2-bromo-9,9-dimethyl-7-(2-naphthyl)-fluorene | 1154751-23-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2-bromo-9,9-dimethyl-7-(2-naphthyl)-fluorene
• 英文别名: 2-bromo-9,9-dimethyl-7-(naphthalene-2-yl)-9H-fluorene；2-bromo-9,9-dimethyl-7-naphthalen-2-ylfluorene
• CAS: 1154751-23-1
• 化学式: C₂₅H₁₉Br
• 分子量: 399.33
• InChiKey: OMRQZMZOVJEJGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-bromo-9,9-dimethyl-7-(2-naphthyl)-fluorene 在 potassium phosphate 、 四(三苯基膦)钯 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 作用下， 以 乙醇 、 水 、 二甲基亚砜 、 甲苯 为溶剂， 反应 89.0h， 生成 5-bromo-2-(9,9-dimethyl-7-naphthylfluorene-2-yl)pyridine
  参考文献：
  名称：

  Iridium Complex Compound, Iridium-Complex-Compound-Containing Composition, Organic Electroluminescent Element and Method for Producing Same, Organic EL Display Device, and Organic EL Illuminator

  摘要：

  The present invention relates to an iridium complex compound represented by the following formula (1): in the formula (1), Ir represents an iridium atom, R 5 to R 14 , R 21 , and R 22 each independently represent a hydrogen atom, D, F, Cl, Br, I, or a substituent group, the groups adjacent to each other may be further bonded to each other to form a ring, and any one of R 12 and R 13 is a substituent group represented by the formula (2).

  公开号：

  US20230002428A1
• 作为产物：
  描述：

  9,9-二甲基-2-溴芴 在 四(三苯基膦)钯 、 periodic acid dihydrate 、 硫酸 、 碘 、 sodium carbonate 、 溶剂黄146 作用下， 以 水 、 甲苯 为溶剂， 反应 16.5h， 生成 2-bromo-9,9-dimethyl-7-(2-naphthyl)-fluorene
  参考文献：
  名称：

  EP2664609

  摘要：

  公开号：

文献信息

• NOVEL POLYMERIZABLE MONOMER, AND MATERIAL FOR ORGANIC DEVICE, HOLE INJECTION/TRANSPORT MATERIAL, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT EACH COMPRISING POLYMER (POLYMERIC COMPOUND) OF THE POLYMERIZABLE MONOMER
  申请人：Eida Mitsuru

  公开号：US20110315964A1

  公开（公告）日：2011-12-29

  A polymerizable monomer represented by the following formula (1) wherein at least one of Ar 1 to Ar 3 is substituted by a group represented by the following formula (2) and which is substituted by one or more groups comprising a polymerizable functional group. Ar 1 to Ar 3 are a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms, Ar 6 is a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms and Ar 4 and Ar 5 are a substituted or unsubstituted arylene group having 6 to 40 ring carbon atoms.

  由以下公式（1）表示的可聚合单体，其中Ar1至Ar3中的至少一个被以下公式（2）表示的基团取代，并且被一个或多个包含聚合功能基团的基团取代。Ar1至Ar3是具有6至40个环碳原子的取代或未取代芳基，Ar6是具有6至40个环碳原子的取代或未取代芳基，Ar4和Ar5是具有6至40个环碳原子的取代或未取代芳亚基。
• STYRYL-BASED COMPOUND, COMPOSITION CONTAINING STYRYL-BASED COMPOUND, AND ORGANIC LIGHT EMITTING DIODE INCLUDING STYRYL-BASED COMPOUND
  申请人：Han Sang-Hyun

  公开号：US20130119355A1

  公开（公告）日：2013-05-16

  A styryl-based compound represented by Formula 1, a composition containing the styryl-based compound, and an organic light-emitting diode (OLED) including the styryl-based compound: The styryl-based compound may exhibit high heat resistance and thus an OLED including the same may have low driving voltage, high brightness, high efficiency, and long lifetime.

  一种以化学式1表示的基于styryl的化合物，含有该基于styryl的化合物的组合物，以及包括该基于styryl的化合物的有机发光二极管（OLED）：基于styryl的化合物可能表现出高耐热性，因此包括该化合物的OLED可能具有低驱动电压、高亮度、高效率和长寿命。
• 电致发光化合物和包括该电致发光化合物的电致发光装置
  申请人：乐金显示有限公司

  公开号：CN110577471B

  公开（公告）日：2023-09-29

  本发明提供一种下式1和式2之一的电致发光化合物。本发明的另一方面是一种电致发光装置，包括：第一电极；面向所述第一电极的第二电极；和位于所述第一电极和所述第二电极之间的至少一个有机材料层；其中所述至少一个有机材料层中的一个或多个包括所述的电致发光化合物。#imgabs0#
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Takashima Yoriyuki

  公开号：US20110315965A1

  公开（公告）日：2011-12-29

  An organic electroluminescence device and a material for producing the organic electroluminescence device. The organic electroluminescence device includes an organic thin film layer between a cathode and an anode, the organic thin film layer including one or more layers, in which the organic thin film layer includes one or more light emitting layers and at least one of the light emitting layers includes a phosphorescent material and a host material. The host material has an essential structure in which a naphthalene ring is bonded to a fluorene skeleton, dibenzofuran skeleton, or dibenzothiophene skeleton. The organic electroluminescence device is a phosphorescent device having high efficiency and long lifetime.

  一种有机电致发光器件和制备该有机电致发光器件的材料。该有机电致发光器件包括在阴极和阳极之间的有机薄膜层，该有机薄膜层包括一个或多个层，其中有机薄膜层包括一个或多个发光层，至少一个发光层包括磷光材料和主体材料。主体材料具有一个必要的结构，其中萘环连接到芴骨架、二苯并呋喃骨架或二苯并噻吩骨架。该有机电致发光器件是一种具有高效率和长寿命的磷光器件。
• Material for organic electroluminescent element, and organic electroluminescent element
  申请人：Takashima Yoriyuki

  公开号：US08940412B2

  公开（公告）日：2015-01-27

  An organic electroluminescence device and a material for producing the organic electroluminescence device. The organic electroluminescence device includes an organic thin film layer between a cathode and an anode, the organic thin film layer including one or more layers, in which the organic thin film layer includes one or more light emitting layers and at least one of the light emitting layers includes a phosphorescent material and a host material. The host material has an essential structure in which a naphthalene ring is bonded to a fluorene skeleton, dibenzofuran skeleton, or dibenzothiophene skeleton. The organic electroluminescence device is a phosphorescent device having high efficiency and long lifetime.

  一种有机电致发光器件及用于制备该有机电致发光器件的材料。该有机电致发光器件包括阴极和阳极之间的有机薄膜层，该有机薄膜层包括一个或多个层，其中该有机薄膜层包括一个或多个发光层，至少其中一个发光层包括荧光材料和主体材料。该主体材料具有一个基本结构，其中萘环与芴骨架、二苯并呋喃骨架或二苯并噻吩骨架结合。该有机电致发光器件是一种具有高效率和长寿命的磷光器件。