N,N-diphenyl-4'-vinyl-[1,1'-biphenyl]-4-amine | 845754-77-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-diphenyl-4'-vinyl-[1,1'-biphenyl]-4-amine
• 英文别名: 4-(4-ethenylphenyl)-N,N-diphenylaniline
• CAS: 845754-77-0
• 化学式: C₂₆H₂₁N
• 分子量: 347.459
• InChiKey: LESDLFWVSUMKJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-diphenyl-4'-vinyl-[1,1'-biphenyl]-4-amine 在 三乙烯二胺 、 三乙胺 、 cobalt acetylacetonate 作用下， 以 1,4-二氧六环 、 水 、 乙腈 为溶剂， 反应 9.0h， 生成
  参考文献：
  名称：

  发光颜色可调的吡唑并[1,5-a]嘧啶与β,β-二氟过氧化物作为1,3-双亲电体的区域选择性合成

  摘要：

  探讨了荧光吡唑并 [1,5-a] 嘧啶 (PP) 的合成和光物理特性。通过使用β , β-二氟过氧化物作为1,3-双亲电试剂，选择性地制备了一系列5,7-二取代荧光PP 。合成的 PP 显示出相当显着的斯托克斯位移（高达 211 nm）和覆盖大部分可见光谱（400 nm 至 800 nm）的可调发射波长的大窗口。理论计算表明，分子内电荷转移（ICT）能力对不同取代基的显着变化是颜色可调荧光发射的原因。

  DOI：

  10.1002/adsc.202100298
• 作为产物：
  描述：

  三苯胺 在 N-溴代丁二酰亚胺(NBS) 、 potassium carbonate 、 三苯基膦钯 作用下， 以 四氢呋喃 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.25h， 生成 N,N-diphenyl-4'-vinyl-[1,1'-biphenyl]-4-amine
  参考文献：
  名称：

  Polymers with alkyl main chain pendent biphenyl carbazole or triphenylamine unit as host for polymer light emitting diodes

  摘要：

  The soluble styrene polymers, bearing dicarbazole, phenylcarbazole or phenyltriphenylamine side groups were investigated as a host material for green emitter in phosphorescent PLED devices. Those polymers were synthesized by free radical polymerization via azobisisobutyronitrile (AIBN) as initiator under 75 degrees C. All of the host materials exhibit high thermal stability with high decomposition (T-d,T-5% weight loss > 398 degrees C) and glass transition temperatures (T-g > 172 degrees C). The HOMO (ca. -5.39 - -5.69 eV) and LUMO (ca. -2.22 - -2.41 eV) levels with the triplet energy of ca. 2.50-2.93 eV suggest that polymers are suitable for host materials for green emitter. The devices based on the emissive layers containing host materials doped with Ir(ppy)(3) (4 wt%) display stable green emission with high device performances. The brightness and current efficiency reach 15,800 cd/m(2) and 17.5 cd/A, respectively, at the optimum blending with 40 wt% 2-(4-biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazol (t-PBD). Furthermore, the device performance reached higher brightness (23,400 cd/m(2)) and current efficiency (12.3 cd/A) when mixture with 2,4,6-triphenyl-1,3,5-triazine (TRZ) and t-PBD. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2012.08.042

文献信息

• 전하 수송 재료 및 이를 포함한 유기 발광 소자
  申请人：SAMSUNG ELECTRONICS CO., LTD. 삼성전자주식회사(119981042713) Corp. No ▼ 130111-0006246BRN ▼124-81-00998

  公开号：KR20160093531A

  公开（公告）日：2016-08-08

  전하 수송 재료 및 이를 포함한 유기 발광 소자가 제시된다.

  提供了有机发光器件的材料和其中包含的有机发光器件。
• Living Anionic Polymerization of Styrene Derivatives Containing Triphenylamine Moieties through Introduction of Protecting Group
  作者：Beom-Goo Kang、Nam-Goo Kang、Jae-Suk Lee

  DOI：10.1021/ma1014353

  日期：2010.10.26

  We carried out the anionic polymerization of styrene derivatives containing the triphenylamine moieties, 4,4′-vinylphenyltriphenylamine (A) and 4,4′-vinylphenyl-N,N-bis(4-tert-butylphenyl)benzenamine (B), with a variety of initiators in tetrahydrofuran (THF) at −78 °C. The anionic polymerization of A was performed with sec-butyllithium, sec-butyllithium with additives, and (diphenylmethyl)potassium

