2-Tridecylhexanedioic acid | 41240-23-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Tridecylhexanedioic acid
• CAS: 41240-23-7
• 化学式: C₁₉H₃₆O₄
• 分子量: 328.492
• InChiKey: ZZTYPTNXGMEORU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  23
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-Tridecylhexanedioic acid 在 盐酸 作用下， 生成 Hexanedioic acid, 2-tridecyl-, dimethyl ester
  参考文献：
  名称：

  Comeau,D. et al., Bulletin de la Societe Chimique de France, 1972, p. 4163 - 4170

  摘要：

  DOI：
• 作为产物：
  描述：

  1-tosyloxytridecane 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 生成 2-Tridecylhexanedioic acid
  参考文献：
  名称：

  Comeau,D. et al., Bulletin de la Societe Chimique de France, 1972, p. 4163 - 4170

  摘要：

  DOI：

文献信息

• Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof
  申请人：BP CHEMICALS (ADDITIVES) LIMITED

  公开号：EP0273588A1

  公开（公告）日：1988-07-06

  An additive concentrate suitable for incorporation into a finished lubricating oil composition, the additive concentrate comprising: (a) a lubricating oil, (b) a lubricating oil soluble sulphurised alkaline earth metal hydrocarbyl phenate modified by incorporation of from greater than 2 to 35% by weight based on the weight of the composition of either (i) at least one carboxylic acid having the formula:-           R - - COOH      (I) wherein R is a C₁₀ to C₂₄ alkyl or alkenyl group and R¹ is either hydrogen, as C₁ to C₄ alkyl group or a -CH₂-COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the composition having a TBN greater than 300.

  一种适用于掺入成品润滑油组合物的浓缩添加剂，浓缩添加剂包括 (a) 润滑油 (b) 一种润滑油可溶性硫化碱土金属烃基苯甲酸酯，该苯甲酸酯通过掺入以下任一物质进行改性（以组合物重量计，掺入量大于 2%至 35%）： (i) 至少一种具有以下式子的羧酸 R - COOH (I) 其中 R 是 C₁₀ 至 C₂₄ 烷基或烯基，R¹ 是氢、C₁ 至 C₄ 烷基或-CH₂-COOH 基或酸酐、(ii) 含有 36 至 100 个碳原子的二羧酸或多羧酸，或其酸酐、酸氯化物或酯，组合物的 TBN 大于 300。
• A process for the preparation of a lubricating oil additive concentrate
  申请人：BP CHEMICALS (ADDITIVES) LIMITED

  公开号：EP0410648A2

  公开（公告）日：1991-01-30

  A process for the production of a lubricating oil additive concentrate comprises reacting at elevated temperature the following components:- component (A) a defined acid component (B) - a calcium base added either in a single addition or in a plurality of additions at intermediate points during the reaction, component (C) - at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di-­(C₃ or C₄) glycol, (iv) a tri-(C₂-C₄) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I) R(OR¹)xOR²      (I) wherein R is a C₁ to C₆ alkyl group, R¹ is an alkylene group, R² is hydrogen or a C₁ to C₆ alkyl group and x is an integer from 1 to 6, (vi) a C₁ to C₂₀ monohydric alcohol, (vii) a C₁ to C₂₀ ketone, (viii) a C₁ to C₁₀ carboxylic acid ester, or (ix) a C₁ to C₂₀ ether, optionally, component (D) - a lubricating oil, component (E) - carbon dioxide added subsequent to the, or each, addition of component (B), and component (F) - a compound of formula II R³X      (II) wherein X is a halogen and R³ is an alkyl, alkenyl or alkaryl group or halo derivative thereof.

