diethyl 9,10-dihydrophenanthrene-2,7-dicarboxylate | 133208-12-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: diethyl 9,10-dihydrophenanthrene-2,7-dicarboxylate
• CAS: 133208-12-5
• 化学式: C₂₀H₂₀O₄
• 分子量: 324.376
• InChiKey: WRDIOOMOLDUFQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,7-二溴-9,10-二氢菲 生成 diethyl 9,10-dihydrophenanthrene-2,7-dicarboxylate
  参考文献：
  名称：

  Sugi Yoshihiro, Takeuchi Kazuhiko, Hanaoka Taka-aki, Matsuzaki Takehiko, +, Sekiyu gakkaishi (J. Jap. Petrol. Inst), 37 (1994) N 1, S 70-76

  摘要：

  DOI：

文献信息

• Synthesis of Aromatic Esters Catalyzed by Palladium on Charcoal: An Efficient Heterogeneous Catalyst for Alkoxycarbonylation of Aryl Iodides
  作者：Yoshihiro Sugi、Chinnasamy Ramesh、Ryo Nakamura、Yoshihiro Kubota、Minoru Miwa

  DOI：10.1055/s-2003-37646

  日期：——

  Palladium on charcoal was found to catalyze the carbon-ylation of aryl iodides with various aliphatic alcohols as well as less reactive phenols to give the corresponding esters in high yield at 140 °C and in the presence of carbon monoxide (1.0 MPa). The carbonylation-polycondensation of 2,7-diiodo-9,10-dihydrophenanthrene with bisphenol-A afforded high molecular weight polyarylate, poly [oxy-1,4-phenylene

  发现钯炭催化芳基碘化物与各种脂肪醇以及反应性较低的酚类的羰基化反应，在 140 °C 和一氧化碳（1.0 MPa）存在下以高产率生成相应的酯。2,7-diiodo-9,10-dihydrophenanthrene 与双酚 A 的羰基化缩聚反应得到高分子量多芳基化合物，聚 [oxy-1,4-phenylene (1-methylethyleneidene)-1,4-phenyleneoxycarbonyl(9,10) -二氢-2,7-菲二基）羰基]。
• 9,10-dihydrophenanthrene-2,7-dicarboxylic acid diesters, 7-Bromo-9,10-dihydrophenanthrene-2-carboxylic acid esters and a process for producing the same
  申请人：Director General, Agency of Industrial Science and Technology

  公开号：EP0397418A1

  公开（公告）日：1990-11-14

  A novel 9,10-dihydrophenanthrene2,7-­dicarboxylic acid diester represented by the general formula (I): and a novel 7-bromo-9,10-dihydrophenanthrene-2-carboxylic acid monoester represented by the general formula (II): wherein each R represents a hydrocarbon group containing from 1 to 20 carbon atoms. A process for selectively synthesizing the compound of the general formula (I) and the compound of the general formula (II) comprising reacting 2,7-dibromo-9,10-dihydrophenanthrene with carbon monoxide and an alcohol of the general formula (III) R-OH in the presence of a base and a palladium-phosphine catalyst. Such novel compounds of the general formula (I) and (II) can be produced in a high yield and selectivity from inexpensive raw materials by simple reaction steps.

  一种新的9,10-二氢菲烯2,7-二羧酸二酯，其通式表示为(I)：和一种新的7-溴-9,10-二氢菲烯-2-羧酸单酯，其通式表示为(II)：其中每个R表示含有1至20个碳原子的烃基。一种选择性合成通式(I)化合物和通式(II)化合物的方法，包括在碱和钯-膦催化剂的存在下，将2,7-二溴-9,10-二氢菲烯与通式(III) R-OH的醇和一氧化碳反应。这些新的通式(I)和(II)化合物可以通过简单的反应步骤从廉价原材料中高产率和选择性地制备。