N-butyl-2,2-dimethylbutanamide | 349416-93-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-butyl-2,2-dimethylbutanamide
• CAS: 349416-93-9
• 化学式: C₁₀H₂₁NO
• 分子量: 171.283
• InChiKey: VZLDLKNBRVHFEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-butyl-2,2-dimethylbutanamide 在 甲醇 、 dipotassium peroxodisulfate 、 palladium diacetate 、 potassium carbonate 作用下， 反应 20.0h， 生成 N-butyl-2-(hydroxymethyl)-2-methylbutanamide
  参考文献：
  名称：

  Palladium-Catalyzed β-Acyloxylation of Simple Amide via sp³ C–H Activation

  摘要：

  beta-Acylcoxy amides are prepared in moderate to high yields by palladium-catalyzed acyloxylation of primary sp(3) C-H bonds from simple amides without any special directing group. A catalytic system of Pd(OAc)(2)/CF3CO2H/K2S2O8 is available to various amides with N-substituted by linear alkanes, cyclic alkanes, and electron-deficient benzyl compounds in this reaction. Acyloxylated products could be transformed easily to the corresponding beta-hydroxy amides.

  DOI：

  10.1021/ol403393w
• 作为产物：
  描述：

  2,2-二甲基丁酰氯 、 正丁胺 在 三乙胺 作用下， 以 乙酸乙酯 为溶剂， 生成 N-butyl-2,2-dimethylbutanamide
  参考文献：
  名称：

  Palladium-Catalyzed β-Acyloxylation of Simple Amide via sp³ C–H Activation

  摘要：

  beta-Acylcoxy amides are prepared in moderate to high yields by palladium-catalyzed acyloxylation of primary sp(3) C-H bonds from simple amides without any special directing group. A catalytic system of Pd(OAc)(2)/CF3CO2H/K2S2O8 is available to various amides with N-substituted by linear alkanes, cyclic alkanes, and electron-deficient benzyl compounds in this reaction. Acyloxylated products could be transformed easily to the corresponding beta-hydroxy amides.

  DOI：

  10.1021/ol403393w

文献信息

• Shape memory polymers
  申请人：Anthamatten Mitchell L.

  公开号：US20080177303A1

  公开（公告）日：2008-07-24

  The present disclosure relates to Shape Memory Polymers (SMP's) comprising function groups that allow the polymers to be elastically deformed, utilized in the elastically deformed state, and subsequently returned to the original polymorphic shape.

  本公开涉及形状记忆聚合物（SMP），其中包含允许聚合物弹性变形的功能基团，可在弹性变形状态下使用，并随后返回到原始的多态形状。
• Shape Memory Polymers
  申请人：Anthamatten Mitchell L.

  公开号：US20110251364A1

  公开（公告）日：2011-10-13

  The present disclosure relates to Shape Memory Polymers (SMP's) comprising function groups that allow the polymers to be elastically deformed, utilized in the elastically deformed state, and subsequently returned to the original polymorphic shape.

  本公开涉及具有功能基团的形状记忆聚合物（SMP），这些功能基团使聚合物能够弹性变形，在弹性变形状态下使用，并随后返回到原始的多形态形状。
• LITHOGRAPHIC PRINTING PLATE PRECURSORS AND PROCESSES FOR PREPARING LITHOGRAPHIC PRINTING PLATES
  申请人：FUJIFILM Corporation

  公开号：US20150044612A1

  公开（公告）日：2015-02-12

  Lithographic printing plates and processes for preparing the lithographic printing plates are provided. The plates have excellent printing durability, staining resistance and staining resistance over time. The lithographic printing plate precursor includes: a substrate; a photosensitive layer provided on the substrate; and an extra layer optionally provided between the substrate and the photosensitive layer. The photosensitive layer or the extra layer adjacent to the substrate contains (A) a copolymer. The copolymer (A) includes: (a1) a repeating unit of formula (a1-1) below in a side chain, and (a2) a repeating unit having at least one of the structures represented by formulae (a2-1) to (a2-6) shown in the specification in a side chain. L 1 , Z 1 , R 1 , and R 21 , R 22 and R 23 in formula (a1-1) and the variables in formulae (a2-1) to (a2-6) are as defined in the specification.

  提供了用于制备平版印刷版和制备平版印刷版的过程。该版具有良好的印刷耐久性、耐污染性和随时间的污染性。平版印刷版的前体包括：基板；设置在基板上的感光层；以及可选地设置在基板和感光层之间的额外层。感光层或靠近基板的额外层包含(A)共聚物。共聚物(A)包括：(a1)公式(a1-1)的重复单元在侧链中，以及(a2)重复单元在侧链中至少具有公式(a2-1)到(a2-6)所表示的结构中的一个。公式(a1-1)中的L1、Z1、R1和R21、R22和R23以及公式(a2-1)到(a2-6)中的变量如规范中所定义。
• AGENT FOR FIBERS CONTAINING KERATIN, CONTAINING AT LEAST ONE SPECIFIC AMPHIPHILIC CATIONIC POLYMER AND AT LEAST ONE ADDITIONAL FILM-FORMING CATIONIC AND/OR STABILIZING POLYMER
  申请人：Mueller Burkhard

  公开号：US20110135591A1

  公开（公告）日：2011-06-09

  Agent for treating fibers containing keratin, particularly human hair, comprising, in a cosmetically acceptable carrier: (a) at least one amphiphilic, cationic polymer having at least one structural unit of formulae (I) to (IV), wherein; R 1 and R 4 are independently hydrogen or a methyl group, X 1 and X 2 are independently oxygen or an NH group, A 1 and A 2 are independently an ethane-1,2-diyl, propane-1,3-diyl or butane-1,4-diyl group, R 2 , R 3 , R 5 and R 6 are independently a (C 1 to C 4 )-alkyl group, R 7 is a C 8 to C 30 )-alkyl group and; (b) at least one film-forming cationic and/or stabilizing cationic polymer. The invention also relates to use of agents for temporarily styling hair and for haircare, particularly as an aerosol hairspray or mousse.
• POLYMERS, COMPOSITIONS AND METHODS FOR USE FOR FOAMS, LAUNDRY DETERGENTS, SHOWER RINSES AND COAGULANTS
  申请人：BERGERON Vance

  公开号：US20110257015A1

  公开（公告）日：2011-10-20

  The present invention relates to a polymeric material comprising units capable of having a cationic charge at a pH of from about 4 to about 12; provided that said polymeric material has an average cationic charge density from about 2.75 or less units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for hand dishwashing compositions and personal care products such as soaps, shaving cream foam, foaming shaving gel, foam dephiliatories and shampoos. The polymers are also effective as a soil release agent in fabric cleaning compositions. The polymers are also useful in agrochemical foam, fire-fighting foam, hard surface cleaner foam, and coagulant for titanium dioxide in paper making.