dodecafluorohexane-1,6-disulfonic acid | 51604-66-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: dodecafluorohexane-1,6-disulfonic acid
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexane-1,6-disulfonic acid
• CAS: 51604-66-1
• 化学式: C₆H₂F₁₂O₆S₂
• 分子量: 462.191
• InChiKey: RRDATUVLKCKLBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  126
• 氢给体数：
  2
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  1,6-Bis-methylmercapto-dodecafluor-hexan 生成 dodecafluorohexane-1,6-disulfonic acid
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.1, page 76 - 99

  摘要：

  DOI：

文献信息

• SULFUR-BASED ELECTROLYTE SOLUTION FOR MAGNESIUM CELL
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：EP3904337A1

  公开（公告）日：2021-11-03

  An object of the present invention is to provide a highly practical electrolyte solution which has high oxidation resistance and enables dissolution-precipitation of magnesium to proceed repeatedly and stably. The present invention relates to an electrolyte solution for a magnesium battery comprising a mixture of a compound represented by the general formula [1], a Lewis acid or a compound represented by the general formula [4], and a solvent; an electrochemical device containing the electrolyte solution; and a compound represented by the general formula [1]. [In the general formula [1], X1 represents a halogeno group, and R1 represents an alkyl group having 1 to 10 carbon atoms, which may have a group represented by - SO3MgX2 (X2 represents a halogeno group); a haloalkyl group having 1 to 10 carbon atoms, which may have a group represented by -SO3MgX2 (X2 is the same as described above); an aryl group having 6 to 14 carbon atoms, which may have an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a halogeno group, or a group represented by -SO3MgX2 (X2 is the same as described above); or a biphenyl group which may have a group represented by -SO3MgX2 (X2 is the same as described above).]         Mg [N(SO2R4)2]2     [4] (In the general formula [4], four R4's each independently represent an alkyl group having 1 to 6 carbon atoms, a perfluoroalkyl group having 1 to 6 carbon atoms, a phenyl group, or a perfluorophenyl group.)

  本发明的目的是提供一种实用性很强的电解质溶液，它具有很强的抗氧化性，并能使镁的溶解沉淀反复稳定地进行。 本发明涉及一种用于镁电池的电解质溶液，它包括通式[1]所代表的化合物、路易斯酸或通式[4]所代表的化合物和溶剂的混合物；含有该电解质溶液的电化学装置；以及通式[1]所代表的化合物。 [在通式[1]中，X1 代表卤代基团，R1 代表具有 1 至 10 个碳原子的烷基，其基团可以是 -SO3MgX2 （X2 代表卤代基团）；具有 1 至 10 个碳原子的卤代烷基，其基团可以是 -SO3MgX2 （X2 与上述相同）；具有 6 至 14 个碳原子的芳基，该芳基可以具有 1 至 6 个碳原子的烷基、1 至 6 个碳原子的烷氧基、卤代基团或由 -SO3MgX2 代表的基团（X2 与上述相同）；或联苯基团，该联苯基团可以具有由 -SO3MgX2 代表的基团（X2 与上述相同）。] 镁[N(SO2R4)2]2[4］ (通式[4]中，四个 R4 各自独立地代表具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的全氟烷基、苯基或全氟苯基)。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.1, page 76 - 99
  作者：

  DOI：——

  日期：——
• Process of preparing perfluoroalkane-disulfonic acid salts by contacting bis (alkylsulfonyl) perfluoroalkanes with alkali permanganate
  申请人：DU PONT

  公开号：US03346606A1

  公开（公告）日：1967-10-10
• PROCESS FOR PRODUCING CATALYST COMPONENT FOR ADDITION POLYMERIZATION
  申请人：ITO Kazuyuki

  公开号：US20120053306A1

  公开（公告）日：2012-03-01

  A production process of a contact product, which can be used as a polymerization catalyst component, comprising contacting a metal oxide such as zinc oxide with a compound defined by a specific formula such as trifluoroacetic acid; a production process of a polymerization catalyst, comprising contacting the polymerization catalyst component with a transition metal compound; and a production process of a polymer, comprising polymerizing an addition-polymerizable monomer in the presence of the polymerization catalyst.
• US8288490B2
  申请人：——

  公开号：US8288490B2

  公开（公告）日：2012-10-16