tris-(4-nitro-phenyl)-oxazole | 100235-07-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: tris-(4-nitro-phenyl)-oxazole
• 英文别名: Tris-(4-nitro-phenyl)-oxazol；2.4.5-Tris-(4-nitro-phenyl)-oxazol；2,4,5-Tris(4-nitrophenyl)oxazole；2,4,5-tris(4-nitrophenyl)-1,3-oxazole
• CAS: 100235-07-2
• 化学式: C₂₁H₁₂N₄O₇
• 分子量: 432.349
• InChiKey: NHEFKSBGLHCGRA-UHFFFAOYSA-N

物化性质

• 沸点：
  635.8±65.0 °C(Predicted)
• 密度：
  1.456±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  164
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  tris-(4-nitro-phenyl)-oxazole 生成 2,4,5-Tris(4-aminophenyl)oxazole
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  三苯基恶唑 生成 tris-(4-nitro-phenyl)-oxazole
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Photosensitive composition comprising azo compounds
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04612271A1

  公开（公告）日：1986-09-16

  A photosensitive composition is provided comprising at least one azo compound represented by formula (1) ##STR1## wherein A.sup.1 represents a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring; X represents an atomic group forming a substituted or unsubstituted carbocyclic or heterocyclic aromatic ring upon condensation with benzene rings; Ar represents a carbocyclic or heterocyclic aromatic ring substituted by at least one perfluoroalkyl group (groups other than perfluoroalkyl group may also be present); and n represents an integer of 3, 4, 5, or 6.

  提供一种光敏组合物，其中包括至少一个由式（1）表示的偶氮化合物 ##STR1## 其中，A.sup.1代表取代或未取代的碳环或杂环芳香环；X代表原子基团，与苯环缩合后形成取代或未取代的碳环或杂环芳香环；Ar代表至少一个全氟烷基取代的碳环或杂环芳香环（还可以存在除全氟烷基以外的其他基团）；n代表3、4、5或6的整数。
• Photoconductive composition and electro-photographic light-sensitive
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04619881A1

  公开（公告）日：1986-10-28

  A photoconductive composition is disclosed, containing at least one trisazo compound represented by the following general formula (1): ##STR1## wherein Z represents ##STR2## R.sup.6 represents a hydrogen atom, a lower alkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyl group, or a substituted group of them; As', which may be the same or different, each represents ##STR3## B.sup.1, B.sup.2 and B.sup.3 each represents a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a substituted lower alkyl group or lower alkoxy group, and B.sup.1, B.sup.2 and B.sup.3 may be identical or different; X represents an atomic group necessary to form an aromatic ring or heterocyclic ring, which may be substituted or unsubstituted, by condensing with the benzene ring to which the hydroxyl group and Y are bonded; Y represents ##STR4## R.sup.1 represents an alkyl group, a phenyl group or a substituted alkyl or phenyl group; R.sup.2 represents a hydrogen atom, a lower alkyl group, a carbamoyl group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group or a substituted or unsubstituted amino group; R.sup.3 represents an alkyl group, an aromatic group or a heteroaromatic group or a substituted alkyl group, aromatic group or heteroaromatic group; and R.sup.4 and R.sup.5, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aromatic group, a heteroaromatic group or a substituted alkyl group, aromatic group or heteroaromatic group, provided that R.sup.4 and R.sup.5 are not both hydrogen atoms, and R.sup.5 is not a hydrogen atom when Y is ##STR5## . An electrophotographic light-sensitive material is also disclosed, comprising an electrically conductive base and a layer containing an electric charge carrier transport compound and the trisazo compound as an electric charge carrier generating compound.

