2-(morpholin-4-ylmethyl)acrylate d'ethyle | 27316-13-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 2-(morpholin-4-ylmethyl)acrylate d'ethyle
• 英文别名: 2(1-Morpholino)methylacrylsaeureethylester；2-(1-Morpholino)-methacrylsaeure ethyl ester；2-morpholin-4-ylmethyl-acrylic acid ethyl ester；Ethyl α-morpholinomethylacrylate；ethyl 2-(morpholin-4-ylmethyl)prop-2-enoate
• CAS: 27316-13-8
• 化学式: C₁₀H₁₇NO₃
• 分子量: 199.25
• InChiKey: LXXMMRWDJZFVME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(morpholin-4-ylmethyl)acrylate d'ethyle 在 sodium ethanolate 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 45.0h， 生成 Triethyl 2-phosphonomethylacrylate
  参考文献：
  名称：

  NOUVELLES VOIES D'ACCES AUX 2-ETHOXYCARBONYLALLYLPHONATES

  摘要：

  Michaelis-Arbusov 反应（方法 A）和亚磷酸二烷基酯的亲核加成，然后是 Hoffman 烯化（方法 B）代表了两种合成方法，从容易获得的乙基 2-(N ,N-二烷基氨基甲基)丙烯酸酯 1.

  DOI：

  10.1080/10426500490257005

文献信息

• 3-Pyrazolidinone derivatives
  申请人：Minnesota Mining and Manufacturing Company

  公开号：US04074051A1

  公开（公告）日：1978-02-14

  3-Pyrazolidinone compounds having a solubility of at least 12 grams/liter in an aqueous medium of pH 9 of the formula: ##STR1## wherein R is a mononuclear phenyl group having substituents in the 3, 4, or 5 positions with a total of no more than 4 non-metallic atoms with an atomic number greater than 1 and the total mass of the substituents being less than that of benzene, Q is an aqueous-solubilizing group of the formula: ##STR2## wherein R.sup.1 and R.sup.2 are independently a hydrogen, or alkyl group or together with the included nitrogen form a 5 or 6 membered heterocyclic ring composed of carbon, nitrogen and no more than one atom from the group of sulfur and oxygen, the total number of atoms in R.sup.1 and R.sup.2 having an atomic number greater than 1 being equal to or less than 6.

  3-吡唑烷酮化合物在pH为9的水性介质中的溶解度至少为每升12克，其化学式如下：其中R是一个单核苯基团，在3、4或5位置具有不超过4个非金属原子，其原子序数大于1，且取代基的总质量小于苯的质量，Q是一个具有以下化学式的水性增溶基团：其中R1和R2分别是氢、烷基基团或与所包括的氮一起形成由碳、氮组成的5或6元杂环环，其中最多有一个硫和氧原子，R1和R2中原子序数大于1的总数等于或小于6。
• [EN] DELIVERY OF SMALL INTERFERING RNA AND MICRO RNA THROUGH NANOGELS CONTAINING HYDROPHOBIC PSEUDO-PEPTIDES<br/>[FR] LIBÉRATION DE PETIT ARN INTERFÉRENT ET DE MICRO ARN À TRAVERS DES NANOGELS CONTENANT DES PSEUDO-PEPTIDES HYDROPHOBES
  申请人：UNIV TEXAS

  公开号：WO2016073706A1

  公开（公告）日：2016-05-12

  Nanoscale, pH-responsive polycationic networks useful for the delivery of anionic biologic therapeutics and associated methods.

  纳米级、pH响应性的多阳离子网络，可用于输送阴离子生物治疗剂及相关方法。
• Holograms
  申请人：ILFORD Limited

  公开号：EP0226542A2

  公开（公告）日：1987-06-24

  Holograms using gelatin as the binder are prepared by holographically exposing holographic material with coherent light, developing the holographic image by a chemical or physical process and before processing, simultaneously or subsequently, treating the material with an aqueous solution of a polymer which comprises a tertiary amine group.

  使用明胶作为粘合剂的全息图是通过以下方法制备的：用相干光对全息材料进行全息曝光，通过化学或物理过程对全息图像进行显影，然后在处理之前，同时或随后用含有叔胺基团的聚合物水溶液对材料进行处理。
• Sealing material for cable and cable using the same
  申请人：SANYO CHEMICAL INDUSTRIES, Ltd.

  公开号：EP0790265A1

  公开（公告）日：1997-08-20

  This invention relates to a polyurethane resin-forming sealing material for cables comprising a component (A) which comprises a water-insoluble water absorbent resin dispersion and a component (B) which comprises an organic polyisocyanate. A water absorbent resin dispersion used in the sealing material is a dispersion having a water absorbent resin or a hydrogel thereof dispersed in a polyol, and the dispersion is prepared by the polymerization of a water-soluble monomer or a precursor thereof and a crosslinking agent and/or a polysaccharide in a polyol. This invention is for providing a sealing material for optical fiber cables having an excellent water-stoppability without the risk of falling-off at the time of cable connection.

  本发明涉及一种用于电缆的聚氨酯树脂成型密封材料，包括由不溶于水的吸水树脂 分散体组成的组分（A）和由有机多异氰酸酯组成的组分（B）。密封材料中使用的吸水性树脂分散体是一种具有分散在多元醇中的吸水性树脂或其水凝胶的分散体，该分散体是通过水溶性单体或其前体与交联剂和/或多糖在多元醇中聚合制备的。本发明用于提供一种光缆密封材料，该材料具有优异的防水性，在光缆连接时不会有脱落的风险。
• BASE OIL FOR HYDRAULIC OIL AND HYDRAULIC OIL COMPOSITIONS
  申请人：Nippon Oil Corporation

  公开号：EP1908816A1

  公开（公告）日：2008-04-09

  The object of the present invention is to provide a base oil for hydraulic oil suitably used for hydraulic systems having filters of which micropore diameter is 50µm or less, which is capable to improve the decrease of flow in a hydraulic pump at low temperature like -30°C or less and capable to normally operate the hydraulic systems. The invention also provides a hydraulic oil composition using the above base oil, especially a hydraulic oil composition suitably used for such as tractors, transmissions, and common systems thereof having the hydraulic systems. In order to achieve the object, provided is a base oil for hydraulic oil comprising mineral oil, wherein the mineral oil is defined by kinematic viscosity at 100°C: 1.5~6mm2/s, pour-point: -10°C or less, viscosity index: 100 or more, %CP: 70 or more, %CA: 2 or less, and aniline point: 106°C or more; and wherein, the mineral base oil is treated by catalytic dewaxing process and/or contains tertiary carbon atoms at a ratio of 7.4% or more to the total carbon atoms.

  本发明的目的是提供一种用于液压系统的液压油基础油，该液压油适用于具有微孔直径为 50µm 或更小的过滤器的液压系统，能够改善液压泵在低温（如 -30°C 或更低）条件下流量的减少，并能够正常操作液压系统。本发明还提供了一种使用上述基础油的液压油组合物，特别是一种适用于拖拉机、变速箱及其具有液压系统的普通系统的液压油组合物。为了实现上述目的，本发明提供了一种由矿物油组成的液压油基础油，其中矿物油在 100°C 时的运动粘度为 1.5~6mm2/s：1.5~6mm2/s，倾点：-10°C 或更低，粘度指数：100 或更高，%CP：70 或更低：其中，矿物基础油经过催化脱蜡工艺处理，和/或含有占碳原子总数 7.4% 或以上比例的三级碳原子。