[Ru(meso-tetrakis(p-methoxyphenyl)porphyrinato)(sec-butylphosphine)2] | 905710-53-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Ru(meso-tetrakis(p-methoxyphenyl)porphyrinato)(sec-butylphosphine)2]
• 英文别名: [Ru(4-MeO-TPP)(PH2Bu(sec))2]
• CAS: 905710-53-4
• 化学式: C₅₆H₅₈N₄O₄P₂Ru
• 分子量: 1014.12
• InChiKey: CJGJQYTYLIHXGY-OWMWYBPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sec-Butylphosphonic dichloride 、 (tetra(p-methoxyphenyl)porphyrinato)Ru(CO) 、 lithium aluminium tetrahydride 以 乙醚 为溶剂， 生成 [Ru(meso-tetrakis(p-methoxyphenyl)porphyrinato)(sec-butylphosphine)2]
  参考文献：
  名称：

  One-Pot Synthesis of Metal Primary Phosphine Complexes from OPCl₂R or PCl₂R. Isolation and Characterization of Primary Alkylphosphine Complexes of a Metalloporphyrin

  摘要：

  Treatment of [Ru-II(Por)(CO)] [Por) porphyrinato(2-)] and O= PCI2R [R = Ad ( adamantyl), Bu-t, Bu-sec] or PCI(2)Mes (Mes = mesityl) with LiAIH(4) afforded primary alkyl- and arylphosphine complexes [Ru-II(Por)(PH2R)(2)], which have been isolated in pure form and characterized by H-1 NMR, P-31 NMR, IR, and UV-vis spectroscopy and mass spectrometry. The structures of [Ru-II(TTP)(PH(2)Ad)(2)] and [Ru-II(F-20-TPP)(PH(2)Mes)(2)] were determined by X-ray crystallography.

  DOI：

  10.1021/ic060553w