2-propyl-tetradecanoic acid | 53705-91-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-propyl-tetradecanoic acid
• 英文别名: 2-Propyl-tetradecansaeure；2-propyltetradecanoic acid；2-Propyltetradecansaeure；Hexadecan-4-carbonsaeure
• CAS: 53705-91-2
• 化学式: C₁₇H₃₄O₂
• mdl: MFCD12974661
• 分子量: 270.456
• InChiKey: DSOCLLZEJDPHNQ-UHFFFAOYSA-N

物化性质

• 熔点：
  24.5-26.2 °C
• 沸点：
  167-190 °C(Press: 1.5 Torr)
• 密度：
  0.889±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.941
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-propyl-tetradecanoic acid 生成 2-羟基肉豆蔻酸
  参考文献：
  名称：

  .alpha.-Anions. VII. Direct oxidation of enolate anions to 2-hydroperoxy- and 2-hydroxycarboxylic acids and esters

  摘要：

  DOI：

  10.1021/jo00910a020
• 作为产物：
  描述：

  丙基丙二酸二乙酯 160.0~180.0 ℃ 、2.67 kPa 条件下， 生成 2-propyl-tetradecanoic acid
  参考文献：
  名称：

  Asinger,F.; Scheuffler,B., Journal fur praktische Chemie (Leipzig 1954), 1960, vol. 10, p. 265 - 289

  摘要：

  DOI：

文献信息

• [EN] NOVEL AROMA CHEMICALS HAVING A 1,2,2-TRIMETHYLCYCLOPENTAN-1-YL MOIETY<br/>[FR] NOUVEAUX ARÔMES CHIMIQUES PRÉSENTANT UNE FRACTION 1,2,2-TRIMÉTHYLCYCLOPENTAN-1-YLE
  申请人：BASF SE

  公开号：WO2016193133A1

  公开（公告）日：2016-12-08

  The present invention relates to novel compounds of general formulae (la), (lb) and (Ic) and to the stereoisomers thereof. The compounds are useful as a fragrance or as flavor as they have a sandalwood like scent. The invention also relates to a method for imparting or modifying a scent or a flavor to a composition by including said compounds into such composition, to a fragrance containing composition and/or a fragrance material containing said compound and to a process for preparing these compounds. X is C(R4)-OH or C=O; R1 is selected from the group consisting of hydrogen, C1-C4-alkyl, C2-C4- alkenyl and C3-C4-cycloalkyl, R2 is selected from the group consisting of hydrogen, C1-C4-alkyl, C2-C4- alkenyl and C3-C4-cycloalkyl, R3 is C1-C4-alkyl, R3a is selected from the group consisting of hydrogen and C1-C4-alkyl, R3b is hydrogen or together with R3a is CH2; R4 is selected from the group consisting of hydrogen and C1-C4-alkyl.

  本发明涉及一般式（Ia）、（Ib）和（Ic）的新化合物及其立体异构体。这些化合物可用作香精或调味剂，因为它们具有类似檀香的香味。该发明还涉及一种通过将这些化合物包含在组合物中来赋予或修改香味或口味的方法，涉及一种含有这些化合物的香精组合物和/或含有该化合物的香精材料，以及制备这些化合物的方法。X为C（R4）-OH或C=O；R1选自氢、C1-C4烷基、C2-C4烯基和C3-C4环烷基组成的群；R2选自氢、C1-C4烷基、C2-C4烯基和C3-C4环烷基组成的群；R3为C1-C4烷基，R3a选自氢和C1-C4烷基，R3b为氢或与R3a一起为CH2；R4选自氢和C1-C4烷基。
• Aqueous non-aggressive anthelmintic pour-on formulations
  申请人：JANSSEN PHARMACEUTICA N.V.

  公开号：EP0147883A2

  公开（公告）日：1985-07-10

  A spot-on formulation for combatting helmintic infestations in non-human animals containing per 100 ml from 0.04 to 0.15 moles of a pharmaceuticany acceptable acid addition salt of tetramisole or levamisole and a vehicle consisting of from 1 to 60% v/v of a penetration enhancing and/or moistening agent in water.

  一种用于防治非人类动物蠕虫感染的点滴制剂，每 100 毫升中含有 0.04 至 0.15 摩尔的四咪唑或左旋咪唑的药学上可接受的酸加成盐，以及一种由 1 至 60% v/v 的渗透增强剂和/或湿润剂在水中组成的载体。
• REFRIGERATING MACHINE OIL COMPOSITIONS
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1167495A1

  公开（公告）日：2002-01-02

  The invention provides a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing (a) a partial ester of a polyalcohol and a fatty acid and (b) an acid phosphate or its amine salt; and a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing any of (a) acid phosphates or their amine salts, (b) acetylene glycol alkylene oxide adducts, (c) potassium salts of fatty acids, etc., (d) organic acids, and (e) fatty acid amides. The refrigerator oil compositions have good lubricity and are especially effective for reducing the friction in both the oil region and the extreme-pressure region in the sliding area between aluminium materials and steel materials.

  本发明提供了一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 多元醇和脂肪酸的部分酯和 (b) 酸性磷酸盐或其胺盐；以及一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 酸性磷酸盐或其胺盐、(b) 乙二醇环氧烷加合物、(c) 脂肪酸钾盐等中的任何一种、(d) 有机酸，以及 (e) 脂肪酸酰胺。冷冻机油组合物具有良好的润滑性，尤其能有效减少铝材料和钢材料之间滑动区域的油区和极压区的摩擦。
• Refrigerating machine oil composition
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1681341A1

  公开（公告）日：2006-07-19

  The invention provides a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing (a) a partial ester of a polyalcohol and a fatty acid and (b) an acid phosphate or its amine salt; and a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing any of (a) acid phosphates or their amine salts, (b) acetylene glycol alkylene oxide adducts, (c) potassium salts of fatty acids, etc., (d) organic acids, and (e) fatty acid amides. The refrigerator oil compositions have good lubricity and are especially effective for reducing the friction in both the oil region and the extreme-pressure region in the sliding area between aluminium materials and steel materials.

  本发明提供了一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 多元醇和脂肪酸的部分酯和 (b) 酸性磷酸盐或其胺盐；以及一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 酸性磷酸盐或其胺盐、(b) 乙二醇环氧烷加合物、(c) 脂肪酸钾盐等中的任何一种、(d) 有机酸，以及 (e) 脂肪酸酰胺。冷冻机油组合物具有良好的润滑性，尤其能有效减少铝材料和钢材料之间滑动区域的油区和极压区的摩擦。
• COMPOSITION FOR PROTECTION OF BODY SURFACE
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1891924A1

  公开（公告）日：2008-02-27

  A body surface protecting composition, comprising at least one type of multi-chain multiple hydrophilic group-type compound having two or more hydrophobic groups and two or more hydrophilic groups in the molecule, which has an excellent effect of accelerating the recovery of the barrier function of skin and hair and preventing degradation of that function.

  一种体表保护组合物，包含至少一种多链多亲水基团型化合物，其分子中含有两个或两个以上的疏水基团和两个或两个以上的亲水基团，该组合物在加速恢复皮肤和头发的屏障功能以及防止该功能退化方面具有极佳的效果。