[7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazinato]zinc(II) | 888014-95-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazinato]zinc(II)
• 英文别名: Zn[pz(Pr)6(N2Se)]；ZINC;4,5,9,10,14,15-hexapropyl-21-selena-2,7,12,17,24,25,26,27-octaza-20,22-diazanidahexacyclo[16.5.1.13,6.18,11.113,16.019,23]heptacosa-1(24),2,4,6(27),7,9,11(26),12,14,16(25),17,19(23)-dodecaene
• CAS: 888014-95-7
• 化学式: C₃₄H₄₂N₁₀SeZn
• 分子量: 735.124
• InChiKey: CFUPDGCKFGQEET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.44
• 重原子数：
  46
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazinato]zinc(II) 在 H₂S 、 C₅H₅N 作用下， 以 吡啶 为溶剂， 生成 N,O-copper(II)-[7,8,12,13,17,18-hexapropyl-2-(5-tert-butyl-2-oxybenzylideneamino)-3-(quinoline-2-carboxamido)porphyrazinato]zinc(II)
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n
• 作为产物：
  描述：

  7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazine 、 zinc diacetate 在 (CH₃)2NCHO 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以83%的产率得到[7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazinato]zinc(II)
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n

文献信息

• Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes
  作者：Tomasz Goslinski、Chang Zhong、Matthew J. Fuchter、Charlotte L. Stern、Andrew J. P. White、Anthony G. M. Barrett、Brian M. Hoffman

  DOI：10.1021/ic060176n

  日期：2006.5.1

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.