  一种生产润滑油添加剂浓缩物的工艺包括在高温下使下列组分发生反应：- 成分(A) 成分 (A) 一种确定的酸 成分（B）--一种钙碱，可在反应过程中一次性加入或在中间点多次加入、 组分 (C) - 至少一种化合物，它是 (i) 水，(ii) 具有 2 至 4 个碳原子的多元醇，(iii) 二（C₃ 或 C₄）乙二醇，(iv) 三（C₂-C₄）乙二醇，(v) 式 (I) 的一元或多元烷二醇烷基醚 R(OR¹)xOR² (I) 其中 R 是 C₁ 至 C₆ 烷基，R¹ 是亚烷基，R² 是氢或 C₁ 至 C₆ 烷基，x 是 1 至 6 的整数、(vii) C₁ 至 C₂₀ 酮， (viii) C₁ 至 C₁₀ 羧酸酯，或 (ix) C₁ 至 C₂₀ 醚，可选成分 (D) - 润滑油、 成分(E) - 在添加成分(B)后或每次添加后加入的二氧化碳，以及 组分 (F) - 式 II 的化合物 R³X (II) 其中 X 为卤素，R³ 为烷基、烯基或烷芳基或其卤代衍生物。
• Overbased calixarates, process for their production, compositions containing them and use as lubricating oil additives
  申请人：BP CHEMICALS (ADDITIVES) LIMITED

  公开号：EP0450874A2

  公开（公告）日：1991-10-09

  Non-sulphurised overbased metal salts of sulphur-free calixarenes having a substituent hydroxyl group or groups available for reaction with metal base and their preparation are claimed. The salts are useful as additives to lubricating oils by reason of their acids neutralisation capability, their detergent and their antioxidant properties.

  本发明提出了具有一个或多个可与金属碱反应的取代羟基的无硫钙烯烃的非硫化过基金属盐及其制备方法。由于这些盐具有酸中和作用、清洁作用和抗氧化作用，因此可用作润滑油的添加剂。
• Process for the production of ester derivatives useful as fuels and lubricating oil additives and novel esters produced thereby
  申请人：BP CHEMICALS (ADDITIVES) LIMITED

  公开号：EP0450875A1

  公开（公告）日：1991-10-09

  Ester derivatives useful as fuels and lubricating oil additives are prepared by the Michael addition of an alkyl acrylate to an amine to produce an intermediate ester, followed by an ester interchange with the intermediate ester to produce the final ester derivatives, some of which are novel compounds.

  可用作燃料和润滑油添加剂的酯类衍生物的制备方法是：将丙烯酸烷基酯与胺进行迈克尔加成，生成中间酯，然后与中间酯进行酯交换，生成最终的酯类衍生物，其中一些是新型化合物。
• POLYALKOXYAMINES, THEIR PREPARATION, DISPERSANT ADDITIVES PREPARED THEREFROM AND USE OF THE ADDITIVES IN LUBRICATING OILS AND FUELS
  申请人：BP Chemicals Limited

  公开号：EP0452004A2

  公开（公告）日：1991-10-16

  Disclosed are novel polyalkoxyamines having the formula:- wherein (x+y) has a value in the range from 1 to 19 and y is either zero or an integer;         D is ⁅ CHR-CHR¹-O ⁆nCHR¹-CHR-   (II) wherein either R=R¹=H or R=C₁ to C₄ alkyl and R¹= H and n has a value in the range from 1 to 10; and    Y is independently either -OH or -NHR² wherein R² is either H or alkyl. Polyalkoxyamines having the formula (I) are prepared by the deaminative polymerisation of diamines, which can be prepared by the catalysed reaction of a glycol and ammonia in the presence of hydrogen. Reaction of a hydrocarbyl-substituted succinic acylating agent with the polyalkoxyamine of formula (I) produces a dispersant additive suitable for use in lubricating oil and fuel compositions.

  所公开的是具有以下式子的新型聚烷氧胺 其中 (x+y) 的值范围为 1 至 19，y 为零或整数； D 是 ⁅ CHR-CHR¹-O ⁆nCHR¹-CHR- (II) 其中 R=R¹=H 或 R=C₁ 至 C₄ 烷基和 R¹=H 且 n 的值在 1 至 10 之间；以及 Y 独立地为-OH 或-NHR²，其中 R² 为 H 或烷基。 具有式（I）的聚烷氧基胺可通过二胺的脱氨基聚合反应制备，二胺可通过乙二醇和氨在氢存在下的催化反应制备。烃基取代的琥珀酰化剂与式 (I) 的聚烷氧基胺反应，可产生一种适用于润滑油和燃料组合物的分散剂添加剂。