cyclohex-1-en-1-ylmagnesium chloride | 126755-90-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: cyclohex-1-en-1-ylmagnesium chloride
• CAS: 126755-90-6
• 化学式: C₆H₉ClMg
• 分子量: 140.895
• InChiKey: OBLGUMFZBDFSRA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  cyclohex-1-en-1-ylmagnesium chloride 、 四氯化锡 以 四氢呋喃 为溶剂， 生成 Sn(1-cyclohexene-1-yl)4
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.14.3, page 136 - 139

  摘要：

  DOI：

文献信息

• Preparation of substituted bridged indenyl and related ligands
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135596A1

  公开（公告）日：2007-06-14

  A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp 2 -sp 2 or sp 2 -sp 3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L 1 and L 2 in formula (I) and to L 3 and L 4 in formula (II); L 1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp 2 carbon atom of the ring structure of the ligand; L 2 is a monoanionic ligand; or L 2 may, independently, be defined as L 1 ; L 3 is the same group as L 1 , but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L 4 is the same group as L 2 , though, when L 2 is defined as L 1 , L 4 may be the same as L 3 or L 1 ; R 1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M 1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X 2 , if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r+t corresponds to the oxidation number of M 1 .

  从化学配体的公式(I)通过与公式(III)的有机金属化合物进行sp2-sp2或sp2-sp3偶联反应，制备化学配体的公式(II)的方法。其中B是一个桥联基团，与公式(I)中的L1和L2以及公式(II)中的L3和L4结合；L1是一个取代的单环或多环配体，至少包含一个氯、溴、碘或磺酸酯取代基，直接与配体的环结构的sp2碳原子键合；L2是一个单负离子配体；或者L2可以独立地被定义为L1；L3与L1相同，但所述的至少一个氯、溴、碘或磺酸酯取代基被氢化碳基、取代的氢化碳基、卤代碳基或取代的卤代碳基片段所取代；L4与L2相同，但当L2被定义为L1时，L4可以与L3或L1相同；R1是一个氢化碳基、取代的氢化碳基、卤代碳基或取代的卤代碳基；M1是元素周期表第1、2、12、13或14组的元素；每个X2，如果存在，可独立地选择自卤素原子、羟基、烷氧基、芳基氧基、甲磺酸酯、对甲苯磺酸酯和三氟甲磺酸酯组成的群；r为1、2或3，t为0、1或2，其中r+t对应于M1的氧化数。
• Process for producing substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20060160968A1

  公开（公告）日：2006-07-20

  A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.

  一种生产取代茂金属化合物的工艺包括使第一种化合物与转移试剂反应，其中第一种化合物包括选自元素周期表第 3、4、5 或 6 族的过渡金属原子或镧系金属原子或锕系金属原子与至少一种单环或多环配体的复合物，该配体与 M 成 pi 键，并被至少一种卤素或磺酸盐取代、或锕系元素金属原子和至少一个单环或多环配位体，该配位体与 M 呈π键连接，并被至少一个卤素或磺酸盐取代基取代，转移试剂包括烃基、取代烃基、卤代羰基、取代卤代羰基、硅烷基或胚芽烷基自由基，该自由基在反应条件下能够取代所述第一化合物中的至少一个卤素或磺酸盐取代基。
• GB832338
  申请人：——

  公开号：——

  公开（公告）日：——
• PROCESS FOR PRODUCING SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP1866322A2

  公开（公告）日：2007-12-19
• Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
  申请人：Voskoboynikov Alexander Z.

  公开号：US20100113717A1

  公开（公告）日：2010-05-06

  A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.