Disilver;2,2,3,3,3-pentafluoropropanoate | 496968-68-4

• 分子结构分类: 有机化合物
• 英文名称: Disilver;2,2,3,3,3-pentafluoropropanoate
• CAS: 496968-68-4
• 化学式: C₆Ag₂F₁₀O₄
• 分子量: 541.784
• InChiKey: VGBOYKBTBKKHBC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Disilver;2,2,3,3,3-pentafluoropropanoate 、 三乙基膦 以 四氢呋喃 、 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Thermal studies of Ag(I) complexes with triethylphosphine and perfluorinated carboxylates

  摘要：

  Silver(I) complexes with triethylphosphine and perfluorinated carboxylic acids residues of general formula [Et3PAgOOCR](2), where R=C2F5, C3F7, C6F13, C7F15, C8F17, C9F19, C6F5 and Et3PAgOOC(CF2)(3)COOAgPEt3, were synthesized. Thermal decomposition proceeded in two stages - both exothermic processes corresponding to the elimination of carboxylate and triethylphosphine residues. The final product of the thermal decomposition was metallic silver. Analyses by C-13, F-19, P-31 NMR spectroscopy and vibrational spectra suggest trigonal coordination of Ag(I), the coordination sphere consisting of unidentate triethylphosphine and bidentate carboxylates forming bridges between metal ions. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(98)00285-8