N-(2-ethylhexyl)-acrylamide | 91625-16-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2-ethylhexyl)-acrylamide
• 英文别名: N-(2-ethylhexyl)prop-2-enamide；N(2-ethylhexyl)acrylamide；N-2-ethylhexylacrylamide；2-Propenamide, N-(2-ethylhexyl)-
• CAS: 91625-16-0
• 化学式: C₁₁H₂₁NO
• 分子量: 183.294
• InChiKey: WEWMLPXWLVIVNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(2-ethylhexyl)-acrylamide 在 盐酸 、 四氯化硅 作用下， 以 水 、 甲苯 为溶剂， 反应 32.0h， 生成
  参考文献：
  名称：

  阴离子受体设计：利用外层配位化学获得对氯化物上金属氯酸盐的高选择性

  摘要：

  对于氯铂酸高阴离子选择性6 2-过氯-是由一系列酰胺基胺中所示，R 1 - [R 2 NCOCH 2 CH 2 NR 3 - [R 4（L1，其中R 1 = R 4 =苄基，R 2 = R 3 =苯基和具有R 1 = H，R 2 = 2-乙基己基，R 3 =苯基和R 4 =甲基的L3和酰胺基醚，R 1 R 2 NCOCH 2 CH 2 OR 3（具有R 1的L5= H，R 2 = 2-乙基己基和R 3 =苯基），其提供一种氯铂酸提取受体位点6 2-优先于氯-在从-6 M HCl溶液中萃取。发现酰胺醚受体L5对PtCl 6 2–的萃取剂比其酰胺胺类似物弱得多。密度泛函理论计算表明，这是由于难以使酰胺醚质子化以产生阳离子受体LH +，而不是后者显示出与PtCl 6 2–的结合较弱的缘故。受体最稳定的形式LH +含有互变异构体，其中添加的质子与酰胺氧原子形成分子内氢键，得到六元质子螯合物。分散校

  DOI：

  10.1021/acs.inorgchem.5b01317
• 作为产物：
  描述：

  丙烯酰胺 生成 N-(2-ethylhexyl)-acrylamide
  参考文献：
  名称：

  DAHMEN, K.;KUESTER, E.;MERTENS, R.;BREHM, H.

  摘要：

  DOI：

文献信息

• Copolymers Based on N-Vinylpyrrolidone and Branched Aliphatic Carbonxylic Acids, and Their Use as Solubilizers
  申请人：Angel Maximilian

  公开号：US20080200564A1

  公开（公告）日：2008-08-21

  Copolymers comprising: (a) 60 to 99% by weight of at least one monomer selected from the group consisting of N-vinyllactams, N-vinylamides, and mixtures thereof; (1) 1 to 40% by weight of at least one monomer selected from the group consisting of vinyl esters of aliphatic branched C 8 -C 30 -carboxylic acids; (c) 0 to 30% by weight of vinyl acetate; and (d) 0 to 39% by weight of at least one additional free-radically copolymnerizable monomer; wherein the % by weight content of components (a), (b), (c) and (d) totals 100%, and with the proviso that the total amount of component (b) and component (c) combined is 1 to 40% by weight based on the copolymer, are described along with methods of using such copolymers to solubilize substances which are insoluble in water, substances which are only sparingly soluble in water, and combinations thereof.

  共聚物包含：（a）60至99重量百分比的至少一种单体，选自N-乙烯基内酰胺、N-乙烯酰胺和它们的混合物；（b）1至40重量百分比的至少一种单体，选自支链的C8-C30脂肪族羧酸的乙烯酯；（c）0至30重量百分比的乙酸乙烯酯；和（d）0至39重量百分比的至少一种额外的自由基共聚单体；其中，组分（a）、（b）、（c）和（d）的重量百分比总和为100%，并且有条件规定组分（b）和组分（c）的总和基于共聚物为1至40重量百分比。还描述了使用这样的共聚物来增溶水不溶性物质、水微溶性物质以及它们的组合的方法。
• Continuous Method for Producing Amides of Ethylenically Unsaturated Carboxylic Acids
  申请人：Krull Matthias

  公开号：US20110089020A1

  公开（公告）日：2011-04-21

  The invention relates to a continuous method for producing amides, according to which at least one carboxylic acid of formula (I) R 3 -COON (I), wherein R 3 is an optionally substituted alkenyl group comprising between 2 and 4 carbon atoms, is reacted with at least one amine of formula (II) HNR 1 R 2 (II), wherein R 1 and R 2 are independently hydrogen or a hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt and/or a Michael adduct, and said ammonium salt is then reacted to form a carboxylic acid amide. under microwave irradiation in a reaction pipe, the longitudinal axis of the pipe being oriented in the direction of propagation of the microwaves of a monomode microwave applicator.

