino group, subsequent alkylation, and hydrolysis; or on their amino group via imination and following reduction.

  氨基苯酚的O或N-烷基化衍生物是有机合成中重要的合成中间体。通过氨基苯甲醛保护，随后烷基化和水解，一系列氨基酚在其羟基上以良好的收率被选择性烷基化；或通过亚胺化和随后的还原作用在其氨基上。
• Oxalsäurediarylamide und deren Verwendung als UV-Absorber und damit ausgerüstete polymere Substrate
  申请人：BASF Aktiengesellschaft

  公开号：EP0116931A1

  公开（公告）日：1984-08-29

  Oxalsäurediarylamide der Formel in der R Wasserstoff oder lineares oder verzweigtes C1- bis C12-Alkyl bedeutet. Die Verbindungen (I) sind als UV-Absorber zur Stabilisierung von Polymeren Substraten sehr gut geeignet.

  式中 R 为氢或直链或支链 C1 至 C12 烷基的草酸二芳基酰胺。 化合物 (I) 非常适合用作稳定聚合物基材的紫外线吸收剂。
• Composition for liquid crystal aligning agent
  申请人：NISSAN CHEMICAL INDUSTRIES LTD.

  公开号：EP0337355A2

  公开（公告）日：1989-10-18

  This invention is concerned with a composition to be used as an agent for aligning liquid crystals in a liquid crystal cell, wherein liquid crystal molecules are aligned with an increased pretilt angle with respect to the substrate, such composition consists essentially of a polyimide resin precursor having repeating units represented by the formula (I) wherein R₁ denotes an organic group constituting a tetracarboxylic acid or its derivative; and R₂ represents a divalent organic group constituting a diamine; and a precursor of a diimide compound represented by the formula (II) or (III): wherein R₃ denotes a divalent organic group constituting a diamine; each of R₄ and R₅ represents an organic groups constituting a dicarboxylic acid containing an alkyl group having 6 to 20 carbon atoms, or its derivative, wherein R₆ denotes an organic group constituting a tetracarboxylic acid or its derivative, and each of R₇ and R₈ represents an organic group constituting a monoamine containing an alkyl group having 6 to 20 carbon atoms.

  本发明涉及一种用作液晶池中液晶排列剂的组合物，其中液晶分子相对于基底以增大的前倾角排列，这种组合物主要由具有由式(I)表示的重复单元的聚酰亚胺树脂前体组成 其中 R₁ 表示构成四羧酸或其衍生物的有机基团；R₂ 表示构成二胺的二价有机基团；以及 式 (II) 或 (III) 所代表的二亚胺化合物的前体： 其中 R₃ 表示构成二胺的二价有机基团； R₄ 和 R₅ 各自代表构成含有 6 至 20 个碳原子的烷基的二羧酸的有机基团或其衍生物、 其中 R₆ 表示构成四羧酸的有机基团或其衍生物，R₇ 和 R₈ 各代表构成含有 6 至 20 个碳原子的烷基的单胺的有机基团。
• Dye-forming coupler, silver halide photographic light-sensitive material and azomethine dye compound
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1246006A2

  公开（公告）日：2002-10-02

  A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: wherein Q is a group -C(-R11)=C(-R12)-SO2-; R11 and R12 bond with each other to form, together with the -C=C- moiety, a 5- to 7-membered ring, or they each represent a hydrogen atom or a substituent; R1, R3 and R4 each represent a substituent; m is an integer of 0 to 4; and X represents a hydrogen atom or a group that splits off upon a coupling reaction with an oxidized product of a developing agent; with the proviso that the following compound (I-A) is excluded from the dye-forming coupler of formula (I).

  一种式(I)的染料形成耦合剂，一种含有该耦合剂的卤化银感光材料，以及一种可由染料形成耦合剂衍生的偶氮染料：其中 Q 是基团 -C(-R11)=C(-R12)-SO2-；R11 和 R12 相互键合，与 -C=C- 分子一起形成 5 至 7 元环，或者它们各自代表氢原子或取代基；R1、R3 和 R4 各自代表取代基；m 是 0 至 4 的整数；以及 X 代表氢原子或与显色剂的氧化产物发生偶联反应后分裂出的基团；但下述化合物 (I-A) 不包括在式 (I) 的染料形成偶联剂中。
• TRIPHENYLBORON COMPOUND-CONTAINING ANTIFOULING COATING COMPOSITION HAVING IMPROVED STABILITY, ANTIFOULING AGENT SET USED THEREFOR, AND METHOD FOR SUPPRESSING/CONTROLLING DECOMPOSITION OF TRIPHENYLBORON COMPOUND
  申请人：CHUGOKU MARINE PAINTS, LTD.

  公开号：EP2161318A1

  公开（公告）日：2010-03-10

  An object of the present invention is to provide an antifouling coating material composition in which, though containing a triphenylboron compound as an antifouling agent, the triphenylboron compound is inhibited from being decomposed in production and long term storage and which is excellent in a storage stability and a static antifouling property of an antifouling coating film obtained therefrom. The antifouling coating material composition of the present invention comprises at least (A) a coating film-forming resin and (B) a triphenylboron-amine complex (b1) as an antifouling agent, and it further comprises (C) an amine compound other than the triphenylboron-amine complex (b1) described above as a decomposition inhibitor for the above compound (b1). A content of the amine compound (C) described above is preferably a proportion of 1.0 to 210 parts by weight per 100 parts by weight of the component (b1).

  本发明的目的是提供一种防污涂层材料组合物，其中虽然含有作为防污剂的三苯基硼化合物，但该三苯基硼化合物在生产和长期储存过程中被抑制分解，其储存稳定性和由此获得的防污涂膜的静态防污性能优异。 本发明的防污涂层材料组合物至少包括(A)成膜树脂和(B)作为防污剂的三苯基硼-胺复合物(b1)，还包括(C)除上述三苯基硼-胺复合物(b1)以外的胺化合物，作为上述化合物(b1)的分解抑制剂。上述胺化合物（C）的含量最好为每 100 重量份组分（b1）1.0 至 210 重量份。