2-(2,5-Dicarbonochloridoylphenyl)benzene-1,4-dicarbonyl chloride | 1031284-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2,5-Dicarbonochloridoylphenyl)benzene-1,4-dicarbonyl chloride
• CAS: 1031284-67-9
• 化学式: C₁₆H₆Cl₄O₄
• 分子量: 404.033
• InChiKey: KWVMSMBDRCXCQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(2,5-Dicarbonochloridoylphenyl)benzene-1,4-dicarbonyl chloride 在 ammonium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 反应 2.0h， 以149 mg的产率得到1,1'-biphenyl-2,2',5,5'-tetracarboxamide
  参考文献：
  名称：

  Self-assembly of chiral hydrogen-bonded grid layers from terephthalic Siamese twins

  摘要：

  2,2',5,5'-Tetracarboxy- and 2,2', 5,5'-tetracarbamoyl-substituted biphenyls and also the 2,2',3,3',6,6'-hexacarboxy-substituted analogue behave as Siamese twins of terephthalic tectons in the single crystal self-assembly, giving rise to chiral 2D grid layers. A comparison has been made with the corresponding 2,2',6,6'-tetrasubstituted biphenyls which mimic isophthalic twins in their self-assembly. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00758-9
• 作为产物：
  描述：

  2,2',5,5'-biphenyltetracarboxylic acid 在 氯化亚砜 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 生成 2-(2,5-Dicarbonochloridoylphenyl)benzene-1,4-dicarbonyl chloride
  参考文献：
  名称：

  Self-assembly of chiral hydrogen-bonded grid layers from terephthalic Siamese twins

  摘要：

  2,2',5,5'-Tetracarboxy- and 2,2', 5,5'-tetracarbamoyl-substituted biphenyls and also the 2,2',3,3',6,6'-hexacarboxy-substituted analogue behave as Siamese twins of terephthalic tectons in the single crystal self-assembly, giving rise to chiral 2D grid layers. A comparison has been made with the corresponding 2,2',6,6'-tetrasubstituted biphenyls which mimic isophthalic twins in their self-assembly. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00758-9