1-decanesulfonic acid methyl ester | 67779-44-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 1-decanesulfonic acid methyl ester
• 英文别名: Nonan-1-sulfonsaeuremethylester；Methyl decanesulfonate；methyl decane-1-sulfonate
• CAS: 67779-44-6
• 化学式: C₁₁H₂₄O₃S
• 分子量: 236.376
• InChiKey: NSLRWZAGVYHOTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-decanesulfonic acid methyl ester 、 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 3-[2-[4-(dimethylamino)-6-[2-[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxycarbonyl]phenyl]ethynyl]pyridin-2-yl]ethynyl]benzoate 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Foldamers as Reactive Sieves:  Reactivity as a Probe of Conformational Flexibility

  摘要：

  A series of m-phenyleneethynylene (mPE) oligomers modified with a dimethylaminopyridine (DMAP) unit were treated with methyl sulfonates of varying sizes and shapes, and the relative reactivities were measured by UV spectrophotometry. Using a small-molecule DMAP analogue as a reference, each of the methyl sulfonates was shown to react at nearly identical rate. In great contrast, oligomers that are long enough to fold, and hence capable of binding the methyl sulfonate, experience rate enhancements of 18-1600-fold relative to that of the small-molecule analogue, depending on the type of alkyl chain attached to the guest. Three different oligomer lengths were studied, with the longest oligomers exhibiting the fastest rate and greatest substrate specificity. Even large, bulky guests show slightly enhanced methylation rates compared to that with the reference DMAP, which suggests a dynamic nature to the oligomer's binding cavity. Several mechanistic models to describe this behavior are discussed.

  DOI：

  10.1021/ja067670a
• 作为产物：
  描述：

  癸基溴 在 sodium sulfite 作用下， 以 水 为溶剂， 生成 1-decanesulfonic acid methyl ester
  参考文献：
  名称：

  The chemistry of terpenes—VIII

  摘要：

  DOI：

  10.1016/0040-4020(78)80050-7

文献信息

• Method of making polymeric particles
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0653442A2

  公开（公告）日：1995-05-17

  A method of making polymeric particles by forming a suspension of ethylenically unsaturated monomer droplets in water, the water containing a particulate suspension agent, the monomer droplets containing a nonreactive hydrophobic compound where the water solubility of the nonreactive compound is less than that of the monomer and polymerizing the monomer droplets.

  一种通过在水中形成乙烯基不饱和单体液滴悬浮液来制造聚合物微粒的方法，水中含有微粒悬浮剂，单体液滴中含有非反应性疏水化合物，其中非反应性化合物的水溶性小于单体的水溶性，并使单体液滴聚合。
• The process for making photographic polymeric matte bead particles
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0709399A2

  公开（公告）日：1996-05-01

  A process of making polymeric matte bead particles for use in photographic elements which comprises forming a suspension of ethylenically unsaturated monomer droplets in an aqueous media, subsequent to the formation of droplets and before commencement of reaction, adding to the aqueous media an effective amount of a hydrophilic colloid to improve adhesion and polymerizing the monomer to form solid polymeric particles.

  一种用于摄影元件的聚合消光珠粒子的制造工艺，包括在水介质中形成乙烯不饱和单体液滴悬浮液，在液滴形成后和反应开始前，向水介质中加入有效量的亲水胶体以提高粘附性，并使单体聚合形成固体聚合粒子。
• CURABLE COMPOSITION IMPROVED IN CURABILITY AND STORAGE STABILITY
  申请人：Kaneka Corporation

  公开号：EP1942153B1

  公开（公告）日：2010-11-17
• Curable composition improved in curability and storage stability
  申请人：KANEKA CORPORATION

  公开号：EP2366733B1

  公开（公告）日：2014-10-22
• US5455320A
  申请人：——

  公开号：US5455320A

  公开（公告）日：1995-10-03