9-乙烯基-2,3,4,9-四氢-1H-咔唑 | 60507-53-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 9-乙烯基-2,3,4,9-四氢-1H-咔唑
• 英文名称: 9-vinyl-2,3,4,9-tetrahydro-1H-carbazole
• 英文别名: 9-vinyl-1,2,3,4-tetrahydro-carbazole；9-Vinyl-1,2,3,4-tetrahydro-carbazol；9-Vinyl-1,2,3,4-tetrahydrocarbazol；N-Vinyl-tetrahydrocarbazol；N-vinyl-tetrahydrocarbazole；9-ethenyl-1,2,3,4-tetrahydrocarbazole
• CAS: 60507-53-1
• 化学式: C₁₄H₁₅N
• mdl: MFCD09839514
• 分子量: 197.28
• InChiKey: BCFAZFGWDQRUTC-UHFFFAOYSA-N

物化性质

• 保留指数：
  1882

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.285
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  9-乙烯基-2,3,4,9-四氢-1H-咔唑 、 硫酸 生成 1,2,3,4-四氢咔唑
  参考文献：
  名称：

  Clemo; Perkin; Robinson, Journal of the Chemical Society, 1924, vol. 125, p. 1780

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 生成 9-乙烯基-2,3,4,9-四氢-1H-咔唑
  参考文献：
  名称：

  Clemo; Perkin, Journal of the Chemical Society, 1924, vol. 125, p. 1810

  摘要：

  DOI：

文献信息

• Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials
  作者：Konstantin Rodygin、Alexander Bogachenkov、Valentine Ananikov

  DOI：10.3390/molecules23030648

  日期：——

  We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yields. Cross-linked and linear polymers were synthesized from N-vinyl carbazoles through free radical and

  我们开发了一种简单有效的策略，可以使用容易获得的固态乙炔试剂（碳化钙，KF和KOH）来获得各种天然材料的N-乙烯基仲胺。吡咯，吡唑，吲哚，咔唑和二芳基胺已成功乙烯基化，收率很高。N-乙烯基咔唑通过自由基聚合和阳离子聚合合成了交联的线性聚合物。奥氮平（一种抗精神病药物）的后修饰成功进行。
• Process for producing colored molded product of thermoplastic resin
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0050501A1

  公开（公告）日：1982-04-28

  A process for producing colored molded product of thermoplastic resin excellent in gloss, color tone, transparency, uniformity and various fastnesses which comprises mixing (A) 100 parts by weight of a thermoplastic resin and (B) 0.01-20 parts by weight of a dyed product obtained by dyeing, with an anionic dyestuff, a copolymer of ethylene and one or more monomer(s) copolymerizable having a basic nitrogen or a composition comprising said copolymer and a metal salts of an organic carboxylic acid(s) and thereafter molding the mixture.

  一种生产光泽度、色调、透明度、均匀性和各种牢度均优良的热塑性树脂彩色模塑产品的工艺，包括将(A)100 份（重量）热塑性树脂和(B)0.01-20 份（重量）用阴离子染料染色得到的染色产品、乙烯和一种或多种具有碱性氮的可共聚单体的共聚物或由上述共聚物和有机羧酸的金属盐组成的组合物混合，然后将混合物模塑。
• Anti-fouling agent
  申请人：Nitto Kasei Co., Ltd.

  公开号：EP0091039A2

  公开（公告）日：1983-10-12

  An antifouling agent comprising as an antifouling component a substantially linear triorganotin-containing copolymer containing (a) at least one kind of N-coordinated triorganotin-containing recurring units of the formula (la) or (Ib) represented in the specification and (b) comonomer recurring units derived from at least one ethylenic vinyl compound as a comonomer. The antifouling agent is applied to a structure which is needed to be protected from fouling organisms to form a film of the copolymer on the structure.

  一种防污剂，其防污成分包括基本上线性的含三聚有机锡共聚物，该共聚物含有(a)至少一种如说明书中所示的式(la)或(Ib)的N-配位三聚有机锡循环单元和(b)作为共聚单体的至少一种乙烯基乙烯基化合物衍生的共聚单体循环单元。 将防污剂涂在需要防止污损生物的结构上，在该结构上形成一层共聚物薄膜。
• Plasma developable negative resist compositions for electron beam, X-ray and optical lithography
  申请人：TEXAS INSTRUMENTS INCORPORATED

  公开号：EP0130088A2

  公开（公告）日：1985-01-02

  A negative resist composition including a polymeric matrix material, a polymerizable monomer, and an onium salt radiation sensitive initiator. The monomer is polymerized by irradiating the resist with an e-beam, x-ray, or ultraviolet source and heating the exposed resist. The resist is developed by a dry etchant such as plasma or a reactive ion etchant.

  一种阴性抗蚀剂组合物，包括聚合物基体材料、可聚合单体和铟盐辐射敏感引发剂。 用电子束、X 射线或紫外线源照射抗蚀剂并加热暴露的抗蚀剂，使单体聚合。 抗蚀剂通过干蚀刻剂（如等离子体或活性离子蚀刻剂）显影。
• Palladium-catalyzed vinylation of indoles with vinyl ethers via deoxygenative coupling
  作者：Bowen Wang、Jianxiao Li、Wanqing Wu、Liangbin Huang、Huanfeng Jiang

  DOI：10.1007/s11426-024-2184-x

  日期：2024.11

  therefore, various synthetic methods for indole functionalizations have arisen in recent years. Herein, we report a Pd-catalyzed deoxygenative coupling for the N-vinylation of indoles by employing vinyl ethers. The vinylated indoles could be readily prepared in good to excellent yields with N1-regioselectivity regardless of the electronic characteristics and substitution patterns of indole substrates

  吲哚是一种在许多天然产物和药物中很有前途的杂芳烃；因此，近年来出现了各种吲哚官能化的合成方法。在此，我们报道了使用乙烯基醚进行吲哚N-乙烯基化的 Pd 催化脱氧偶联。无论吲哚底物的电子特性和取代模式如何，乙烯基化吲哚都可以很容易地以良好到优异的产率制备，并具有 N1 区域选择性。一些基于吲哚的药物分子，如禾本科胺、吴茱萸碱、吴茱萸碱和褪黑激素也成功地乙烯基化。此外，咔唑和吲唑也被证明参与其中。此外，乙烯基化吲哚可以很容易地转化为结构有趣的吲哚衍生物。