  该发明涉及一种连续生产酰胺的方法，根据该方法，至少一个具有化学式（I）R3-COON（I）的羧酸发生反应，其中R3是一个由2至4个碳原子组成的可选择取代的烯基基团，与至少一个具有化学式（II）HNR1R2（II）的胺发生反应，其中R1和R2独立地是氢或包含1至100个碳原子的烃基团，形成铵盐和/或迈克尔加合物，然后将所述铵盐反应形成羧酸酰胺，在微波辐射下在反应管内进行，管的纵轴朝向单模微波应用器的微波传播方向。
• Method For Producing Amides In The Presence Of Superheated Water
  申请人：Krull Matthias

  公开号：US20110089021A1

  公开（公告）日：2011-04-21

  The invention relates to a method for producing carboxylic acid amides, according to which at least one carboxylic acid of formula (I) R 3 —COON   (I) wherein R 3 is hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 50 carbon atoms, is reacted with at least one amine of formula (II) HNR 1 R 2 (II) wherein R 1 and R 2 are independently hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is reacted in the presence of superheated water, under microwave irradiation, to form a carboxylic acid amide.

  该发明涉及一种生产羧酸酰胺的方法，根据该方法，至少一种具有以下结构的羧酸（I）R3—COON（I）其中R3是氢或含有1至50个碳原子的可选择取代的烃基，与至少一种具有以下结构的胺（II）HNR1R2（II）其中R1和R2独立地是氢或含有1至100个碳原子的可选择取代的烃基，反应形成一种铵盐，然后在超热水存在下，在微波辐射下，将该铵盐反应形成一种羧酸酰胺。
• Process for the production of N-substituted acrylic acid amides
  申请人：Chemische Fabrik Stockhausen GmbH

  公开号：US04605740A1

  公开（公告）日：1986-08-12

  The present invention relates to a process for the production of N-substituted acrylic acid amides by conversion of 2-carboalkoxy-t-oxabicyclo(2,2,1)hept-5-enes with primary or secondary amines to 2-carboxamide-7-oxabicyclo(2,2,1)hept-5-enes and the thermal decomposition of the latter, preferably in the presence of Lewis acids and in a vacuum, to furane and N-substituted acrylic acid amides. The process according to the invention results in high purity N-substituted acrylic acid amides that are, in the main, free of bifunctional monomers which would disrupt the subsequent polymerization of the N-substituted acrylic acid amides by undesired cross-linking.

  本发明涉及一种生产N-取代丙烯酸酰胺的方法，通过将2-碳酰基-t-氧杂双环(2,2,1)庚-5-烯与一级或二级胺转化为2-羧酰胺-7-氧杂双环(2,2,1)庚-5-烯，然后在热分解时，首选在路易斯酸的存在下，在真空条件下对其进行处理，以得到呋喃和N-取代丙烯酸酰胺。本发明的方法可获得高纯度的N-取代丙烯酸酰胺，主要不含双官能团单体，这些单体会通过不希望的交联破坏后续的N-取代丙烯酸酰胺的聚合。
• NOVEL COPOLYMER, NOVEL COPOLYMER-CONTAINING COMPOSITION, LAMINATE BODY, METHOD OF PRODUCING METAL FILM-COATED MATERIAL, METAL FILM-COATED MATERIAL, METHOD OF PRODUCING METALLIC PATTERN-BEARING MATERIAL AND METALLIC PATTERN-BEARING MATERIAL
  申请人：KANO Takeyoshi

  公开号：US20100247880A1

  公开（公告）日：2010-09-30

  There is provided a polymer containing a unit represented by the following Formula (1), and a unit represented by following Formula (2). In Formula (1) and Formula (2), R 1 to R 5 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group; R 6 represents an unsubstituted alkyl group, alkenyl group, alkynyl group or an aryl group; V and Z each independently represent a single bond, a substituted or unsubstituted divalent organic group, an ester group, an amide group or an ether group, and L 1 and L 2 each independently represent a substituted or unsubstituted divalent organic group.

  提供了一种聚合物，其中包含由以下公式（1）表示的单元和由以下公式（2）表示的单元。在公式（1）和公式（2）中，R1到R5分别独立表示氢原子，取代或未取代的烷基基团；R6表示未取代的烷基基团，烯基基团，炔基基团或芳基基团；V和Z分别独立表示单键，取代或未取代的二价有机基团，酯基团，酰胺基团或醚基团，并且L1和L2分别独立表示取代或未取代的二价有机基团。