3-oxiranyl-propionic acid vinyl ester | 98272-65-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-oxiranyl-propionic acid vinyl ester
• 英文别名: 3-Oxiranyl-propionsaeure-vinylester；Ethenyl 3-(oxiran-2-yl)propanoate
• CAS: 98272-65-2
• 化学式: C₇H₁₀O₃
• 分子量: 142.155
• InChiKey: KRKDIEMRKYVNLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  乙烯基戊-4-烯酸酯 在 过氧乙酸 、 乙酸乙酯 作用下， 生成 3-oxiranyl-propionic acid vinyl ester
  参考文献：
  名称：

  Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹

  摘要：

  DOI：

  10.1021/ja01522a048

文献信息

• [EN] MANUFACTURE OF AN EPOXYETHYL CARBOXYLATE OR GLYCIDYL CARBOXYLATE<br/>[FR] FABRICATION D'UN CARBOXYLATE D'ÉPOXYÉTHYLE OU D'UN CARBOXYLATE DE GLYCIDYLE
  申请人：MOMENTIVE SPECIALTY CHEMICALS RES S A

  公开号：WO2011095294A1

  公开（公告）日：2011-08-11

  The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate, including reacting a vinyl carboxylate or an allyl carboxylate using an oxidant and a water-soluble manganese complex in an aqueous reaction medium, and the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX3]Y, or a binuclear species of the general formula (II): [LMn(μ-X)3MnL]Yn, wherein Mn is a manganese; L is a ligand and each L is independently a polydentate ligand, each X is independently a coordinating species and each μ-X is independently a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 7.0.

  本发明涉及一种生产环氧乙基羧酸酯或环氧丙基羧酸酯的方法，包括在水相反应介质中使用氧化剂和水溶性锰配合物反应乙烯基羧酸酯或烯丙基羧酸酯，其中水溶性锰配合物包括氧化催化剂，其特征在于所述水溶性锰配合物是通式(I)的单核物种：[LMnX3]Y，或通式(II)的双核物种：[LMn(μ-X)3MnL]Yn，其中Mn是锰，L是配体，每个L独立地是多齿配体，每个X独立地是配位物种，每个μ-X独立地是桥联配位物种，Y是非配位的反离子，环氧化反应在pH为1.0至7.0的范围内进行。
• Manufacture of an epoxyethyl carboxylate or glycidyl carboxylate
  申请人：Momentive Specialty Chemicals Research Belgium

  公开号：EP2354130A1

  公开（公告）日：2011-08-10

  The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate by catalytic oxidation of a vinyl or allyl carboxylate using an oxidant, preferably hydrogen peroxide, and a manganese complex wherein the catalytic oxidation is performed in an aqueous reaction medium, comprising water with less than 10% by volume of cosolvents, wherein a water-soluble manganese complex is used as oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (1):          [LMnX3]Y     (I) or a binuclear species of the general formula (II):          [LMn(µ-X)3MnL]Y2     (II) wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each µ-X independently is a bridging coordinating species, whereas Y is an oxidatively-stable counterion, and wherein the epoxidation is carried out at a pH in the range of from 1.0. to 7.0. This invention also relates to epoxyethyl esters of neoacids having from 5 to 30 carbon atoms in the acid moiety.

  本发明涉及一种通过使用氧化剂（最好是过氧化氢）和锰络合物对乙烯基或烯丙基羧酸酯进行催化氧化来制造环氧乙基羧酸酯或缩水甘油酯的工艺，其中催化氧化在水反应介质中进行、其中水溶性锰络合物用作氧化催化剂，其特征在于水溶性锰络合物是通式（1）的单核物质： [LMnX3]Y (I) 或通式（II）的双核种类： [LMn(µ-X)3MnL]Y2 (II) 其中 Mn 是锰；L 或每个 L 独立地是多齿配位体，每个 X 独立地是配位体，每个 µ-X 独立地是桥接配位体，而 Y 是氧化稳定的反离子，环氧化作用在 pH 值为 1.0 至 7.0 的范围内进行。 本发明还涉及酸基中含有 5 至 30 个碳原子的新酸的环氧乙基酯。
• Ionic polymers and their use as wet-adhesives and coatings
  申请人：ACatechol, Inc.

  公开号：US10435599B2

  公开（公告）日：2019-10-08

  The present application discloses an adhesive composition comprising a polymer of the formulae A, B and C and methods for using the adhesive composition.

  本申请公开了一种包含式 A、B 和 C 聚合物的粘合剂组合物以及使用该粘合剂组合物的方法。
• MANUFACTURE OF AN EPOXYETHYL CARBOXYLATE OR GLYCIDYL CARBOXYLATE
  申请人：Momentive Specialty Chemicals Research Belgium S.A.

  公开号：EP2531496A1

  公开（公告）日：2012-12-12
• IONIC POLYMERS AND THEIR USE AS WET-ADHESIVES AND COATINGS
  申请人：Acatechol, Inc.

  公开号：EP3469032A1

  公开（公告）日：2019-04-17