Pelargonsaeure-2-butylester | 55195-29-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Pelargonsaeure-2-butylester
• 英文别名: nonanoic acid sec-butyl ester；Nonansaeure-sec-butylester；1-Methylpropyl nonanoate；butan-2-yl nonanoate
• CAS: 55195-29-4
• 化学式: C₁₃H₂₆O₂
• 分子量: 214.348
• InChiKey: VBZZHIMUESOSKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  壬酰氯 、 仲丁醇 在 吡啶 作用下， 生成 Pelargonsaeure-2-butylester
  参考文献：
  名称：

  Schlenk,W., Justus Liebigs Annalen der Chemie, 1973, p. 1179 - 1194

  摘要：

  DOI：

文献信息

• Regiochemical control in palladium(0) and palladium(<scp>II</scp>) catalysed alkene–formate ester carbonylation reactions
  作者：Ivan J. B. Lin、Howard Alper

  DOI：10.1039/c39890000248

  日期：——

  Palladium(0) complexes [Pd(PPh3)4 or Pd(dba)2], (dba = dibenzylideneacetone) in the presence of 1,4-bis(diphenylphosphino)butane, can catalyse the reaction of alkenes and formate esters to give linear carboxylic esters as the major product, while the branched chain isomer was the principal ester obtained by use of a palladium(II) complex [bis(triphenylphosphine)palladium dichloride] as the catalyst

  钯（0）络合物[Pd（PPh 3）4或Pd（dba）2 ]，（dba =二亚苄基丙酮），在1,4-双（二苯基膦基）丁烷的存在下，可以催化烯烃和甲酸酯的反应，得到线性羧酸酯是主要产物，而支链异构体是通过使用钯（II）配合物[双（三苯基膦）钯二氯化物]作为催化剂获得的主要酯。
• CURABLE FLUORINE-CONTAINING POLYMER COMPOSITION
  申请人：Imoto Katsuhiko

  公开号：US20100113700A1

  公开（公告）日：2010-05-06

  There is provided a curable fluorine-containing polymer composition which is quickly cured at relatively low temperatures by hydrosilylation reaction and provides a coating film which has high hardness, excellent solvent resistance and flexibility. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and a non-fluorinated ethylenic monomer unit, in which a part or the whole of the non-fluorinated ethylenic monomer units is a unit represented by the formula: wherein R 1 is hydrogen or methyl; R 2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R 3 is —O—, —O[CH(R 4 )] m O—, —(CH 2 ) m O—, —OC(O)—(CH 2 ) m O— or —(CH 2 ) m OC(O)—(CH 2 ) n O—, where R 4 is —H, —OH, —CH 2 OH or —O—X—R 2 , a siloxane compound having hydrogen atom bonded to silicon atom, and a catalyst for hydrosilylation reaction.
• POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20180030175A1

  公开（公告）日：2018-02-01

  A polymer that is capable of affording a heat storage material superior in humidity permeability and shape retention after phase transition and that is superior in molding processability is provided. The polymer includes constitutional units (A) derived from ethylene, constitutional units (B) represented by a specified formula, and optionally includes constitutional units (C) represented by another specified formula. Where the total number of the units (A), the units (B), and the units (C) is 100%, the number of the units (A) accounts for 70% to 99%, the total number of the units (B) and the units (C) accounts for 1% by weight to 30% by weight. Where the total number of the units (B) and the units (C) is 100%, the number of the units (B) accounts for 1% to 100% and the number of the units (C) accounts for 0% to 99%.
• US9018306B2
  申请人：——

  公开号：US9018306B2

  公开（公告）日：2015-04-28
• US9127114B2
  申请人：——

  公开号：US9127114B2

  公开（公告）日：2015-09-08