  本发明公开了一种光电导组合物，包含至少一种由以下普通公式（1）表示的三偶氮化合物：##STR1## 其中，Z表示##STR2## R.sup.6表示氢原子，低碳基，芳基，芳氧基，烷氧羰基，芳氧羰基，酰基或它们的取代基；As'，可以相同也可以不同，每个都表示##STR3## B.sup.1，B.sup.2和B.sup.3每个表示氢原子，卤素原子，低碳基，低烷氧基或取代的低碳基或低烷氧基，并且B.sup.1，B.sup.2和B.sup.3可以相同也可以不同；X表示必要的原子团以形成芳香环或杂环，可以是取代或未取代的，通过与氢氧基和Y连接的苯环缩合而成；Y表示##STR4## R.sup.1表示烷基，苯基或取代的烷基或苯基；R.sup.2表示氢原子，低碳基，氨基甲酰基，羧基，烷氧羰基，芳氧羰基或取代或未取代的氨基；R.sup.3表示烷基，芳基或杂芳基或取代的烷基，芳基或杂芳基；而R.sup.4和R.sup.5，可以相同也可以不同，每个都表示氢原子，烷基，芳基，杂芳基或取代的烷基，芳基或杂芳基，前提是R.sup.4和R.sup.5不是同时为氢原子，当Y为##STR5##时，R.sup.5不是氢原子。本发明还公开了一种电子照相感光材料，包括电导基底和含有电荷载流子传输化合物和三偶氮化合物的层作为电荷载流子发生化合物。
• Photoconductive composition and electrophotographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0155522A1

  公开（公告）日：1985-09-25

  A photoconductive composition is disclosed, containing at least one trisazo compound represented by the following general formula (1): wherein Z represents , -0-, -S-, or -Se-; R6 represents a hydrogen atom, a lower alkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyl group, or a substituted group of them; As', which may be the same or different, each represents B1. B2 and B3 each represents a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a substituted lower alkyl group or lower alkoxy group, and B1, B2 and B3 may be identical or different, X represents an atomic group necessary to form an aromatic ring or heterocyclic ring, which may be substituted or unsubstituted, by condensing with the benzene ring to which the hydroxyl group and Y are bonded; Y represents R' represents an alkyl group, a phenyl group or a substituted alkyl or phenyl group; R2 represents a hydrogen atom, a lower alkyl group, a carbamoyl group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group or a substituted or unsubstituted amino group; R3 represents an alkyl group, an aromatic group or a heteroaromatic group or a substituted alkyl group, aromatic group or heteroaromatic group; and R4 and R5, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aromatic group, a heteroaromatic group or a substituted alkyl group, aromatic group or heteroaromatic group, provided that R4 and R5 are not both hydrogen atoms, and R5 is not a hydrogen atom when Y is An electrophotographic light-sensitive material is also disclosed, comprising an electrically conductive base and a layer containing an electric charge carrier transfer compound and the trisazo compound as an electric charge carrier forming compound.

  本发明公开了一种光电导组合物，其中至少含有一种由以下通式 (1) 表示的三唑类化合物： 其中 Z 代表 、-0-、-S-或-Se-；R6 代表氢原子、低级烷基、芳基、芳氧基、烷氧羰基、芳氧羰基、酰基或它们的取代基；As'可以相同或不同，各自代表 B1.B2和B3各自代表氢原子、卤素原子、低级烷基、低级烷氧基或取代的低级烷基或低级烷氧基，B1、B2和B3可以相同或不同，X代表与羟基和Y键合的苯环缩合形成芳环或杂环所需的原子团，芳环或杂环可以是取代或未取代的；Y代表 R' 代表烷基、苯基或取代的烷基或苯基； R2 代表氢原子、低级烷基、氨基甲酰基、羧基、烷氧羰基、芳氧羰基或取代或未取代的氨基； R3 代表烷基、芳香族基团或杂芳族基团或取代的烷基、芳香族基团或杂芳族基团；以及 R4 和 R5（可以相同或不同）各自代表一个氢原子、一个烷基、一个芳香族基团、一个杂芳香族基团或一个取代的烷基、芳香族基团或杂芳香族基团，但 R4 和 R5 不能都是氢原子，且当 Y 是时，R5 不是氢原子 本发明还公开了一种电致发光感光材料，包括导电基底和含有电荷载体转移化合物和作为电荷载体形成化合物的三唑化合物的层。
• Troeger; Philippson, Journal fur praktische Chemie (Leipzig 1954), 1925, vol. <2> 110, p. 74
  作者：Troeger、Philippson

  DOI：——

  日期：——
• Henius, Justus Liebigs Annalen der Chemie, 1885, vol. 228, p. 346,354
  作者：Henius

  DOI：——

  日期：——