  我们对含有三苯胺部分，4,4'-乙烯基苯基三苯胺（A）和4,4'-乙烯基苯基-N，N-双（4-叔丁基苯基）苯胺（B）的苯乙烯衍生物进行了阴离子聚合-78°C下，四氢呋喃（THF）中有多种引发剂。A的阴离子聚合是在-78℃下用仲丁基锂，具有添加剂的仲丁基锂和（二苯基甲基）钾在THF中进行的。在所有情况下，聚合期间在聚合物链之间发生分子间副反应。相比之下，B的阴离子聚合反应成功进行了sec丁基锂和萘化钾在THF中于-78°C放置0.5 h，而未观察到任何分子间副反应。得到了具有可预测的分子量和窄的分子量分布（M w / M n = 1.05-1.11）的明确定义的poly（B）。随后尝试了B与苯乙烯和2-乙烯基吡啶的顺序嵌段共聚，并定量合成了明确定义的嵌段共聚物，即聚苯乙烯-b-聚（B）和聚（B）-b-聚（2-乙烯基吡啶） 。所得聚（B）进行了调查。
• A new approach to 4-arylstyrenes: microwave-assisted synthesis and photophysical properties
  作者：M. Zen Eddin、M. G. Pervova、E. F. Zhilina、K. A. Chistyakov、E. V. Verbitskiy、G. L. Rusinov、V. N. Charushin

  DOI：10.1007/s11172-021-3325-x

  日期：2021.11

  convenient method was developed for the synthesis of 4-arylstyrenes containing residues of polycyclic aromatics or triphenylamine. The method is based on the microwave-assisted Suzuki—Miyaura cross-coupling reaction. The optical properties of the compounds were studied. High fluorescence quantum yields of 4-arylstyrenes make them promising monomers for the synthesis of polymers that can find use as photovoltaic

  开发了一种方便的方法来合成含有多环芳烃或三苯胺残基的 4-芳基苯乙烯。该方法基于微波辅助 Suzuki-Miyaura 交叉偶联反应。研究了化合物的光学性质。4-芳基苯乙烯的高荧光量子产率使其成为合成聚合物的有前途的单体，可用作光伏和传感器材料。
• Arylamine compounds and their use in electronic devices
  申请人：E. I. du Pont de Nemours and Company

  公开号：US07723546B1

  公开（公告）日：2010-05-25

  Provided are arylamine compounds having Formula I, II, III, or IV: wherein Ar is the same or different at each occurrence and is aryl having from 6 to 30 carbon atoms or heteroaryl having from 2 to 30 carbon atoms. Also provided are compositions comprising arylamine compounds. The invention also relates to use of such compounds in electronic devices, for example, organic electronic devices.

  提供的是具有化学式I、II、III或IV的芳胺化合物：其中Ar在每次出现时相同或不同，是具有6至30个碳原子的芳基或具有2至30个碳原子的杂环芳基。还提供了含有芳胺化合物的组合物。本发明还涉及在电子器件中使用这些化合物，例如有机电子器件。
• Organic electroluminescent device
  申请人：TDK CORPORATION

  公开号：US20040048100A1

  公开（公告）日：2004-03-11

  A vinyl polymer having a 9,10-substituted anthracene structure which is a stable structure with a high solid quantum efficiency is obtained from a vinyl monomer having a group derived from the structure of formula (1) wherein n 1 is an integer of 1 to 3, each of X 1 , X 2 , X 3 and X 4 is a substituent group, k 1 and k 4 are integers of 0 to 5, and k 2 and k 3 are integers of 0 to 4. An organic EL device comprising an organic layer containing the vinyl polymer becomes a molecule dispersed type organic EL device featuring a high efficiency and a long life. 1

  从具有9,10-取代蒽环结构的乙烯单体中获得了一种聚乙烯基聚合物，该结构稳定且具有高固体量子效率。该乙烯单体具有从式（1）的结构中派生的基团，其中n1是1至3的整数，X1、X2、X3和X4中的每一个均为取代基，k1和k4是0至5的整数，k2和k3是0至4的整数。含有该聚乙烯基聚合物的有机EL器件成为分子分散型有机EL器件，具有高效率和长寿命。