The present disclosure is concerned with reinforced flame retarded polyethylene terephthalate molding compositions which have good mold release properties upon being injection molded because they contain low molecular weight copolymer acids which may have been neutralized with selected metal cations. If these copolymer acids are used in sufficient amount they may also act as drip suppressant agents thus allowing the compositions to reproducibly obtain a UL-94 rating at 1/32" of V-0. When used in lower amounts in combination with other drip suppressants these low molecular weight copolymer acids provide both enhanced mold release and enhanced drip suppression. These compositions contain a flame retardant package sufficient to give the base polyethylene terephthalate resin a UL-94 rating at ⅛" of V-0 when tested with just the flame retardant package. These compositions are preferably reinforced with glass or other fibers. The addition to these compositions of a compound bearing at least 3 terminal epoxy groups can improve the composition's physical properties and does improve their resistance to degradation due to thermal or hydrolysis exposure. These compositions are suitable for the injection molding of a wide variety of articles of commerce.
本公开涉及增强型阻燃聚
对苯二甲酸乙二醇酯模塑组合物,这种组合物在注塑成型时具有良好的脱模性能,因为它们含有低分子量的共聚物酸,这些共聚物酸可能已被选定的
金属阳离子中和。如果这些共聚物酸的用量足够大,它们还可以起到抑制滴
水的作用,从而使这些组合物在 1/32" V-0 时可重复获得 UL-94 等级。当以较低用量与其他滴注
抑制剂结合使用时,这些低分子量共聚物酸既能增强脱模性,又能增强滴注抑制性。这些组合物含有阻燃剂包,足以使基底聚
对苯二甲酸乙二醇酯
树脂在 V-0 ⅛ 英寸时达到 UL-94 等级。这些组合物最好用
玻璃纤维或其他纤维增强。在这些组合物中加入至少含有 3 个末端环氧基团的化合物,可以改善组合物的物理性能,并提高其抗热分解或
水解降解的能力。这些组合物适用于各种商业产品的注塑成型。