2-(5-Methylpyridin-2-yl)-6-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]pyridine | 1375186-69-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(5-Methylpyridin-2-yl)-6-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]pyridine
• CAS: 1375186-69-8
• 化学式: C₂₅H₂₃N₃
• 分子量: 365.478
• InChiKey: UIRQMPZAFLHCGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(5-Methylpyridin-2-yl)-6-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]pyridine 、 iron(II) bromide 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

  摘要：

  Iron complexes formulated as Fe(terpy)X-2 (terpy = 2,2':6',2 ''-terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for hydrosilylation of olefin with hydrosilane were examined. Although Fe(terpy)X-2 did not show catalytic activity, the treatment of Fe(terpy)X-2 with NaHBEt3 caused catalytic activity. The influence of substituents in terpy on the catalytic activity was examined, and it was found that some complexes with an unsymmetrically disubstituted terpy selectively produced 1-silylalkane with quite high catalytic activity. In the reaction of 1-octene with PhSiH3, the double-hydrosilylation product Ph(1-octyl)(2)SiH was selectively obtained.

  DOI：

  10.1021/om300279t
• 作为产物：
  描述：

  2,6-二溴吡啶 在 盐酸 、 四(三苯基膦)钯 、 正丁基锂 、 Na₃PO₄*12H₂O 、 三丁基氯化锡 、 copper dichloride 作用下， 以 四氢呋喃 、 乙二醇二甲醚 、 乙醚 、 水 为溶剂， 生成 2-(5-Methylpyridin-2-yl)-6-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]pyridine
  参考文献：
  名称：

  Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

  摘要：

  Iron complexes formulated as Fe(terpy)X-2 (terpy = 2,2':6',2 ''-terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for hydrosilylation of olefin with hydrosilane were examined. Although Fe(terpy)X-2 did not show catalytic activity, the treatment of Fe(terpy)X-2 with NaHBEt3 caused catalytic activity. The influence of substituents in terpy on the catalytic activity was examined, and it was found that some complexes with an unsymmetrically disubstituted terpy selectively produced 1-silylalkane with quite high catalytic activity. In the reaction of 1-octene with PhSiH3, the double-hydrosilylation product Ph(1-octyl)(2)SiH was selectively obtained.

  DOI：

  10.1021/om300279t