1-[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]-N,N-bis[[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]methyl]methanamine | 1427282-78-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]-N,N-bis[[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]methyl]methanamine
• CAS: 1427282-78-7
• 化学式: C₁₄₇H₁₆₂N₁₀O₃₀
• 分子量: 2548.95
• InChiKey: CIPKHCGVUVTEDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.2
• 重原子数：
  187
• 可旋转键数：
  45
• 环数：
  48.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  372
• 氢给体数：
  0
• 氢受体数：
  37

反应信息

• 作为产物：
  描述：

  三炔丙基胺 、 mono-1-(2’-azidethoxy)methoxylpillar[5]arene 在 tetrakis(actonitrile)copper(I) hexafluorophosphate 、 三[(1-苄基-1H-1,2,3-三唑-4-基)甲基]胺 作用下， 以 丙酮 为溶剂， 反应 48.0h， 以91%的产率得到1-[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]-N,N-bis[[1-[2-[(9,14,19,24,26,28,30,32,34-nonamethoxy-4-hexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaenyl)oxy]ethyl]triazol-4-yl]methyl]methanamine
  参考文献：
  名称：

  主客体复合作用驱动的动态超分子自组装†

  摘要：

  柱状芳烃三聚体1和biviologen 2之间的主体-客体复合物被用于制造动态超分子自组装，该自组装在浓度变化时表现出从0D到3D的可逆多维转换。作为比较，由1，4-二甲氧基立柱[5]芳烃与2之间的络合作用建立的组装体仅在相似条件下显示出球形形态。

  DOI：

  10.1039/c2ob27340c

文献信息

• Host–guest complexation driven dynamic supramolecular self-assembly
  作者：Huacheng Zhang、Kim Truc Nguyen、Xing Ma、Hong Yan、Junfei Guo、Liangliang Zhu、Yanli Zhao

  DOI：10.1039/c2ob27340c

  日期：——

  Host–guest complexation between pillararene trimer 1 and biviologen 2 was used to fabricate the dynamic supramolecular self-assembly, which exhibits a reversible multidimensional transformation from 0D to 3D upon concentration changes. As a comparison, assemblies built by the complexation between 1,4-dimethoxypillar[5]arene and 2 only show spherical morphology under similar conditions.

  柱状芳烃三聚体1和biviologen 2之间的主体-客体复合物被用于制造动态超分子自组装，该自组装在浓度变化时表现出从0D到3D的可逆多维转换。作为比较，由1，4-二甲氧基立柱[5]芳烃与2之间的络合作用建立的组装体仅在相似条件下显示出球形形态。