Methanesulfonic acid 2,2-bis-iodomethyl-3-methanesulfonyloxy-propyl ester | 842120-57-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: Methanesulfonic acid 2,2-bis-iodomethyl-3-methanesulfonyloxy-propyl ester
• 英文别名: [2,2-Bis(iodomethyl)-3-methylsulfonyloxypropyl] methanesulfonate
• CAS: 842120-57-4
• 化学式: C₇H₁₄I₂O₆S₂
• 分子量: 512.126
• InChiKey: OAMAVOFZICXJIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  足球烯 、 Methanesulfonic acid 2,2-bis-iodomethyl-3-methanesulfonyloxy-propyl ester 在 sodium thiomethoxide 作用下， 以 乙腈 为溶剂， 反应 168024.0h， 以8%的产率得到
  参考文献：
  名称：

  [60]Fullerene diol issued from pentaerythritol derivatives

  摘要：

  A new [60]fullerene diol is synthesized in good yield, in two steps starting front reaction of C-60(2-) anion with the benzyl-ideneacetal derived from 2,2-bis(iodomethyl)-1,3-propanediol. The corresponding [60]fullerene bis-mesylate is also formed in a similar way starting from bis-iodo bis-mesylate compound in the same series. The scope of this fullerene diol in synthesis is exemplified by its easy esterification with 4-formyl benzoyl chloride. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.132
• 作为产物：
  描述：

  二溴新戊二醇 在 三乙胺 、 sodium iodide 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 75.0h， 生成 Methanesulfonic acid 2,2-bis-iodomethyl-3-methanesulfonyloxy-propyl ester
  参考文献：
  名称：

  [60]Fullerene diol issued from pentaerythritol derivatives

  摘要：

  A new [60]fullerene diol is synthesized in good yield, in two steps starting front reaction of C-60(2-) anion with the benzyl-ideneacetal derived from 2,2-bis(iodomethyl)-1,3-propanediol. The corresponding [60]fullerene bis-mesylate is also formed in a similar way starting from bis-iodo bis-mesylate compound in the same series. The scope of this fullerene diol in synthesis is exemplified by its easy esterification with 4-formyl benzoyl chloride. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.132